DFT/molecular scale, MD simulation and assessment of the eco-friendly anti-corrosion performance of a novel Schiff base on XC38 Carbon steel in acidic medium

2021 ◽  
pp. 117874
Author(s):  
Chérifa Boulechfar ◽  
Hana Ferkous ◽  
Souad Djellali ◽  
Mohammed A. Amin ◽  
Sihem Boufas ◽  
...  
2019 ◽  
Vol 277 ◽  
pp. 330-340 ◽  
Author(s):  
Chuxin Liang ◽  
Zheng Liu ◽  
Qiuqun Liang ◽  
Guo-Cheng Han ◽  
Jiaxing Han ◽  
...  

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.


2011 ◽  
Vol 53 (5) ◽  
pp. 1680-1689 ◽  
Author(s):  
Ayman M. Atta ◽  
Olfat E. El-Azabawy ◽  
H.S. Ismail ◽  
M.A. Hegazy

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