Selective oxidation of organosulfurs with a sandwich-type polyoxometalate/hydrogen peroxide system

Polyhedron ◽  
2020 ◽  
Vol 186 ◽  
pp. 114622
Author(s):  
Hadi Naslhajian ◽  
Mojtaba Amini ◽  
Mohammad Amin Dastyar ◽  
Arshad Bayrami ◽  
Mojtaba Bagherzadeh ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Sandwich Type

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Janus amphiphilic carbon nanotubes as Pickering interfacial catalysts for the treatment of oily wastewater by selective oxidation with hydrogen peroxide

2020 ◽  
Vol 356 ◽  
pp. 205-215 ◽  
Author(s):  
Jose L. Diaz de Tuesta ◽  
Bruno F. Machado ◽  
Philippe Serp ◽  
Adrián M. T. Silva ◽  
Joaquim L. Faria ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Oily Wastewater

Selective Oxidation of Sulfides to Sulfoxides/Sulfones by 30% Hydrogen Peroxide

2012 ◽  
Vol 187 (7) ◽  
pp. 822-830 ◽  
Author(s):  
Ying He ◽  
Xiaoyun Ma ◽  
Hai Feng Ji ◽  
Xin Bing Zha ◽  
Hongliang Jiang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Oxidation Of Sulfides

scholarly journals Selective Oxidation Reactions of Natural Compounds with Hydrogen Peroxide Mediated by Methyltrioxorhenium

Molecules ◽  
2013 ◽  
Vol 18 (11) ◽  
pp. 13754-13768 ◽  
Author(s):  
Maria Amato ◽  
Francesco Ballistreri ◽  
Andrea Pappalardo ◽  
Gaetano Tomaselli ◽  
Rosa Toscano ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Natural Compounds ◽  
Oxidation Reactions ◽  
Selective Oxidation Reactions

Highly Selective Oxidation of Cinnamaldehyde to Benzaldehyde by Hydrogen Peroxide in Mild Conditions

2014 ◽  
Vol 522-524 ◽  
pp. 458-464
Author(s):  
Yuan Mei Nie ◽  
Yong Peng An ◽  
Cai Hua Peng ◽  
Xing Dong Yao
Keyword(s):  
Hydrogen Peroxide ◽  
Hydrogen Bond ◽  
Sodium Bicarbonate ◽  
Propylene Glycol ◽  
Selective Oxidation ◽  
High Selectivity ◽  
Protic Solvent ◽  
Hydrogen Bond Interaction ◽  
Mild Conditions ◽  
Effect Of Solvent

Benzaldehyde was produced from oxidation of cinnamaldehyde by hydrogen peroxide in propylene glycol in the presence of sodium bicarbonate. Protic solvent demonstrated high selectivity and the yield of benzaldehyde could reach up to 82% in propylene glycol. The effect of solvent on the selectivity was attributed to hydrogen bond interaction between the oxidation intermediate epoxide and the solvent.

Heterogeneous epoxidation of alkenes with H2O2 catalyzed by a recyclable organic–inorganic polyoxometalate-based framework catalyst

2015 ◽  
Vol 39 (12) ◽  
pp. 9879-9885 ◽  
Author(s):  
Hedayat Haddadi ◽  
Shahrbanou Moradpour Hafshejani ◽  
Mostafa Riahi Farsani ◽  
Ali Kazemi Babahydari
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Stable Catalyst ◽  
Epoxidation Of Alkenes

PW-MOF as an efficient, recyclable and stable catalyst for the selective oxidation of alkenes with hydrogen peroxide.

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