Electrochemical cell

1998 ◽  
Vol 70 (1) ◽  
pp. 167
Author(s):  
J Coetzer
Keyword(s):  
2018 ◽  
Vol 12 (1) ◽  
pp. 98-109 ◽  
Author(s):  
Adolfo Dannier ◽  
Gianluca Brando ◽  
Ivan Spina ◽  
Diego Iannuzzi

Objective:This paper analyses the Modular Multilevel Converter (MMC) topology, where each individual Sub Module (SM), in half bridge configuration, is directly fed by an elementary electrochemical cell.Methods:The aim is to investigate how the reference voltages influence the cells currents waveforms, determining how the active powers and the losses are distributed among the cells. Considering a 2-level Voltage Source Inverter (VSI) topology working in the same conditions, the ratio between the MMC total cells losses and VSI total cells losses is calculated. After showing the system architecture and mathematical model, the cells current waveform investigation is presented and detailed both for triangular and sinusoidal voltage reference waveform.Results:Finally, the results are critically discussed with particular focus on the comparison between the MMC and the VSI topologies.


Author(s):  
S.P.A.U.K. Samarakoon ◽  
C.A.N. Fernando

A considerable photo-current enhancement was found at the Cu/p-Cu2O/rGO-electrolyte interface in a photo-electrochemical cell with compared to that of Cu/p-Cu2O-electrolyte interface. The reason for the photo-current enhancement may be due to the efficient charge separation process provided at Cu/p-Cu2O/rGO-electrolyte interface. Here rGO (reduced graphene oxide) acts as an electron acceptor for the photo-generated charge carriers as it readily accept electrons from the conduction band of p-Cu2O. rGO was synthesized using electro-phoretic deposition (EPD) technique. Fabricated samples were characterized using diffuse reflectance spectra, photo-current action spectra and the time development of the photocurrent of photo-electrochemical cells.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Mingzi Sun ◽  
Qiuyang Lu ◽  
Zhong Lin Wang ◽  
Bolong Huang

AbstractThe charge transfer phenomenon of contact electrification even exists in the liquid–solid interface by a tiny droplet on the solid surface. In this work, we have investigated the contact electrification mechanism at the liquid–solid interface from the electronic structures at the atomic level. The electronic structures display stronger modulations by the outmost shell charge transfer via surface electrostatic charge perturbation than the inter-bonding-orbital charge transfer at the liquid–solid interface, supporting more factors being involved in charge transfer via contact electrification. Meanwhile, we introduce the electrochemical cell model to quantify the charge transfer based on the pinning factor to linearly correlate the charge transfer and the electronic structures. The pinning factor exhibits a more direct visualization of the charge transfer at the liquid–solid interface. This work supplies critical guidance for describing, quantifying, and modulating the contact electrification induced charge transfer systems in triboelectric nanogenerators in future works.


JOM ◽  
2021 ◽  
Author(s):  
S. I. Moreno-Saldaña ◽  
V. J. Martínez-Gómez ◽  
S. Valle-Cervantes ◽  
R. Lucho-Chigo ◽  
J. C. Rojas-Montes ◽  
...  
Keyword(s):  

2021 ◽  
Vol 330 ◽  
pp. 129345
Author(s):  
Xiaohua Tian ◽  
Yonghai Feng ◽  
Liang Yuan ◽  
Yuqing Duan ◽  
Lei Liu ◽  
...  

2012 ◽  
Vol 45 (6) ◽  
pp. 1261-1269 ◽  
Author(s):  
Olaf J. Borkiewicz ◽  
Badri Shyam ◽  
Kamila M. Wiaderek ◽  
Charles Kurtz ◽  
Peter J. Chupas ◽  
...  

This article presents a versatile easy-to-use electrochemical cell suitable forin operando,in situmeasurements of battery materials during electrochemical cycling using a variety of X-ray techniques. Argonne's multi-purposein situX-ray (AMPIX) cell provides reliable electrochemical cycling over extended periods owing to the uniform stack pressure applied by rigid X-ray windows and the formation of a high-fidelity hermetic seal. The suitability of the AMPIX cell for a broad range of synchrotron-based X-ray scattering and spectroscopic measurements has been demonstrated with studies at eight Advanced Photon Source beamlines to date. Compatible techniques include pair distribution function analysis, high-resolution powder diffraction, small-angle scattering and X-ray absorption spectroscopy. These techniques probe a broad range of electronic, structural and morphological features relevant to battery materials. The AMPIX cell enables experiments providing greater insight into the complex processes that occur in operating batteries by allowing the electrochemical reactions to be probed at fine reaction intervals with greater consistency (within the charge–discharge cycle and between different methodologies) with potential for new time-dependent kinetic studies or studies of transient species. Representative X-ray and electrochemical data to demonstrate the functionality of the AMPIX cell are presented.


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