The effect of rare-earth oxide addition on the hot-pressing of magnesium silicon nitride

2002 ◽  
Vol 22 (5) ◽  
pp. 777-783 ◽  
Author(s):  
Shukiko Tanaka ◽  
Kiyoshi Itatani ◽  
Hiroshi Uchida ◽  
Mamoru Aizawa ◽  
Ian J Davies ◽  
...  
ChemInform ◽  
1988 ◽  
Vol 19 (33) ◽  
Author(s):  
E. RAPOPORT ◽  
C. BRODHAG ◽  
F. THEVENOT

1987 ◽  
Vol 11 (2) ◽  
pp. 235-238 ◽  
Author(s):  
K. Ohashi ◽  
T. Yokoyama ◽  
Y. Tawara

2009 ◽  
Vol 409 ◽  
pp. 377-381 ◽  
Author(s):  
Peter Tatarko ◽  
Štefánia Lojanová ◽  
Ján Dusza ◽  
Pavol Šajgalík

Fracture toughness of hot-pressed silicon nitride and Si3N4+SiC nanocomposites prepared with different rare-earth oxides (La2O3, Sm2O3, Y2O3, Yb2O3, Lu2O3) sintering additives have been investigated by Chevron Notched Beam, Indentation Strength and Indentation Fracture techniques. The fracture toughness values of composites were lower due to the finer microstructures and the lack of toughening mechanisms. In the Si3N4 with higher aspect ratio (Lu or Yb additives) crack deflection occurred more frequently compared to the Si3N4 doped with La or Y, which was responsible for the higher fracture toughness.


1992 ◽  
Vol 287 ◽  
Author(s):  
Terry N. Tiegs ◽  
Stephen D. Nunn ◽  
Kristin L. Ploetz ◽  
Paul A. Menchoffer ◽  
Claudia A. Walls

ABSTRACTThe rare earth-oxide and nitride apatites were examined as grain boundary phases in silicon nitride to assess their potential for developing high toughness materials using gas-pressuresintering. Densification was dependent on the quantity of additives used with high densities achieved at equivalent oxygen contents of ∼8%. Fracture toughnesses (KIc) up to 8-10 MPa√m were obtained for some compositions. Ambient temperature flexural strengths were in the range of 400-720 MPa; however, the strengths atelevated temperatures (1200ºC) were reduced from these values.


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