A study of oxyfluorination of multi-walled carbon nanotubes on mechanical interfacial properties of epoxy matrix nanocomposites

2004 ◽  
Vol 385 (1-2) ◽  
pp. 13-16 ◽  
Author(s):  
Soo-Jin Park ◽  
Hyo-Jin Jeong ◽  
Changwoon Nah
2007 ◽  
Vol 334-335 ◽  
pp. 797-800
Author(s):  
Peng Cheng Ma ◽  
Jang Kyo Kim ◽  
Ben Zhong Tang

This paper presents a method for chemical functionalization of CNTs through the combined process of UV/O3 treatment and silanization process. FT-IR and TEM were employed to characterize the changes in surface functionalities and morphology. The results indicate improved dispersion and attachment of silane molecules on the surface of CNTs. Epoxy matrix nanocomposites containing functionalized CNTs showed much better dispersion with associated higher mechanical properties than those without functionalization. These findings confirmed the improved interfacial interactions due to covalent bonding between the functionalized CNTs and epoxy resin.


2011 ◽  
Vol 13 (2) ◽  
pp. 62-69 ◽  
Author(s):  
Maria Wladyka-Przybylak ◽  
Dorota Wesolek ◽  
Weronika Gieparda ◽  
Anna Boczkowska ◽  
Ewelina Ciecierska

The effect of the surface modification of carbon nanotubes on their dispersion in the epoxy matrix Functionalization of multi-walled carbon nanotubes (MWCNTs) has an effect on the dispersion of MWCNT in the epoxy matrix. Samples based on two kinds of epoxy resin and different weight percentage of MWCNTs (functionalized and non-functionalized) were prepared. Epoxy/carbon nanotubes composites were prepared by different mixing methods (ultrasounds and a combination of ultrasounds and mechanical mixing). CNTs modified with different functional groups were investigated. Surfactants were used to lower the surface tension of the liquid, which enabled easier spreading and reducing the interfacial tension. Solvents were also used to reduce the liquid viscosity. Some of them facilitate homogeneous dispersion of nanotubes in the resin. The properties of epoxy/nanotubes composites strongly depend on a uniform distribution of carbon nanotubes in the epoxy matrix. The type of epoxy resin, solvent, surfactant and mixing method for homogeneous dispersion of CNTs in the epoxy matrix was evaluated. The effect of CNTs functionalization type on their dispersion in the epoxy resins was evaluated on the basis of viscosity and microstructure studies.


2008 ◽  
Vol 450 (1-2) ◽  
pp. 323-326 ◽  
Author(s):  
R. Pérez-Bustamante ◽  
I. Estrada-Guel ◽  
W. Antúnez-Flores ◽  
M. Miki-Yoshida ◽  
P.J. Ferreira ◽  
...  

2002 ◽  
Vol 01 (05n06) ◽  
pp. 719-723 ◽  
Author(s):  
JIN-HONG DU ◽  
ZHE YING ◽  
SHUO BAI ◽  
FENG LI ◽  
CHAO SUN ◽  
...  

Single-walled carbon nanotubes (SWNTs), multiwalled carbon nanotubes (MWNTs) and vapor-grown carbon nanofibers (VGCNFs)/epoxy matrix nanocomposites were prepared, respectively. The microstructure of the nanocomposites was observed by SEM and the resistivities of the nanocomposites with different concentration of CNTs/VGCNFs were measured. Based on the experimental results, the dispersion of SWNTs and MWNTs were relatively poor but that of VGCNFs is uniform within the matrix. The resistivitiy of pure epoxy is about 1010.5Ω · cm and several orders of magnitude higher than those of SWNT, MWNT and VGCNF/epoxy nanocomposites. The resistivities of the nanocomposites drop with the increase of the CNTs/VGCNFs content in the matrix and the resistivity of VGCNFs/epoxy nanocomposites was much lower than that of CNT/epoxy nanocomposites.


Polymer ◽  
2011 ◽  
Vol 52 (9) ◽  
pp. 2070-2074 ◽  
Author(s):  
Long-cheng Tang ◽  
Hui Zhang ◽  
Xiao-ping Wu ◽  
Zhong Zhang

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