Basis for Selectivity of Phenmedipham and Desmedipham on Wild Mustard, Redroot Pigweed, and Sugar Beet
The basis for selectivity of phenmedipham (methyl-m-hydroxycarbanilatem-methylcarbanilate) and desmedipham (ethylm-hydroxycarbanilate carbanilate) on wild mustard [Brassica kaber(DC.) L.C. Wheeler ‘pinnatifida’ (Stokes) L.C. Wheeler], redroot pigweed (Amaranthus retroflexusL.), and sugar beet (Beta vulgarisL.) was studied by evaluating spray retention, absorption, translocation, and metabolism. Total photosynthesis in wild mustard was severely inhibited in less than 5 hr after foliar application of either herbicide and did not recover. Total photosynthesis in sugar beet was slightly inhibited but recovered after 24 hr. Photosynthesis in redroot pigweed recovered from a treatment of phenmedipham but did not recover when treated with desmedipham. Differences in spray retention or foliar absorption did not explain selectivity. Within 5 hr after herbicide application, redroot pigweed had translocated more desmedipham than phenmedipham from the site of absorption and had metabolized a large amount of the phenmedipham but little desmedipham. The key factor explaining selectivity appeared to be at the initial detoxication reaction of the parent compound.