Tuning the redox potential of riboflavin by zirconium phosphate in carbon paste electrodes

1999 ◽  
Vol 49 (1) ◽  
pp. 21-27 ◽  
Author(s):  
A. Malinauskas ◽  
T. Ruzgas ◽  
L. Gorton
Keyword(s):  
Redox Potential ◽  
Zirconium Phosphate ◽  
Carbon Paste ◽  
Carbon Paste Electrodes

scholarly journals NADH Electrooxidation Using Bis(1,10-phenanthroline-5,6-dione)(2,2′-bipyridine)ruthenium(II)-Exchanged Zirconium Phosphate Modified Carbon Paste Electrodes

2006 ◽  
Vol 18 (6) ◽  
pp. 559-572 ◽  
Author(s):  
Mitk'El B. Santiago ◽  
Meredith M. Vélez ◽  
Solmarie Borrero ◽  
Agustín Díaz ◽  
Craig A. Casillas ◽  
...  
Keyword(s):  
Zirconium Phosphate ◽  
Carbon Paste ◽  
Carbon Paste Electrodes ◽  
Modified Carbon Paste Electrodes

NADH electrooxidation using carbon paste electrodes modified with nitro-fluorenone derivatives immobilized on zirconium phosphate

2004 ◽  
Vol 564 ◽  
pp. 167-178 ◽  
Author(s):  
F.D Munteanu ◽  
N Mano ◽  
A Kuhn ◽  
L Gorton
Keyword(s):  
Zirconium Phosphate ◽  
Carbon Paste ◽  
Carbon Paste Electrodes

scholarly journals Influence of Nitrogen-Doped Carbon Dot and Silver Nanoparticle Modified Carbon Paste Electrodes on the Potentiometric Determination of Tobramycin Sulfate: A Comparative Study

Chemosensors ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 52
Author(s):  
Nermine V. Fares ◽  
Passant M. Medhat ◽  
Christine M. El Maraghy ◽  
Sherif Okeil ◽  
Miriam F. Ayad
Keyword(s):  
Silver Nanoparticle ◽  
Carbon Nanodots ◽  
Carbon Paste ◽  
X Ray Diffraction ◽  
Loteprednol Etabonate ◽  
Carbon Paste Electrodes ◽  
Transmission Electron ◽  
Nernstian Slope ◽  
Nitrogen Doped Carbon ◽  
Modified Carbon Paste Electrodes

Two inexpensive and simple methods for synthesis of carbon nanodots were applied and compared to each other, namely a hydrothermal and microwave-assisted method. The synthesized carbon nanodots were characterized using transmission electron microscopy (TEM), ultraviolet-visible (UV-Vis), photoluminescence (PL), Fourier transform-infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The synthesized microwave carbon nanodots had smaller particle size and were thus chosen for better electrochemical performance. Therefore, they were used for our modification process. The proposed electrodes performance characteristics were evaluated according to the IUPAC guidelines, showing linear response in the concentration range 10−6–10−2, 10−7–10−2, and 10−8–10−2 M of tobramycin with a Nernstian slope of 52.60, 58.34, and 57.32 mV/decade for the bare, silver nanoparticle and carbon nanodots modified carbon paste electrodes, respectively. This developed potentiometric method was used for quantification of tobramycin in its co-formulated dosage form and spiked human plasma with good recovery percentages and without interference of the co-formulated drug loteprednol etabonate and excipients.

scholarly journals Polyvinyl Chloride Modified Carbon Paste Electrodes for Sensitive Determination of Levofloxacin Drug in Serum, Urine, and Pharmaceutical Formulations

Sensors ◽  
2021 ◽  
Vol 21 (9) ◽  
pp. 3150
Author(s):  
Fatehy M. Abdel-Haleem ◽  
Sonia Mahmoud ◽  
Nour Eldin T. Abdel-Ghani ◽  
Rasha Mohamed El Nashar ◽  
Mikhael Bechelany ◽  
...  
Keyword(s):  
Bacterial Infections ◽  
Pharmaceutical Preparation ◽  
Pharmaceutical Formulations ◽  
Selectivity Coefficient ◽  
Pvc Membrane ◽  
Carbon Paste ◽  
Serum Samples ◽  
Carbon Paste Electrodes ◽  
Antibiotic Drug

