Lithiation of optically active oxazolinyloxiranes: configurational stability

Tetrahedron ◽  
2003 ◽  
Vol 59 (49) ◽  
pp. 9707-9712 ◽  
Author(s):  
Renzo Luisi ◽  
Vito Capriati ◽  
Claudia Carlucci ◽  
Leonardo Degennaro ◽  
Saverio Florio
1988 ◽  
Vol 61 (10) ◽  
pp. 3761-3763 ◽  
Author(s):  
Toshio Shimizu ◽  
Michio Kobayashi ◽  
Nobumasa Kamigata

2000 ◽  
Vol 611 (1-2) ◽  
pp. 20-25 ◽  
Author(s):  
Masakatsu Omote ◽  
Tetsushi Tokita ◽  
Yasutaka Shimizu ◽  
Ichiro Imae ◽  
Eiji Shirakawa ◽  
...  

ChemInform ◽  
2001 ◽  
Vol 32 (2) ◽  
pp. no-no
Author(s):  
Masakatsu Omote ◽  
Tetsushi Tokita ◽  
Yasutaka Shimizu ◽  
Ichiro Imae ◽  
Eiji Shirakawa ◽  
...  

2021 ◽  
Author(s):  
Takumi Furuta ◽  
Takuya Murai ◽  
Yongning Xing ◽  
Mayu Kurokawa ◽  
Toshifumi Kuribayashi ◽  
...  

A one-pot transformation of biaryl dicarboxylic acids to (NH)-phenanthridinone derivatives based on a Curtius rearrangement and subsequent basic hydrolysis was developed. This method is also applicable for the preparation of optically active amide-functionalized [7]helicene-like molecules. Furthermore, aza[5]helicene derivatives with a phosphate moiety were isolated as a product of the Curtius rearrangement step in the case of substrates that bear chalcogen atoms. The stereostructures of these products, revealed by X-ray diffraction analysis, suggested that chalcogen-bonding and pnictogen-bonding interactions might contribute to their stabilization. The configurational stability of the helicene-like molecules and their chiroptical properties were further investigated.


TAPPI Journal ◽  
2012 ◽  
Vol 11 (8) ◽  
pp. 51-58
Author(s):  
ANTTI HAAPALA ◽  
MIKA KÖRKKÖ ◽  
ELISA KOIVURANTA ◽  
JOUKO NIINIMÄKI

Analysis methods developed specifically to determine the presence of ink and other optically active components in paper machine white waters or other process effluents are not available. It is generally more interest¬ing to quantify the effect of circulation water contaminants on end products. This study compares optical techniques to quantify the dirt in process water by two methods for test media preparation and measurement: direct process water filtration on a membrane foil and low-grammage sheet formation. The results show that ink content values obtained from various analyses cannot be directly compared because of fundamental issues involving test media preparation and the varied methodologies used to formulate the results, which may be based on different sets of assumptions. The use of brightness, luminosity, and reflectance and the role of scattering measurements as a part of ink content analysis are discussed, along with fine materials retention and measurement media selection. The study concludes with practical tips for case-dependent measurement methodology selection.


2003 ◽  
Vol 770 ◽  
Author(s):  
H. Przybylinska ◽  
N. Q. Vinh ◽  
B.A. Andreev ◽  
Z. F. Krasil'nik ◽  
T. Gregorkiewicz

AbstractA successful observation and analysis of the Zeeman effect on the near 1.54 μm photoluminescence spectrum in Er-doped crystalline MBE-grown silicon are reported. A clearly resolved splitting of 5 major spectral components was observed in magnetic fields up to 5.5 T. Based on the analysis of the data the symmetry of the dominant optically active center was conclusively established as orthorhombic I (C2v), with g‼≈18.4 and g⊥≈0 in the ground state. The fact that g⊥≈0 explains why EPR detection of Er-related optically active centers in silicon may be difficult. Preferential generation of a single type of an optically active Er-related center in MBE growth confirmed in this study is essential for photonic applications of Si:Er.


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