Optimum glass formation at off-eutectic composition and its relation to skewed eutectic coupled zone in the La based La–Al–(Cu,Ni) pseudo ternary system

2003 ◽  
Vol 51 (15) ◽  
pp. 4551-4561 ◽  
Author(s):  
H Tan ◽  
Y Zhang ◽  
D Ma ◽  
Y.P Feng ◽  
Y Li
2000 ◽  
Vol 644 ◽  
Author(s):  
Y. Li

AbstractOnset temperature, Tm and offset temperature (liquidus) Tl of melting of a series of bulk glass forming alloys based on La, Mg, and Pd have been measured by studying systematically the melting behaviour of these alloys using DTA or DSC. Bulk metallic glass formation has been found to be most effective at or near their eutectic points and less effective for off-eutectic alloys. Reduced glass transition temperature Trg given by Tg/Tl is found to show a stronger correlation with critical cooling rate or critical section thickness for glass formation than Trg given by Tg/Tm.


2004 ◽  
Vol 30 (6) ◽  
pp. 571-572 ◽  
Author(s):  
Gasymly Shakhnaz Shapur gyzy

2012 ◽  
Vol 511 (1) ◽  
pp. 209-214 ◽  
Author(s):  
M. Nouadji ◽  
A. Attaf ◽  
R. El Abdi ◽  
M. Poulain

2004 ◽  
Vol 19 (8) ◽  
pp. 2221-2225 ◽  
Author(s):  
J.Y. Lee ◽  
D.H. Bae ◽  
J.K. Lee ◽  
D.H. Kim

In this study, the effect of addition of Nb on glass formation in Ni–Ti–Zr–Si–Sn alloys has been studied. The composition range for bulk glass formation with Dmax > 2 mm (Dmax, maximum diameter for glass formation by injection cast method) becomes wider when compared with the non-Nb–containing alloy. The ΔTx (= Tx – Tg; Tx, crystallization onset temperature; Tg, glass transition temperature), Trg (= Tg/Tl; Tl, liquidus temperature) and γ [= Tx/(Tl + Tg)] values for the alloys Dmax > 2 mm are in the range of 40–59, 0.638–0.651, and 0.410–0.419, respectively. The compositions of the alloys (Dmax > 2 mm) are closer to pseudo-eutectic composition than that of the alloy without Nb, showing an improved glass forming ability. The critical cooling rate for glass formation (Dmax = 5 mm) is estimated to be order of approximately 40 K/s.


2007 ◽  
Vol 353 (32-40) ◽  
pp. 3425-3428 ◽  
Author(s):  
Qing Wang ◽  
Jianbing Qiang ◽  
Yingmin Wang ◽  
Junhai Xia ◽  
Chuang Dong

2021 ◽  
Vol 7 (8(62)) ◽  
pp. 35-38
Author(s):  
DUNIA TALEH HASANOVA

In order to determine the region of glass formation between the AsS and ErS compounds, we studied the methods of physicochemical analysis: differential thermal (DTA), X-ray phase (XRD), microstructural (MCA), as well as by measuring microhardness and density. The eutectic composition between the AsS and ErS compounds is 10 mol. % ErS and temperature 280oC. At a cooling rate v = 102 K / min, the glass transition region based on AsS reaches 10 mol. % ErS. Some physicochemical properties of alloys from the region of glass formation have been investigated. The area of homogeneity based on AsS reaches up to 1.5 mol. % ErS.


2017 ◽  
Vol 19 (19) ◽  
pp. 12056-12063 ◽  
Author(s):  
S. Zhao ◽  
J. H. Li ◽  
S. M. An ◽  
S. N. Li ◽  
B. X. Liu

A realistic interatomic potential was first constructed for the Ca–Mg–Ni system and then applied to Monte Carlo simulations to predict the favored composition for metallic glass formation in the ternary system.


2012 ◽  
Vol 135 (1) ◽  
pp. 73-79 ◽  
Author(s):  
Feifei Chen ◽  
Baoan Song ◽  
Changgui Lin ◽  
Shixun Dai ◽  
Junwen Cheng ◽  
...  

2018 ◽  
Vol 63 (7) ◽  
pp. 962-965
Author(s):  
I. B. Bakhtiyarly ◽  
G. M. Fatullaeva ◽  
O. Sh. Kerimli

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