The ring expansion of a dimethyl-substituted vinylcyclobutene derivative by metal complexes that can undergo an inner-sphere electron transfer

2000 ◽  
Vol 601 (1) ◽  
pp. 147-152 ◽  
Author(s):  
Herman L Holt ◽  
Tom Russo ◽  
Allan R Pinhas
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Ring Expansion ◽  
Inner Sphere

Inner-sphere electron transfer at the ruthenium-azo interface

2022 ◽  
Author(s):  
Goutam Kumar Lahiri ◽  
Sanjib Panda ◽  
Kuo-Wei Huang ◽  
Aditi Singh ◽  
Sanchaita Dey
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Present Article ◽  
Research Interest ◽  
Redox States ◽  
Redox Active ◽  
Reversible Redox ◽  
Inner Sphere

Metal complexes exhibiting multiple reversible redox states have drawn continuing research interest due to their electron reservoir features. In this context, the present article described ruthenium-acac complexes (acac=acetylacetonate) incorporating redox-active...

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

Hydroquinone/quinone electro- and photochemical interconversion in isolable polypyridylruthenium(II) complexes

2021 ◽  
Author(s):  
Dai Oyama ◽  
Takatoshi Kanno ◽  
Tsugiko Takase
Keyword(s):  
Electron Transfer ◽  
Metal Complexes ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Fundamental Knowledge ◽  
Redox Active ◽  
Quinone Complexes

Quinone derivatives and their metal complexes are well-known molecules that participate in electron-transfer reactions relevant to diverse fields. However, the fundamental knowledge on the unique reactivity of redox-active quinone complexes...

Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO2 via Through‐Space Electronic Conjugation

2021 ◽  
Author(s):  
Shelby L. Hooe ◽  
Juan J. Moreno ◽  
Amelia G. Reid ◽  
Emma N. Cook ◽  
Charles Machan
Keyword(s):  
Electron Transfer ◽  
Homogeneous Reduction ◽  
Inner Sphere ◽  
Reduction Of Co2
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