Shellac derived graphene films on solid, flexible, and porous substrates for high performance bipolar plates and supercapacitor electrodes

2022 ◽  
Vol 181 ◽  
pp. 1008-1022
Author(s):  
Ram Sevak Singh ◽  
Maurice Jansen ◽  
Dipsikha Ganguly ◽  
Giridhar U. Kulkarni ◽  
Sundara Ramaprabhu ◽  
...  
Coatings ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 437
Author(s):  
Yi Liu ◽  
Luofu Min ◽  
Wen Zhang ◽  
Yuxin Wang

In this article, we proposed a facile method to electrophoretically deposit a highly conductive and corrosion-resistant graphene layer on metal bipolar plates (BPs) while avoiding the oxidation of the metal substrate during the electrophoretic deposition (EPD). p-Phenylenediamine (PPD) was first grafted onto negatively charged graphene oxide (GO) to obtain modified graphene oxide (MGO) while bearing positive charges. Then, MGO dispersed in ethanol was coated on titanium plates via cathodic EPD under a constant voltage, followed by reducing the deposited MGO with H2 at 400 °C, gaining a titanium plate coated with reduced MGO (RMGO@Ti). Under the simulated environment of proton exchange membrane fuel cells (PEMFCs), RMGO@Ti presents a corrosion current of < 10−6 A·cm−2, approximately two orders of magnitude lower than that of bare titanium. Furthermore, the interfacial contact resistance (ICR) of RMGO@Ti is as low as 4 mΩ·cm2, which is about one-thirtieth that of bare titanium. Therefore, RMGO@Ti appears very promising for use as BP in PEMFCs.


2021 ◽  
Author(s):  
Enaganti Prasanth Kumar ◽  
Venkatarao Selamneni ◽  
Parikshit Sahatiya ◽  
Sanket Goel

The effective incorporation of novel and highly conductive hybrid functional nanomaterials onto flexible and porous substrates are extremely desirable to develop flexible supercapacitors. Even though there are reports on the...


2018 ◽  
Vol 43 (48) ◽  
pp. 21918-21927 ◽  
Author(s):  
Moon Hee Lee ◽  
Ho Young Kim ◽  
Seong Moon Oh ◽  
Byung Choon Kim ◽  
Daesuk Bang ◽  
...  

2018 ◽  
Vol 35 (2) ◽  
pp. 181-202 ◽  
Author(s):  
Ayesha Kausar

Corrosion is a serious problem for implementing metallic components and devices in industrial zones. Considerable effort has been made to develop corrosion prevention strategies. Initially, paints, pigments, and organic coatings have been applied to prevent metal corrosion. Consequently, conjugated polymers, epoxy resin, phenolics, acrylic polymers, and many thermoplastics as well as thermoset resins have been used to inhibit corrosion. Lately, nanofillers such as fullerene, nanodiamond, graphene, graphene oxide, carbon nanotube, carbon black, nanoclay, and inorganic nanoparticle have been introduced in polymeric matrices to harness valuable corrosion protection properties of the nanocomposite. Corrosion protection performance of a nanocomposite depends on nanofiller dispersion, physical and covalent interaction between matrix/nanofiller and nanofiller adhesion to the substrate. Moreover, a high performance anti-corrosion nanocomposite must have good barrier properties, and high scratch, impact, abrasion, and chemical resistance. Thus, polymeric nanocomposites have been found to prevent corrosion in aerospace and aircraft structural parts, electronic components, bipolar plates in fuel cells, and biomedical devices and systems. However, numerous challenges need to be addressed in this field to attain superior corrosion resistant nanocomposites. Future research on polymer nanocomposites has the potential to resolve the current challenges of metal corrosion through entire replacement of metal-based materials with advanced nanomaterials.


2018 ◽  
Vol 2 (12) ◽  
pp. 2313-2319 ◽  
Author(s):  
Muhammad Salman ◽  
Xingyuan Chu ◽  
Tieqi Huang ◽  
Shengying Cai ◽  
Qiuyan Yang ◽  
...  

Aminophenol isomer functionalized graphene film electrodes are fabricated with wet-spinning technology for high performance supercapacitors.


ACS Nano ◽  
2011 ◽  
Vol 5 (9) ◽  
pp. 7686-7686 ◽  
Author(s):  
Yu Zhu ◽  
Zhengzong Sun ◽  
Zheng Yan ◽  
Zhong Jin ◽  
James M. Tour

The Analyst ◽  
2016 ◽  
Vol 141 (15) ◽  
pp. 4725-4732 ◽  
Author(s):  
Fei Xing ◽  
Shan Zhang ◽  
Yong Yang ◽  
Wenshuai Jiang ◽  
Zhibo Liu ◽  
...  

Various graphene-based gas sensors that operate based on the electrical properties of graphene have been developed for accurate detection of gas components.


2019 ◽  
Vol 158 ◽  
pp. 1980-1985
Author(s):  
Wenbin Hao ◽  
Hongyan Ma ◽  
Guoxing Sun ◽  
Zongjin Li

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Myungsoo Kim ◽  
Gu-Hyeok Kang ◽  
Hyung Wook Park ◽  
Young-Bin Park ◽  
Yeon Ho Park ◽  
...  

We report a study on manufacturing and characterization of a platform material for high-performance lightweight bipolar plates for fuel cells based on nanocomposites consisting of carbon nanotubes (CNTs) and exfoliated graphite nanoplatelets (xGnPs). The experiments were designed and performed in three steps. In the preexperimental stage, xGnP-epoxy composite samples were prepared at various xGnP weight percentages to determine the maximum processable nanofiller concentration. The main part of the experiment employed the statistics-based design of experiments (DOE) methodology to identify improved processing conditions and CNT : xGnP ratio for minimized electrical resistivity. In the postexperimental stage, optimized combinations of material and processing parameters were investigated. With the aid of a reactive diluent, 20 wt.% was determined to the be maximum processable carbon nanomaterial content in the epoxy. The DOE analyses revealed that the CNT : xGnP ratio is the most dominant factor that governs the electrical properties, and its implications in relation to CNT-xGnP interactions and microstructure are elucidated. In addition, samples fabricated near the optimized condition revealed that there exists an optimal CNT : xGnP ratio at which the electrical performance can be maximized. The electrical and mechanical properties of optimal samples suggest that CNT-xGnP hybrid nanocomposites can serve as an alternative material platform for affordable, lightweight bipolar plates.


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