Fabrication and characterization of polymer/nanoclay hybrid ultrathin multilayer film by spin self-assembly method

2004 ◽  
Vol 458 (1-2) ◽  
pp. 9-14 ◽  
Author(s):  
Ho-Chul Lee ◽  
Tae-Woo Lee ◽  
Tae-Ho Kim ◽  
O.Ok Park
2011 ◽  
Vol 66 (1) ◽  
pp. 43-48
Author(s):  
Changyun Chen ◽  
Jun Peng ◽  
Yan Shen ◽  
Dan Chen ◽  
Huanqiu Zhang ◽  
...  

A luminescent multilayer film has been fabricated from the polyoxometalate anion α- [PMo12O40]3− (α-PMo12) and the cation Fuchsin Basic (FB) through an electrostatic layer-by-layer (LbL) self-assembly method and characterized by UV/Vis spectra, atomic force microscopy and X-ray photoelectron spectra. The fluorescence properties of the LbL film have also been investigated. Cyclic voltammetry measurements have demonstrated that the electrochemical properties of the polyoxometalate and FB are maintained in the multilayer film, which exhibits electrocatalytic activity for the reduction of bromate


2004 ◽  
Vol 13 (03n04) ◽  
pp. 581-586
Author(s):  
TAE-HO KIM ◽  
O OK PARK

Multilayer nanostructural thin films through a layer-by-layer spin self-assembly method were prepared using poly(p-phenylene vinylene)/montmorillonite. Sodium montmorillonite particles exfoliated into single sheets and cationic PPV precursor and such anionic MMT plates were spin self-assembled by electrostatic attraction. Self-assembled MMT layers blocked the penetration of oxygen and moisture and they reduced the photo-oxidation of the emitting material. Spin self-assembled films showed higher environmental stability and luminescence, and their PL spectra were somewhat different from that of bulk PPV films.


2007 ◽  
Vol 336-338 ◽  
pp. 2235-2237
Author(s):  
Hui Yuan Ma ◽  
Jun Peng ◽  
Fu Ping Wang ◽  
Bao Xia Dong

A novel nanosized multilayer film containing polyoxometalate anion with a pendant supportligand α-[SiW11O39Co(H3P2O7)]7- (abbr. SiW11Co-P2O7) and poly(diallyldimethyl ammonium chloride (PDDA) was fabricated by layer-by-layer self-assembly. The multilayer film was characterized by XPS, UV-vis, AFM and ESR. The mean interface roughness was about 2.0 nm, calculated from an area of 0.5 × 0.5 μm2. The electrochemical property was studied by the cyclic voltammetry, the results indicating that the self-assembly film exhibited favorable electrochemical behavior of polyoxometalate.


2013 ◽  
Vol 401-403 ◽  
pp. 663-666
Author(s):  
Xue Lian Bai ◽  
Jian Ting Mei ◽  
Zhong Guo Mu ◽  
Yun Bai

Polyaniline (PANI) nanotubes were synthesized separately using amino acetic acid (AA), ethylenediamine tetraacetic acid (EDTA), oxalic acid (OA) as dopant and ammonium persulfate (APS) as oxidant by a self-assembly method. SEM, TEM,FTIR and X-ray diffraction (XRD) and applying the 4 probes method characterized the morphology, structure and property of the product. It was found that nanotubes morphology were synthesized when the [Aci/[A ratio is 1:2.The room template conductivity of the products were studied.


2019 ◽  
Vol 114 ◽  
pp. 68-73
Author(s):  
Yuanting Wu ◽  
Jun Yuan ◽  
Menglong Li ◽  
Changqing Liu ◽  
Penghong Wu ◽  
...  

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Yansheng Zhao ◽  
Xingji Ma ◽  
Yongmei Liu ◽  
Guangwei Yuan ◽  
Meijuan Guo ◽  
...  

AbstractIn acidic media, poly(styrene-methacrylic acid)/MCM-41 [P(St- MAA)/MCM-41] core/shell microspheres were synthesized using monodisperse P(St-MAA) particles contained in soap-free emulsion and cetyltrimethylammonium bromide as co-templates by adsorption self-assembly method. The effects of P(St- MAA) composition on shell structure of the core/shell microspheres were investigated. The morphology and composition of P(St-MAA)/MCM-41 microspheres were characterized by TEM, XRD and FTIR. The results show that the ordering degree of MCM-41 shells increased as the molar ratio of MAA to St increased. When n(MAA)/n(St) is 0.2, the average diameter and the shell thickness of nanocomposite microspheres are about 170 nm and 20 nm, respectively.


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