Performance of five commercial bipolar membranes under forward and reverse bias conditions for acid-base flow battery applications

2021 ◽  
Vol 640 ◽  
pp. 119748 ◽  
Author(s):  
Emad Al-Dhubhani ◽  
Ragne Pärnamäe ◽  
Jan W. Post ◽  
Michel Saakes ◽  
Michele Tedesco
Processes ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 99 ◽  
Author(s):  
Jiabing Xia ◽  
Gerhart Eigenberger ◽  
Heinrich Strathmann ◽  
Ulrich Nieken

Neutralization of acid and base to produce electricity in the process of reverse electrodialysis with bipolar membranes (REDBP) presents an interesting but until now fairly overlooked flow battery concept. Previously, we presented single-cell experiments, which explain the principle and discuss the potential of this process. In this contribution, we discuss experiments with REDBP stacks at lab scale, consisting of 5 to 20 repeating cell units. They demonstrate that the single-cell results can be extrapolated to respective stacks, although additional losses have to be considered. As in other flow battery stacks, losses by shunt currents through the parallel electrolyte feed/exit lines increases with the number of connected cell units, whereas the relative importance of electrode losses decreases with increasing cell number. Experimental results are presented with 1 mole L−1 acid (HCl) and base (NaOH) for open circuit as well as for charge and discharge with up to 18 mA/cm2 current density. Measures to further increase the efficiency of this novel flow battery concept are discussed.


Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 409
Author(s):  
Ragne Pärnamäe ◽  
Luigi Gurreri ◽  
Jan Post ◽  
Willem Johannes van Egmond ◽  
Andrea Culcasi ◽  
...  

The increasing share of renewables in electric grids nowadays causes a growing daily and seasonal mismatch between electricity generation and demand. In this regard, novel energy storage systems need to be developed, to allow large-scale storage of the excess electricity during low-demand time, and its distribution during peak demand time. Acid–base flow battery (ABFB) is a novel and environmentally friendly technology based on the reversible water dissociation by bipolar membranes, and it stores electricity in the form of chemical energy in acid and base solutions. The technology has already been demonstrated at the laboratory scale, and the experimental testing of the first 1 kW pilot plant is currently ongoing. This work aims to describe the current development and the perspectives of the ABFB technology. In particular, we discuss the main technical challenges related to the development of battery components (membranes, electrolyte solutions, and stack design), as well as simulated scenarios, to demonstrate the technology at the kW–MW scale. Finally, we present an economic analysis for a first 100 kW commercial unit and suggest future directions for further technology scale-up and commercial deployment.


2021 ◽  
pp. 129529
Author(s):  
Maryori C. Díaz-Ramírez ◽  
Maria Blecua-de-Pedro ◽  
Alvaro J. Arnal ◽  
Jan Post

2022 ◽  
Vol 641 ◽  
pp. 119899
Author(s):  
Arturo Ortega ◽  
Luis F. Arenas ◽  
Joep J.H. Pijpers ◽  
Diana L. Vicencio ◽  
Juan C. Martínez ◽  
...  

2020 ◽  
Vol 277 ◽  
pp. 115576 ◽  
Author(s):  
Andrea Culcasi ◽  
Luigi Gurreri ◽  
Andrea Zaffora ◽  
Alessandro Cosenza ◽  
Alessandro Tamburini ◽  
...  

2017 ◽  
Vol 42 (4) ◽  
pp. 1524-1535 ◽  
Author(s):  
W. J. van Egmond ◽  
M. Saakes ◽  
I. Noor ◽  
S. Porada ◽  
C. J. N. Buisman ◽  
...  

2021 ◽  
Vol 13 (11) ◽  
pp. 6089
Author(s):  
Jesús Muñoz-Cruzado-Alba ◽  
Rossano Musca ◽  
Javier Ballestín-Fuertes ◽  
José F. Sanz-Osorio ◽  
David Miguel Rivas-Ascaso ◽  
...  

There are many different types of energy storage systems (ESS) available and the functionality that they can provide is extensive. However, each of these solutions come with their own set of drawbacks. The acid-base flow battery (ABFB) technology aims to provide a route to a cheap, clean and safe ESS by means of providing a new kind of energy storage technology based on reversible dissociation of water via bipolar electrodialysis. First, the main characteristics of the ABFB technology are described briefly to highlight its main advantages and drawbacks and define the most-competitive use-case scenarios in which the technology could be applied, as well as analyze the particular characteristics which must be considered in the process of designing the power converter to be used for the interface with the electrical network. As a result, based on the use-cases defined, the ESS main specifications are going to be identified, pointing out the best power converter configuration alternatives. Finally, an application example is presented, showing an installation in the electrical network of Pantelleria (Italy) where a real pilot-scale prototype has been installed.


ChemSusChem ◽  
2021 ◽  
Author(s):  
Pavel Loktionov ◽  
Anastasia Bocharova ◽  
Dmitry Konev ◽  
Alexander Modestov ◽  
Roman Pichugov ◽  
...  

2018 ◽  
Vol 565 ◽  
pp. 157-168 ◽  
Author(s):  
Jiabing Xia ◽  
Gerhart Eigenberger ◽  
Heinrich Strathmann ◽  
Ulrich Nieken

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