Hydrogen storage in heat-treated carbon nanofibers prepared by the vertical floating catalyst method

2003 ◽  
Vol 78 (3) ◽  
pp. 670-675 ◽  
Author(s):  
Hongwei Zhu ◽  
Xuesong Li ◽  
Lijie Ci ◽  
Cailu Xu ◽  
Dehai Wu ◽  
...  
Surfaces ◽  
2019 ◽  
Vol 2 (1) ◽  
pp. 205-215 ◽  
Author(s):  
Anna Testolin ◽  
Stefano Cattaneo ◽  
Wu Wang ◽  
Di Wang ◽  
Valentina Pifferi ◽  
...  

Three types of carbon nanofibers (pyrolytically stripped carbon nanofibers (PS), low-temperature heat treated carbon nanofibers (LHT), and high-temperature heat treated carbon nanofibers (HHT)) with different graphitization degrees and surface chemistry have been used as support for Au, Pd, or bimetallic AuPd alloy nanoparticles (NPs). The carbon supports have been characterized using Raman, X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Moreover, the morphology of the metal nanoparticles was investigated using transmission electron microscopy (TEM) and CV. The different properties of the carbon-based supports (particularly the graphitization degree) yield different electrochemical behaviors, in terms of potential window widths and electrocatalytic effects. Comparing the electrochemical behavior of monometallic Au and Pd and bimetallic AuPd, it is possible to observe the interaction of the two metals when alloyed. Moreover, we demonstrate that carbon surface has a strong effect on the electrochemical stability of AuPd nanoparticles. By tuning the Au-Pd nanoparticles’ morphology and modulating the surface chemistry of the carbon support, it is possible to obtain materials characterized by novel electrochemical properties. This aspect makes them good candidates to be conveniently applied in different fields.


Carbon ◽  
2006 ◽  
Vol 44 (8) ◽  
pp. 1404-1413 ◽  
Author(s):  
Marcello Marella ◽  
Michele Tomaselli

2018 ◽  
Vol 14 ◽  
pp. 314-323 ◽  
Author(s):  
Guanglin Xia ◽  
Lijun Zhang ◽  
Xiaowei Chen ◽  
Yuqin Huang ◽  
Dalin Sun ◽  
...  

2002 ◽  
Vol 09 (03n04) ◽  
pp. 1443-1452 ◽  
Author(s):  
C. D. HUANG ◽  
Z. T. XIONG ◽  
J. Y. LIN ◽  
K. L. TAN

In this paper we report the electrochemical behavior of heat-treated carbon blacks and Pt/C catalysts. Cyclic voltammetry indicates that the heat-treated carbon black as catalyst support does not improve the Pt/C catalyst's activity for methanol oxidation. An XPS study of a Pt-loaded carbon black indicates that the amounts of oxidized platinum and oxygen-functional groups on catalysts are decreased when the platinum particles are deposited on the heat-treated carbon surface. These changes in the surface and crystalline structural properties of carbon materials lead to the catalytic activity change in methanol electro-oxidation.


Carbon ◽  
1994 ◽  
Vol 32 (7) ◽  
pp. 1377-1382 ◽  
Author(s):  
Tyler Gruber ◽  
T.Waldek Zerda ◽  
Michel Gerspacher

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