Levofloxacin (LF) is a medically important antibiotic drug that is used to treat a variety of bacterial infections. In this study, three highly sensitive and selective carbon paste electrodes (CPEs) were fabricated for potentiometric determination of the LF drug: (i) CPEs filled with carbon paste (referred to as CPE); (ii) CPE coated (drop-casted) with ion-selective PVC membrane (referred to as C-CPE); (iii) CPE filled with carbon paste modified with a plasticizer (PVC/cyclohexanone) (referenced as P-CPE). The CPE was formulated from graphite (Gr, 44.0%) and reduced graphene oxide (rGO, 3.0%) as the carbon source, tricresyl phosphate (TCP, 47.0%) as the plasticizer; sodium tetrakis[3,5-bis(trifluoromethyl)phenyl] borate (St-TFPMB, 1.0%) as the ion exchanger; and levofloxacinium-tetraphenylborate (LF-TPB, 5.0%) as the lipophilic ion pair. It showed a sub-Nernstian slope of 49.3 mV decade−1 within the LF concentration range 1.0 × 10−2 M to 1.0 × 10−5 M, with a detection limit of 1.0 × 10−5 M. The PVC coated electrode (C-CPE) showed improved sensitivity (in terms of slope, equal to 50.2 mV decade−1) compared to CPEs. After the incorporation of PVC paste on the modified CPE (P-CPE), the sensitivity increased at 53.5 mV decade−1, indicating such improvement. The selectivity coefficient (log KLF2+,Fe+3pot.) against different interfering species (Na+, K+, NH4+, Ca2+, Al3+, Fe3+, Glycine, Glucose, Maltose, Lactose) were significantly improved by one to three orders of magnitudes in the case of C-CPE and P-CPE, compared to CPEs. The modification with the PVC membrane coating significantly improved the response time and solubility of the LF-TPB within the electrode matrix and increased the lifetime. The constructed sensors were successfully applied for LF determination in pharmaceutical preparation (Levoxin® 500 mg), spiked urine, and serum samples with high accuracy and precision.

Carbon-Paste Electrodes with Incorporated Lactate Oxidase and Mediators

1992 ◽  
Vol 25 (6) ◽  
pp. 1011-1024 ◽  
Author(s):  
J. Kulys ◽  
W. Schuhmann ◽  
H.-L. Schmidt
Keyword(s):  
Carbon Paste ◽  
Lactate Oxidase ◽  
Carbon Paste Electrodes

Determination of meloxicam in plasma samples using a highly selective and sensitive voltammetric sensor based on carbon paste electrodes modified by molecularly imprinted polymer nanoparticle–multiwall carbon nanotubes

2015 ◽  
Vol 7 (4) ◽  
pp. 1280-1292 ◽  
Author(s):  
Saman Azodi-Deilami ◽  
Ebadullah Asadi ◽  
Majid Abdouss ◽  
Fardin Ahmadi ◽  
Alireza Hassani Najafabadi ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Multiwall Carbon Nanotubes ◽  
Voltammetric Sensor ◽  
Plasma Samples ◽  
Carbon Paste ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Carbon Paste Electrodes ◽  
Multiwall Carbon

A highly selective voltammetric sensor for the determination of meloxicam using a MIP@MWCNT–CPE is introduced.

Amperometric biosensor for hypoxanthine based on immobilized xanthine oxidase on nanocrystal gold–carbon paste electrodes

2006 ◽  
Vol 113 (1) ◽  
pp. 272-280 ◽  
Author(s):  
Lourdes Agüí ◽  
Javier Manso ◽  
Paloma Yáñez-Sedeño ◽  
José M. Pingarrón
Keyword(s):  
Xanthine Oxidase ◽  
Amperometric Biosensor ◽  
Carbon Paste ◽  
Carbon Paste Electrodes

Ferrocene-substituted calix[4]pyrrole modified carbon paste electrodes for anion detection in water

2006 ◽  
Vol 591 (2) ◽  
pp. 223-228 ◽  
Author(s):  
Iwona Szymańska ◽  
Hanna Radecka ◽  
Jerzy Radecki ◽  
Philip A. Gale ◽  
Colin N. Warriner
Keyword(s):  
Carbon Paste ◽  
Anion Detection ◽  
Carbon Paste Electrodes ◽  
Modified Carbon Paste Electrodes
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