A thermodynamic study of the aqueous (sodium chloride+sodium hydroxide) electrolyte using sodium amalgam and thallous chloride electrode cells

2003 ◽  
Vol 35 (3) ◽  
pp. 405-416 ◽  
Author(s):  
L. Falciola ◽  
P.R. Mussini ◽  
T. Mussini ◽  
S. Pozzi ◽  
S. Rondinini
2010 ◽  
Vol 42 (7) ◽  
pp. 886-890 ◽  
Author(s):  
Ana C.F. Ribeiro ◽  
Ana C.G. Santos ◽  
Victor M.M. Lobo ◽  
Abilio J.F.N. Sobral ◽  
Ana M.T.D.P.V. Cabral ◽  
...  

1995 ◽  
Vol 30 (2) ◽  
pp. 339-361 ◽  
Author(s):  
Tilak V. Bommaraju

Abstract One of the end uses of chlorine and sodium hydroxide, both produced by the electrolysis of aqueous sodium chloride, is in the manufacture of sodium hypochlorite, commonly called liquid “bleach.” This article outlines the methods of manufacturing liquid bleach, including the factors involved in the selection of materials of construction for handling chlorine, sodium hydroxide and sodium hypochlorite. Experimental results were presented addressing the stability of sodium hypochlorite as influenced by temperature and pH, and by anionic impurities such as Cl−, ClO3−, CO3− and SO4−, and cationic impurities which include Ca++, Mg++, Cu++, Ni++ and Fe++. Various techniques were also outlined to minimize the formation of chlorates during storage and bleaching and to improve the quality and stability of sodium hypochlorite.


2021 ◽  
Vol 155 (4) ◽  
pp. 044703
Author(s):  
Alessandra Serva ◽  
Laura Scalfi ◽  
Benjamin Rotenberg ◽  
Mathieu Salanne

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