Controllable luminescence and efficient energy transfer investigation of a novel white light emission phosphor Ca19Na2Mg(PO4)14: Dy3+, Tm3+ with high thermal stability

Author(s):  
Heng Dai ◽  
Zhuowei Li ◽  
Miao Gao ◽  
Yuehui Yan ◽  
Chuang Wang ◽  
...  
2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Libing Liao ◽  
Jie Fu ◽  
Dan Yang

Abstract What ideal w-LED phosphors always aim to do is to achieve a single phase near-sunlight emission phosphor simultaneously with both high luminescence efficiency and high thermal stability at operation temperature. And It is well known that apatite compound phosphors are one of the most promising optical materials to realize those above because of their unique structure enhanced luminescence properties and thermal stability. Here, we synthesized a co-doped single phase apatite phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ (CLSO:Dy3+/Sm3+) for white light emission, which was provided with excellent thermal stability and of which luminescence intensity at 150 °C still was 92 percentage of that at room temperature. Moreover, X-ray diffraction technique, Fourier transform infrared spectroscopy, scanning electron microscope were employed to characterization of phase structure and morphology, and consequently pure apatite structure and gravel-like morphology of phosphors were proved. Analysis of photoluminescence spectra indicated that concentration quenching effect exist in single-doped CLSO:Dy3+ phosphors owing to dipole-dipole interaction between Dy3+ ions. It is revealed that maybe exist Dy3+ ↔ Sm3+ bilateral non-radiative energy transfer processes in Dy3+/Sm3+ co-doped CLSO system by PL spectra and decay curves. And variation of Sm3+ ion concentration can control color emission, namely CIE chromaticity coordinates and correlated color temperature, finally to achieve white light emission (0.309,0.309) with CCT 6848 K, able to be a potential candidate for commercial lighting applications.


2018 ◽  
Vol 47 (35) ◽  
pp. 12228-12242 ◽  
Author(s):  
Karamjyoti Panigrahi ◽  
Subhajit Saha ◽  
Sumanta Sain ◽  
Rituparna Chatterjee ◽  
Antika Das ◽  
...  

An efficient energy transfer from Dy3+ to Eu3+ in MgAl2O4 offers white light emission and self-referencing thermal behaviour.


2018 ◽  
Vol 47 (19) ◽  
pp. 6860-6867 ◽  
Author(s):  
Chao Li ◽  
Hongwei Zheng ◽  
Hengwei Wei ◽  
Shijie Qiu ◽  
Ling Xu ◽  
...  

Achieving tunable color and white light emission in a single phase phosphor is a challenging issue.


2019 ◽  
Vol 7 (10) ◽  
pp. 2927-2935 ◽  
Author(s):  
Mao Xia ◽  
Xianbo Wu ◽  
Yuan Zhong ◽  
H. T. (Bert) Hintzen ◽  
Zhi Zhou ◽  
...  

Energy transfer from Tb3+ to Eu3+ was observed and verified in a warm white light emission phosphor SZYP:Tb3+,Eu3+ with high thermal stability.


2020 ◽  
Vol 124 (6) ◽  
pp. 3857-3866 ◽  
Author(s):  
G. Saavedra-Rodriguez ◽  
U. Pal ◽  
R. Sánchez-Zeferino ◽  
M. E. Álvarez-Ramos

2015 ◽  
Vol 17 (48) ◽  
pp. 32297-32303 ◽  
Author(s):  
Xinhua Cao ◽  
Haichuang Lan ◽  
Zhenhua Li ◽  
Yueyuan Mao ◽  
Liming Chen ◽  
...  

A two-component light-harvesting organogel containing a naphthalimide-based gelator as a donor and a phosphorescent Ir(iii) complex as an acceptor was used to produce white-light-emitting organogels.


2018 ◽  
Vol 5 (11) ◽  
pp. 2868-2874 ◽  
Author(s):  
Yu-Pei Xia ◽  
Chen-Xue Wang ◽  
Lian-Cai An ◽  
Da-Shuai Zhang ◽  
Tong-Liang Hu ◽  
...  

By introducing dyes into a MOF, a white-light-emitting luminophor was obtained based on effective framework to dye energy transfer mechanism.


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