Al substitution effect on magnetic properties of magnetocaloric material HoB2

2022 ◽  
Vol 342 ◽  
pp. 114616
Author(s):  
Suguru Iwasaki ◽  
Takafumi D. Yamamoto ◽  
Pedro Baptista de Castro ◽  
Kensei Terashima ◽  
Hiroyuki Takeya ◽  
...  
2003 ◽  
Vol 171 (1-2) ◽  
pp. 339-344 ◽  
Author(s):  
H. Samata ◽  
R. Kasai ◽  
T. Taniguchi ◽  
Y. Nagata

2011 ◽  
Vol 399-401 ◽  
pp. 992-996
Author(s):  
Yi Hu ◽  
Shan Dong Li ◽  
Mei Mei Liu ◽  
Jian Peng Wu ◽  
Xin Le Cai ◽  
...  

The influence of Al doping on the magnetic properties and magnetic entropy changes (ΔSM) of the La0.8-xAlxCe0.2Fe11.4Si1.6(x = 0-0.2) compounds have been investigated around their Curie temperature TC. The incorporation of Al atoms is unfavorable for the formation of the NaZn13-type phase, however, it increases the TCby ~40 K, effectively decreases the magnetic hysteresis loss, and broadens the ΔSM-T curve at expense of the (ΔSM)maxof the compounds. It is also revealed that Al doping content of x = 0.06 is an important composition knee point where the doped Al start to occupy the site of Rare-earth elements, leading to a turning point for the lattice constant, TC, and magnetic transition type.


1990 ◽  
Vol 67 (9) ◽  
pp. 4638-4640 ◽  
Author(s):  
H. Ido ◽  
K. Konno ◽  
S. F. Cheng ◽  
W. E. Wallace ◽  
S. G. Sankar

2005 ◽  
Vol 359-361 ◽  
pp. 187-189 ◽  
Author(s):  
Gaku Motoyama ◽  
Suguru Yamamoto ◽  
Yasukage Oda ◽  
Koh-ichi Ueda ◽  
Takao Kohara

2013 ◽  
Vol 27 (15) ◽  
pp. 1362006 ◽  
Author(s):  
SAN-LIN YOUNG ◽  
HONE-ZERN CHEN ◽  
MING-CHENG KAO ◽  
CHUNG-YUAN KUNG ◽  
CHEN-CHENG LIN ◽  
...  

La -doped and Cu -doped ZnO nanowires have been prepared to compare the substitution effect on the microstructural and magnetic properties. The XRD patterns of both compositions with single diffraction peak (002) show the same wurtzite hexagonal structure. The growth rate of the ZnO nanowires were enhanced by Cu doping, which were different from the suppression of growth rate by La doping. Room temperature ferromagnetism is observed for all ZnO , Cu -doped ZnO and La -doped ZnO nanowires. The saturation magnetizations are 0.102, 0.232 and 0.04 emu/g for ZnO , Cu -doped ZnO and La -doped ZnO nanowires, respectively. The results showed that the ferromagnetism is restrained by Cu doping, but enhanced by the La doping.


Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2301
Author(s):  
Akihiro Tsuruta ◽  
Shuji Kawasaki ◽  
Masashi Mikami ◽  
Yoshiaki Kinemuchi ◽  
Yoshitake Masuda ◽  
...  

We investigated the Co substitution effect for the magnetic properties in room-temperature ferromagnetic oxide Sr3.1Y0.9Co4O10.5. The substituted element (Al and Ga) and low-spin state Co3+, which was changed from a high-spin or intermediate-spin state by Al or Ga substitution, reduced the Curie temperature to even 1.5 times lower than the temperature estimated from a simple dilution effect. Al3+ preferentially substituted for intermediate-spin-state Co3+ in the ferrimagnetic CoO6 layer and deteriorated the saturation magnetization of Sr3.1Y0.9Co4O10.5. By contrast, Ga3+ substituted for high-spin-state Co3+ in the CoO6 layer and/or the antiferromagnetic CoO4.25 layer and enhanced the saturation magnetization per Co ion. These results indicate that the magnetic properties of Sr3.1Y0.9Co4O10.5 can be controlled by selectively substituting for Co3+ with different spin states.


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