Fabrication of transition-metal (Zn, Mn, Cu)-based MOFs as efficient sensor materials for detection of H2 gas by clad modified fiber optic gas sensor technique

2021 ◽  
Vol 65 ◽  
pp. 102614
Author(s):  
M. Nagoor Meeran ◽  
S.P. Saravanan ◽  
Mohd. Shkir ◽  
S. Karthik Kannan
2021 ◽  
Author(s):  
M Nagoor Meeran ◽  
S.P. Saravanan ◽  
H.H Hegazy

Abstract Recent research demonstrate that promising gas sensing materials are called metal-organic structures (MOFs) and their products due to their tunable form, elevated surface area, and extremely porous structure and physisorption towards gases with relatively low temperature.In this report, recent developments in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives are synthesized as sensing materials. The sensors samples were analyzed by XRD, SEM, TEM, BET and XPS in order to know the textural, structural and electronic state of the samples. Fiber optic clad modified sensors were fabricated and tested gas sensing properties towards H2 gas with various concentrations (0-1000 ppm). Among the three sensing material, Zn doped MOFs sensor showed outstanding selectivity with high sensitivity (115 counts/kpa) towards H2 gas. Moreover, it has shown high response (20 s) and recovery time (27 s) as well as long term stability. The designed sensors may be required to apply to the production of an outstanding sensor for H2 for commercial uses.


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