Sodium Hypochlorite: its Application and Stability in Bleaching

1995 ◽  
Vol 30 (2) ◽  
pp. 339-361 ◽  
Author(s):  
Tilak V. Bommaraju

Abstract One of the end uses of chlorine and sodium hydroxide, both produced by the electrolysis of aqueous sodium chloride, is in the manufacture of sodium hypochlorite, commonly called liquid “bleach.” This article outlines the methods of manufacturing liquid bleach, including the factors involved in the selection of materials of construction for handling chlorine, sodium hydroxide and sodium hypochlorite. Experimental results were presented addressing the stability of sodium hypochlorite as influenced by temperature and pH, and by anionic impurities such as Cl−, ClO3−, CO3− and SO4−, and cationic impurities which include Ca++, Mg++, Cu++, Ni++ and Fe++. Various techniques were also outlined to minimize the formation of chlorates during storage and bleaching and to improve the quality and stability of sodium hypochlorite.

Author(s):  
Carlos Alberto Paraguassu-Chaves ◽  
Cláudio José Pinto de Faria ◽  
Filomena Maria Minetto Brondani ◽  
Vera Lúcia Matias Gomes Geron ◽  
Nelson Pereira Silva Junior ◽  
...  

2010 ◽  
Vol 42 (7) ◽  
pp. 886-890 ◽  
Author(s):  
Ana C.F. Ribeiro ◽  
Ana C.G. Santos ◽  
Victor M.M. Lobo ◽  
Abilio J.F.N. Sobral ◽  
Ana M.T.D.P.V. Cabral ◽  
...  

2007 ◽  
Vol 364-366 ◽  
pp. 1032-1036
Author(s):  
Wen Li Chen ◽  
Quan Zhou ◽  
Da Xing

AflatoxinB1 was extracted from rice contaminated artificially with Aspergillus flavus by using methanol-water (50:50 v/v). As for experiment group, sodium chloride was added into the extracted solution of AfB1, the excitation wavelength of 365 nm under the fluorescence mode, and the emission spectrum peak at 440nm were observed. To study the detoxification of AflatoxinB1 in several alkaline solutions, the solution of alkaline with difference concentration was added into the solution of AfB1 respectively. The results showed that all of three alkaline solutions could decrease the 440nm emission spectrum peak of solution of AfB1 in varying degrees, the effect to decrease emission spectrum peak of AfB1 was very obvious in sodium hypochlorite (NaClO), and sodium hydroxide (NaOH) took second place, whereas in ammonia (NH3·H2O), the effect was the weakest among three alkaline solutions. Moreover, the effects were different in the same alkaline solutions with different concentration, as hydrochloric acid (HCl) in low concentration was added to this complex AfB1 alkaline solutions, detoxification efficacy of AfB1 were found to be obviously increased. It was concluded that the detoxification of AflatoxinB1 may be affected by alkaline solutions according to their concentration and be degraded greatly by acid addition.


Author(s):  
Russell L. Steere ◽  
Eric F. Erbe

Thin sheets of acrylamide and agar gels of different concentrations were prepared and washed in distilled water, cut into pieces of appropriate size to fit into complementary freeze-etch specimen holders (1) and rapidly frozen. Freeze-etching was accomplished in a modified Denton DFE-2 freeze-etch unit on a DV-503 vacuum evaporator.* All samples were etched for 10 min. at -98°C then re-cooled to -150°C for deposition of Pt-C shadow- and C replica-films. Acrylamide gels were dissolved in Chlorox (5.251 sodium hypochlorite) containing 101 sodium hydroxide, whereas agar gels dissolved rapidly in the commonly used chromic acid cleaning solutions. Replicas were picked up on grids with thin Foimvar support films and stereo electron micrographs were obtained with a JEM-100 B electron microscope equipped with a 60° goniometer stage.Characteristic differences between gels of different concentrations (Figs. 1 and 2) were sufficiently pronounced to convince us that the structures observed are real and not the result of freezing artifacts.


TAPPI Journal ◽  
2010 ◽  
Vol 9 (2) ◽  
pp. 23-29 ◽  
Author(s):  
Wei-ming Wang ◽  
Zai-sheng Cai ◽  
Jian-yong Yu

Degumming of pre-chlorite treated jute fiber was studied in this paper. The effects of sodium hydroxide concentration, treatment time, temperature, sodium silicate concentration, fiber-to-liquor ratio, penetrating agent TF-107B concentration, and degumming agent TF-125A concentration were the process conditions examined. With respect to gum decomposition, fineness and mechanical properties, sodium hydroxide concentration, sodium silicate concentration, and treatment time were found to be the most important parameters. An orthogonal L9(34) experiment designed to optimize the conditions for degumming resulted in the selection of the following procedure: sodium hydroxide of 12g/L, sodium silicate of 3g/L, TF-107B of 2g/L, TF-125A of 2g/L, treatment time of 105 min, temperature of 100°C and fiber to liquor ratio of 1:20. The effect of the above degumming process on the removal of impurities was also examined and the results showed that degumming was an effective method for removing impurities, especially hemicellulose.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Yuping Li ◽  
Xiaoju Liang ◽  
Xuguo Zhou ◽  
Yu An ◽  
Ming Li ◽  
...  

AbstractGlycyrrhiza, a genus of perennial medicinal herbs, has been traditionally used to treat human diseases, including respiratory disorders. Functional analysis of genes involved in the synthesis, accumulation, and degradation of bioactive compounds in these medicinal plants requires accurate measurement of their expression profiles. Reverse transcription quantitative real-time PCR (RT-qPCR) is a primary tool, which requires stably expressed reference genes to serve as the internal references to normalize the target gene expression. In this study, the stability of 14 candidate reference genes from the two congeneric species G. uralensis and G. inflata, including ACT, CAC, CYP, DNAJ, DREB, EF1, RAN, TIF1, TUB, UBC2, ABCC2, COPS3, CS, R3HDM2, were evaluated across different tissues and throughout various developmental stages. More importantly, we investigated the impact of interactions between tissue and developmental stage on the performance of candidate reference genes. Four algorithms, including geNorm, NormFinder, BestKeeper, and Delta Ct, were used to analyze the expression stability and RefFinder, a comprehensive software, provided the final recommendation. Based on previous research and our preliminary data, we hypothesized that internal references for spatio-temporal gene expression are different from the reference genes suited for individual factors. In G. uralensis, the top three most stable reference genes across different tissues were R3HDM2, CAC and TUB, while CAC, CYP and ABCC2 were most suited for different developmental stages. CAC is the only candidate recommended for both biotic factors, which is reflected in the stability ranking for the spatio (tissue)-temporal (developmental stage) interactions (CAC, R3HDM2 and DNAJ). Similarly, in G. inflata, COPS3, R3HDM2 and DREB were selected for tissues, while RAN, COPS3 and CS were recommended for developmental stages. For the tissue-developmental stage interactions, COPS3, DREB and ABCC2 were the most suited reference genes. In both species, only one of the top three candidates was shared between the individual factors and their interactions, specifically, CAC in G. uralensis and COPS3 in G. inflata, which supports our overarching hypothesis. In summary, spatio-temporal selection of reference genes not only lays the foundation for functional genomics research in Glycyrrhiza, but also facilitates these traditional medicinal herbs to reach/maximize their pharmaceutical potential.


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