Degradation of diatrizoate in a pin-to-liquid plasma reactor, its transformation products and their residual toxicity

The biodegradation of a mixture of four pharmaceutical and personal care products (PPCPs) (benzophenone (BP), benzophenone-3 (BP-3), caffeine (CF) and carbamazepine (CBZ)) was studied in a laboratory test filter. The column was filled with inert material to exclude the adsorption processes and to enable the development of the biofilm, while river water was recirculated. High removal for BP, BP-3 and CF was observed from the beginning of the experiment at the initial concentration of 20 ?g L-1 (90?99 %). In the case of CBZ analytical difficulties were experienced. The efficacy of biodegradation reflected as a change of the overall toxicity of initial mixture of selected PPCPs vs. toxicity of samples which were undergone different biodegradation phases was assessed with two standard laboratory tests with apical endpoint ? acute toxicity test with Daphnia magna (immobilisation) and bioluminescence inhibition with Vibrio fisheri. Toxicity tests showed the substantial reduction of the overall mixture toxicity in a laboratory test filter. The residual toxicity to D. magna might be attributed to undetected transformation products.

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pH-dependent transformation products and residual toxicity evaluation of sulfamethoxazole degradation through non-radical oxygen species involved process

Chemical Engineering Journal ◽

10.1016/j.cej.2020.124512 ◽

2020 ◽

Vol 390 ◽

pp. 124512 ◽

Cited By ~ 6

Author(s):

Jia Wang ◽

Qing Gong ◽

Jawad Ali ◽

Min Shen ◽

Jiayi Cai ◽

...

Keyword(s):

Transformation Products ◽

Oxygen Species ◽

Toxicity Evaluation ◽

Radical Oxygen Species ◽

Residual Toxicity ◽

Ph Dependent

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Granular bainite or granular ferrite? A preliminary TEM investigation of an HSLA-100 steel

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100087239 ◽

1991 ◽

Vol 49 ◽

pp. 584-585

Author(s):

R. Varughese ◽

S. W. Thompson ◽

P. R. Howell

Keyword(s):

Room Temperature ◽

Transformation Products ◽

Accurate Description ◽

Granular Bainite ◽

Preliminary Results ◽

The Past ◽

Light Micrograph ◽

Multiphase Reaction ◽

Detailed Nature

Ever since Habraken and Economopoulos first employed the term granular bainite to classify certain unconventional transformation products in continuously cooled steels, the term has been widely accepted and used, despite the lack of a clear consensus as to the detailed nature of the transformation products which constitute granular bainite. This paper presents the preliminary results of a TEM investigation of an 0.04 wt% C, copper-containing steel (designated HSLA-100). It is suggested that the term granular ferrite rather than granular bainite is a more accurate description of this multiphase reaction product.Figure 1 is a light micrograph of a sample which had been air-cooled from 900°C to room temperature. The microstructure is typical of that which has been termed granular bainite in the past and appears to consist of equiaxed ferritic grains together with other minor transformation products. In order to examine these structures in more detail, both continuously cooled and isothermally transformed and quenched materials have been examined with TEM. Granular bainite has been found in virtually all samples.

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