Effect of melt processing on thermo-mechanical degradation of poly(vinyl alcohol)s

Author(s):  
P ALEXY
2004 ◽  
Vol 85 (2) ◽  
pp. 823-830 ◽  
Author(s):  
Pavol Alexy ◽  
Igor Lacı́k ◽  
Barbora Šimková ◽  
Dušan Bakoš ◽  
Nad'a Prónayová ◽  
...  

2017 ◽  
Vol 37 (4) ◽  
pp. 335-343 ◽  
Author(s):  
Yottha Srithep ◽  
Dutchanee Pholharn ◽  
Onpreeya Veang-in ◽  
Suphan Yangyuen

Abstract Poly(vinyl alcohol) (PVOH) resin is one of the most widely used water-soluble biodegradable polymer. Because of thermal degradation, PVOH exhibits limited melt processing and lacks moldability. The effects of adding glycerol as plasticizer and banana fibers (BF) to PVOH on its moldability and mechanical property were investigated. Melt blending of PVOH with glycerol and/or BF was performed in an internal mixer. The blended materials were then compression molded to produce tensile specimens. Various characterization techniques were employed to study the mechanical properties, compatibility, and crystallization behavior of the PVOH blends. By melt blending with glycerol, PVOH could be processed but decreased the tensile modulus, tensile strength, and crystallization temperature. Furthermore, the addition of BF enhanced the mechanical and thermal properties and crystallization temperature of plasticized PVOH due to compatibility between the two components. Apart from enhancing the mechanical properties and thermal stability, the incorporation of BF can reduce the production cost.


Polymer ◽  
2002 ◽  
Vol 43 (9) ◽  
pp. 2869-2873 ◽  
Author(s):  
Takashi Nishino ◽  
Shoi'chi Kani ◽  
Kimiya Gotoh ◽  
Katsuhiko Nakamae

2014 ◽  
Vol 109 ◽  
pp. 261-269 ◽  
Author(s):  
Pengju Liu ◽  
Wenhua Chen ◽  
Yuan Liu ◽  
Shibing Bai ◽  
Qi Wang

2018 ◽  
Vol 38 (7) ◽  
pp. 659-665 ◽  
Author(s):  
Aimin Xiang ◽  
Hailiang Wang ◽  
Di Liu ◽  
Songbai Ma ◽  
Xing Zhang ◽  
...  

Abstract Flexibile high hydrolysis degree poly(vinyl alcohol) (PVA) films with different polyol plasticizers were obtained by melt processing in the presence of water, and the plasticizing effect of polyols was studied. The results showed that with the incorporation of polyols, the torque decreased, suggesting the improved melt flowing ability of PVA. Higher molecular weight polyols with more –OH groups exhibited higher efficiency to improve the melt flowing ability. The incorporation of polyol plasticizers did not change the crystalline structure of PVA but decreased crystalline degrees. The transmittance decreased with the increase in plasticizer content. The flexibility of PVA films was dramatically enhanced after being plasticized with polyols. The polyols with higher molecular weight possessed a higher stablity in PVA films and resulted in less weight loss during the thermal degradation process. It was suggested that a combination of different polyol plasticizers would be a better choice to obtain the PVA films with overall excellent properties.


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