The reaction of zinc sulphide with ionic copper—the biological implications. Part 1. Surface area studies of zinc sulphide and its reaction with copper complexes and copper containing proteins

1988 ◽  
Vol 152 (4) ◽  
pp. 265-270
Author(s):  
John Healy ◽  
Ian W. Nowell ◽  
Colin F. Mills ◽  
James R. Lusty
2002 ◽  
Vol 76 (3) ◽  
pp. 217-223 ◽  
Author(s):  
Jining Xie ◽  
Pramod K Sharma ◽  
V.V Varadan ◽  
V.K Varadan ◽  
Bhabendra K Pradhan ◽  
...  

1987 ◽  
Vol 130 (1) ◽  
pp. 11-12 ◽  
Author(s):  
John Healy ◽  
James R. Lusty ◽  
Colin F. Mills

1961 ◽  
Vol 14 (1) ◽  
pp. 20 ◽  
Author(s):  
JA Allen

The thermal decomposition of silver(II) oxide in a vacuum has been studied over the range 83-134 OC. The rates are quantitatively accounted for by the Polanyi-Wigner equation, the values of the vibration frequency at all stages being within a power of 10 of the expected theoretical value. Changes in the rate at different stages of the reaction are interpreted in terms of diffuseness of the reaction interface. This conclusion is supported by X-ray and surface area studies. The activation energy is 30 kcal. The activation energy associated with the removal of oxygen from the first layer has been shown to be the same as that for the subsequent reaction.


1953 ◽  
Vol 45 (8) ◽  
pp. 1703-1710 ◽  
Author(s):  
P. L. Walker ◽  
R. J. Foresti ◽  
C. C. Wright

2014 ◽  
Vol 18 (sup6) ◽  
pp. S6-32-S6-35 ◽  
Author(s):  
B. C. Ang ◽  
I. I. Yaacob ◽  
Y. H. Wong

1979 ◽  
Vol 36 (8) ◽  
pp. 901-905 ◽  
Author(s):  
C. M. G. Van den Berg ◽  
P. T. S. Wong ◽  
Y. K. Chau

The complexing capacities of three algal exudates and the conditional stability constants of their copper complexes have been determined by an ion exchange method. Their ability to ameliorate copper toxicity towards the primary production of Chlorella vulgaris is related to the conditional stability constants, which regulate the ionic copper concentration. Anabaena cylindrica, Navicula pelliculosa, and Scenedesmus quadricauda excreted 6.73, 2.86, and 0.66 μmol/L of complexing ligands, respectively, with conditional stability constants of 107.7, 108.1, and 108.6, respectively, for their corresponding copper complexes. When these constants were applied in calculations, a free copper ion concentration of 10−10.3 mol/L was found in each exudate. Key words: algal exudates, free copper ion concentration, complexing capacity, copper ion toxicity, primary productivity


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