Hydrothermal carbonization for energy-efficient processing of sewage sludge: A review

2019 ◽  
Vol 108 ◽  
pp. 423-440 ◽  
Author(s):  
Liping Wang ◽  
Yuzhi Chang ◽  
Aimin Li
Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1346
Author(s):  
Philipp Knötig ◽  
Hendrik Etzold ◽  
Benjamin Wirth

This research paper evaluates hydrothermal carbonization (HTC) as a possible treatment for sewage sludge, including phosphorus recycling. German governmental requirements force a high number of wastewater treatment plants (WWTP) to recover phosphorus from sewage sludge above limits of 20 g kgTS−1 before further disposal (e.g., co-incineration). The results show that pH reduction has a positive effect on shifting phosphorus to the liquid phase during HTC. Although the experimental results of this research do not yet achieve the necessary phosphorus reduction, various calculations are made to achieve this goal in future experimental studies. In order to be able to assess the energy benefits of HTC, Aspen Plus modeling was used to show the positive impact of implementing this technology in a WWTP. It is shown that the mechanical dewaterability of sewage sludge (SS) increases after HTC enabling energy savings by means of subsequent thermal drying. A heat optimized HTC is able to cut energy expenses by half, further providing a phosphorus-depleted hydrochar for extensive energetic use.


Energies ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2697
Author(s):  
Gabriel Gerner ◽  
Luca Meyer ◽  
Rahel Wanner ◽  
Thomas Keller ◽  
Rolf Krebs

Phosphorus recovery from waste biomass is becoming increasingly important, given that phosphorus is an exhaustible non-renewable resource. For the recovery of plant nutrients and production of climate-neutral fuel from wet waste streams, hydrothermal carbonization (HTC) has been suggested as a promising technology. In this study, digested sewage sludge (DSS) was used as waste material for phosphorus and nitrogen recovery. HTC was conducted at 200 °C for 4 h, followed by phosphorus stripping (PS) or leaching (PL) at room temperature. The results showed that for PS and PL around 84% and 71% of phosphorus, as well as 53% and 54% of nitrogen, respectively, could be recovered in the liquid phase (process water and/or extract). Heavy metals were mainly transferred to the hydrochar and only <1 ppm of Cd and 21–43 ppm of Zn were found to be in the liquid phase of the acid treatments. According to the economic feasibility calculation, the HTC-treatment per dry ton DSS with an industrial-scale plant would cost around 608 USD. Between 349–406 kg of sulfuric acid are required per dry ton DSS to achieve a high yield in phosphorus recovery, which causes additional costs of 96–118 USD. Compared to current sewage sludge treatment costs in Switzerland, which range between 669 USD and 1173 USD, HTC can be an economically feasible process for DSS treatment and nutrient recovery.


2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
H. P. Li

Energy-efficient processing of TiB compound with nanowhiskers by micropyretic synthesis is investigated in this paper. Micropyretic synthesis not only offers shorter processing time but also excludes the requirement for high-temperature sintering and it is considered as the one of the novel energy-saving processing techniques. Experimental study and numerical simulation are both carried out to investigate the correlation of the processing parameters on the microstructures of the micropyretically synthesized products. The diffusion-controlled reaction mechanism is proposed in this study. It is noted that nanosize TiB whiskers only occurred when the combustion temperature is lower than the melting point of TiB but higher than the extinguished temperature. The results generated in the numerical calculation can be used as a helpful reference to select the proper route of processing nanosize materials. The Arrhenius-type plot of size and temperature is used to calculate the activation energy of TiB reaction. In addition to verifying the accuracy of the experimental measures, the reaction temperature for producing the micropyretically synthesized products with nanofeatures can be predicted.


2019 ◽  
Vol 120 ◽  
pp. 166-175 ◽  
Author(s):  
Małgorzata Wilk ◽  
Aneta Magdziarz ◽  
Kandasamy Jayaraman ◽  
Monika Szymańska-Chargot ◽  
Iskender Gökalp

Energies ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 1582 ◽  
Author(s):  
Heiner Brookman ◽  
Fabian Gievers ◽  
Volker Zelinski ◽  
Jan Ohlert ◽  
Achim Loewen

In many areas of application, the influence of hydrothermal carbonization (HTC) on the composition of organic pollutants is still unexplored. In this study, sewage sludge (SS) was carbonized and the input as well as the hydrochar were examined for the organic pollutants: polychlorinated biphenyls (PCB), polychlorinated dibenzo-dioxins (PCDDs), and polychlorinated dibenzo-furans (PCDFs). The process temperatures of carbonization were 200 °C, 220 °C, and 240 °C and the holding time was 5 h for all tests. The total concentration of PCBs was relatively stable for all temperatures, whereas the toxicity equivalent (WHO-TEQ) at 200 °C and 220 °C increases compared to the input material. The strongest impact on toxicity was observed for PCDDs where concentrations were reduced for higher temperatures, whereas the toxicity increases by more than 16 times for temperatures of 240 °C. The concentrations and toxicity of PCDFs were reduced for all carbonization temperatures. In hydrochar from HTC at 240 °C, the limit values for the application of SS in German agriculture have been exceeded. The results indicate that the process conditions for HTC should be controlled also for SS with average contamination if the hydrochar is to be used as material, especially in agriculture.


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