Rejection of organic micropollutants (disinfection by-products, endocrine disrupting compounds, and pharmaceutically active compounds) by NF/RO membranes

2003 ◽  
Vol 227 (1-2) ◽  
pp. 113-121 ◽  
Author(s):  
Katsuki Kimura ◽  
Gary Amy ◽  
Jörg E. Drewes ◽  
Thomas Heberer ◽  
Tae-Uk Kim ◽  
...  
2007 ◽  
Vol 303 (1-2) ◽  
pp. 267-277 ◽  
Author(s):  
Anna M. Comerton ◽  
Robert C. Andrews ◽  
David M. Bagley ◽  
Paul Yang

2013 ◽  
Vol 13 (5) ◽  
pp. 1348-1357 ◽  
Author(s):  
Sabrina Diemert ◽  
Robert C. Andrews

This study assessed the impact of chemical coagulation using alum on the removal of three endocrine-disrupting compounds (EDCs; bisphenol A, clofibric acid and estriol) and nine pharmaceutically active compounds (PhACs; acetaminophen, carbamazepine, diclofenac, gemfibrozil, ketoprofen, naproxen, pentoxifylline, sulfamethoxazole and sulfachloropyridazine). The impact on natural organic matter (NOM) fractions as determined using liquid chromatography–organic carbon detection (LC–OCD; total dissolved organic carbon (DOC), hydrophobic DOC, biopolymers, humic substances, building blocks, low molecular weight neutrals and acids) was also examined. Three test surface waters were included: Lake Ontario, Grand River and Otonabee River water (Ontario, Canada). Gemfibrozil concentrations were reduced in both Otonabee and Grand River waters. Reductions were noted for carbamazepine and (inconsistently) for acetaminophen, and estrone appeared to increase in concentration in Grand River water with increasing alum doses. NOM removal was primarily attributed to the humic fraction, with small reductions in biopolymers in all of the waters studied.


Author(s):  
Anna M. Comerton ◽  
Robert C. Andrews ◽  
David M. Bagley

The detection of organic micropollutants, such as endocrine-disrupting compounds, pharmaceuticals and personal care products, in wastewater and the aquatic environment has brought increasing concern over their potential adverse ecological and human impacts. These compounds are generally present at trace levels (ng l −1 ) and in complex water matrices, such as wastewaters and surface waters, making their analysis difficult. Currently, no standardized analytical methods are available for the analysis of organic micropollutants in environmental waters. Owing to the diversity of physico-chemical properties exhibited by the various classes of organic micropollutants, the majority of established analytical methods described in the literature focus on a specific class of compounds, with few methods applicable to multi-class compound analysis. As such, analytical challenges and limitations contribute to the lack of understanding of the effectiveness of drinking water and wastewater treatment processes to remove organic micropollutants. This paper provides a practical overview of current analytical methods that have been developed for the analysis of multiple classes of organic micropollutants from various water matrices and describes the challenges and limitations associated with the development of these methods.


2014 ◽  
Vol 893 ◽  
pp. 500-503 ◽  
Author(s):  
Elnaz Halakoo ◽  
Javid Adabi ◽  
Sara Aalinezhad ◽  
Alireza Layeghi Moghaddam ◽  
Alireza Rahimi

To date, membrane technology is of great concern while conventional processes are not able to fulfill prosperous separation. The presence of EDCs in the environment indicates that conventional treatment plants (CTPs) may have limited capability to remove these compounds. Membrane process such as membrane bioreactors (MBRs), nanofiltration (NF) and reverse osmosis (RO) can produce high quality effluents suitable for reuse applications. Membrane bioreactor (MBR) technology is a promising method for water and wastewater treatment because of its ability to produce high-quality effluent that meets water quality regulations. This paper aimed to provide a review of recent research on feasibility of membrane technology such as MBR, NF and RO and also their application to remove EDCs and PhACs from aqueous solution which are highly harmful and toxic. The major factors which exert influence on the separation of these organic micropollutants have been also studied.


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