Evaluation of flow accelerated corrosion by coupled analysis of corrosion and flow dynamics. Relationship of oxide film thickness, hematite/magnetite ratio, ECP and wall thinning rate

2011 ◽  
Vol 241 (11) ◽  
pp. 4585-4593 ◽  
Author(s):  
Shunsuke Uchida ◽  
Masanori Naitoh ◽  
Hidetoshi Okada ◽  
Yasushi Uehara ◽  
Seiichi Koshizuka
Author(s):  
Yogendra S. Garud

Wall thinning in pressure retaining components, especially due to the flow-accelerated corrosion, has been a significant factor affecting the safety and unplanned system downtimes. On the other hand, overestimating the impact of possible wall thinning often leads to unnecessary or expensive inspections and replacements. The simplified or quick (short-cut) methods of analysis and prediction often lack the requisite degree of accuracy and confidence. This paper presents a few techniques for better analysis of the wall thinning data to address these issues. These techniques make use of the statistical methods, pattern recognition, and optimization to perform a robust data filtering and thinning rate estimation that accounts for measurement uncertainty. The techniques are discussed with application to a large database and an inspection program. The impact of these analytical improvements is presented in comparison with results of the simplified method of analysis. The results include both the margin on remaining life and the projected wall thinning rates, with implications for inspections.


Author(s):  
Masanori Naitoh ◽  
Shunsuke Uchida ◽  
Yasushi Uehara ◽  
Hidetoshi Okada ◽  
Seiichi Koshizuka

Systematic approaches for evaluating flow accelerated corrosion (FAC) are desired before discussing application of countermeasures for FAC. Future FAC occurrence should be evaluated to identify locations where a higher possibility of FAC occurrence exists, and then, wall thinning rate at the identified FAC occurrence zone should be evaluated to obtain the preparation time for applying countermeasures. Wall thinning rates were calculated with the coupled models of static electrochemical analysis and dynamic double oxide layer analysis. Anodic current density and electrochemical corrosion potential (ECP) were calculated with the electrochemistry model based on an Evans diagram and ferrous ion release rate determined by the anodic current density was applied as input for the double oxide layer model. The thickness of oxide layer was calculated with the double oxide layer model. The dependences of mass transfer coefficients, oxygen concentrations ([O2]), pH and temperature on wall thinning rates were calculated with the coupled model. It was confirmed that the calculated results of the coupled models resulted good agreement with the measured ones. The effects of candidates for countermeasures, e.g., optimization of N2H4 injection point into the feed water system, on FAC mitigation was demonstrated as a result of applying the model.


Author(s):  
Yuyun Zeng ◽  
Jingquan Liu ◽  
Weilin Huang

Flow accelerated corrosion (FAC) is a major degradation form of carbon steel and low alloy pipes in the secondary circuit of pressurized water reactor (PWR) plants, which has great impact on plant safety and reliability. For the purpose of effectively monitoring FAC in nuclear power plants, a statistical model for accessing FAC wall thinning rate using plant inspection data is proposed in this paper. The presented model is developed based on Gaussian stochastic process models. Wall thinning rate is considered as a function of key factors that have important influence on the FAC process (i.e., temperature, pH, mass transfer coefficient, etc.). The Kriging method, which has been widely applied in the domain of spatial analysis, is used to model the relationship between wall thinning rate and its impact factors. Model parameters are determined through maximum likelihood estimation using the inspection data. Since the likelihood function of the Kriging model is usually complicated in form, the genetic algorithm is employed to find parameter values that maximize this function. From the presented model, residual lifetime distributions of pipes affected by FAC can be derived, and conditions that may lead to high FAC rate can be found, which provides decision-making support for maintenance strategies optimization in life cycle management of the feed water system. Wall thinning data simulated from a physical-chemical mechanism model presented in literature are used to verify the presented model. Results of validation show that reasonable wall thinning rates and lifetime distributions can be obtained using this model.


2021 ◽  
Vol 118 (21) ◽  
pp. 212101
Author(s):  
Alena Nikolskaya ◽  
Alexey Belov ◽  
Alexey Mikhaylov ◽  
Anton Konakov ◽  
David Tetelbaum ◽  
...  

1991 ◽  
Vol 226 ◽  
Author(s):  
Hideo Miura ◽  
Hiroshi Sakata ◽  
Shinji Sakata Merl

AbstractThe residual stress in silicon substrates after local thermal oxidation is discussed experimentally using microscopic Raman spectroscopy. The stress distribution in the silicon substrate is determined by three main factors: volume expansion of newly grown silicon–dioxide, deflection of the silicon–nitride film used as an oxidation barrier, and mismatch in thermal expansion coefficients between silicon and silicon dioxide.Tensile stress increases with the increase of oxide film thickness near the surface of the silicon substrate under the oxide film without nitride film on it. The tensile stress is sometimes more than 100 MPa. On the other hand, a complicated stress change is observed near the surface of the silicon substrate under the nitride film. The tensile stress increases initially, as it does in the area without nitride film on it. However, it decreases with the increase of oxide film thickness, then the compressive stress increases in the area up to 170 MPa. This stress change is explained by considering the drastic structural change of the oxide film under the nitride film edge during oxidation.


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