scholarly journals Infrared Observations of Interstellar Ices

2000 ◽  
Vol 197 ◽  
pp. 135-146 ◽  
Author(s):  
P. Ehrenfreund ◽  
W. A. Schutte
Keyword(s):  
Molecular Clouds ◽  
Cosmic Ray ◽  
Dust Particles ◽  
Early Solar System ◽  
Infrared Space Observatory ◽  
Infrared Observations ◽  
Interstellar Ice ◽  
Low Mass ◽  
Interstellar Ices ◽  
Ice Chemistry

In the recent years revolutionary results concerning the nature of icy dust particles have been obtained with the help of the Infrared Space Observatory (ISO) and ground based observations. To date interstellar ice features of H2O, CO, CO2, CH3OH, CH4, H2CO, OCS and HCOOH as well as other minor species are observed. Interstellar grains act as important catalysts in the interstellar medium. Processes such as UV irradiation, cosmic ray processing and temperature variations determine the grain mantle growth and chemical evolution. ISO has revealed that ice segregation is an important and ubiquitous process in the vicinity of massive protostars and reflects the extensive thermal processing of grains in such environments.In this paper a recent view on the inventory of interstellar ices is presented. Constraints on the reservoirs of oxygen in dense clouds are discussed, taking into account recent measurements of oxygen-bearing species. Large abundances of CO2 and CH3OH in dense molecular clouds provide challenging perspectives to investigate the differences of ice chemistry in the vicinity of high and low-mass protostars. Accurate abundances of ice species and knowledge on the ice distribution in the protostellar regions are an important tool to define the environmental conditions in molecular clouds. A global understanding of interstellar ice chemistry also allows monitoring the incorporation and evolution of volatiles in planetesimals and comets and to reveal processes predominant in the early Solar System.

Photochemical Evolution of Interstellar/Precometary Organic Material

1997 ◽  
Vol 161 ◽  
pp. 23-47 ◽  
Author(s):  
Louis J. Allamandola ◽  
Max P. Bernstein ◽  
Scott A. Sandford
Keyword(s):  
Origin Of Life ◽  
Building Blocks ◽  
Complex Species ◽  
Infrared Observations ◽  
Interstellar Ice ◽  
Polycyclic Aromatic ◽  
Ultraviolet Photolysis ◽  
The Origin Of Life ◽  
Simple Molecules ◽  
Complex Organic

AbstractInfrared observations, combined with realistic laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the building blocks of comets. Since comets are thought to be a major source of the volatiles on the primative earth, their organic inventory is of central importance to questions concerning the origin of life. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, CH4, H2, and probably some NH3and H2CO, as well as more complex species including nitriles, ketones, and esters. The evidence for these, as well as carbonrich materials such as polycyclic aromatic hydrocarbons (PAHs), microdiamonds, and amorphous carbon is briefly reviewed. This is followed by a detailed summary of interstellar/precometary ice photochemical evolution based on laboratory studies of realistic polar ice analogs. Ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and the moderately complex organic molecules: CH3CH2OH (ethanol), HC(= O)NH2(formamide), CH3C(= O)NH2(acetamide), R-CN (nitriles), and hexamethylenetetramine (HMT, C6H12N4), as well as more complex species including polyoxymethylene and related species (POMs), amides, and ketones. The ready formation of these organic species from simple starting mixtures, the ice chemistry that ensues when these ices are mildly warmed, plus the observation that the more complex refractory photoproducts show lipid-like behavior and readily self organize into droplets upon exposure to liquid water suggest that comets may have played an important role in the origin of life.

Results from Two Low Mass Cosmic Ray Experiments Flown on the HASP Platform

2009 ◽  
Author(s):  
R. S. Fontenot ◽  
W. A. Hollerman ◽  
M. Tittsworth ◽  
W. Fountain ◽  
M. Christl ◽  
...  
Keyword(s):  
Cosmic Ray ◽  
Low Mass

scholarly journals Molecular Clouds Observed by the EGRET Gamma-Ray Telescope

1997 ◽  
Vol 170 ◽  
pp. 22-24 ◽  
Author(s):  
Seth. W. Digel ◽  
Stanley D. Hunter ◽  
Reshmi Mukherjee ◽  
Eugéne J. de Geus ◽  
Isabelle A. Grenier ◽  
...  
Keyword(s):  
Molecular Mass ◽  
Molecular Clouds ◽  
Gamma Ray ◽  
Angular Resolution ◽  
Cosmic Ray ◽  
High Energy ◽  
Background Rejection ◽  
Γ Rays ◽  
Γ Ray ◽  
Production Mechanisms

EGRET, the high-energy γ-ray telescope on the Compton Gamma-Ray Observatory, has the sensitivity, angular resolution, and background rejection necessary to study diffuse γ-ray emission from the interstellar medium (ISM). High-energy γ rays produced in cosmic-ray (CR) interactions in the ISM can be used to determine the CR density and calibrate the CO line as a tracer of molecular mass. Dominant production mechanisms for γ rays of energies ∼30 MeV–30 GeV are the decay of pions produced in collisions of CR protons with ambient matter and Bremsstrahlung scattering of CR electrons.

scholarly journals CTA and cosmic-ray diffusion in molecular clouds

2012 ◽  
Author(s):  
G. Pedaletti ◽  
D. F. Torres ◽  
S. Gabici ◽  
E. de Oña Wilhelmi ◽  
D. Mazin ◽  
...  
Keyword(s):  
Molecular Clouds ◽  
Cosmic Ray ◽  
Ray Diffusion

scholarly journals Cosmic ray sputtering yield of interstellar ice mantles. CO and CO2 ice thickness dependence

2021 ◽  
Author(s):  
E. Dartois ◽  
M. Chabot ◽  
T. Id Barkach ◽  
H. Rothard ◽  
P. Boduch ◽  
...  
Keyword(s):  
Cosmic Ray ◽  
Thickness Dependence ◽  
Ice Thickness ◽  
Interstellar Ice ◽  
Sputtering Yield

scholarly journals Molecular Clouds and Star Formation at Large R

1991 ◽  
Vol 144 ◽  
pp. 121-130
Author(s):  
J. Brand ◽  
J.G.A. Wouterloot
Keyword(s):  
Star Formation ◽  
Molecular Clouds ◽  
Density Wave ◽  
Cosmic Ray ◽  
Volume Density ◽  
Kinetic Temperature ◽  
Galactocentric Distance ◽  
The Galaxy ◽  
The Mean ◽  
Cosmic Ray Flux

In the outer Galaxy (defined here as those parts of our system with galactocentric radii R>R0) the HI gas density (Wouterloot et al., 1990), the cosmic ray flux (Bloemen et al, 1984) and the metallicity (Shaver et al., 1983) are lower than in the inner parts. Also, the effect of a spiral density wave is much reduced in the outer parts of the Galaxy due to corotation. This changing environment might be expected to have its influence on the formation of molecular clouds and on star formation within them. In fact, some differences with respect to the inner Galaxy have been found: the ratio of HI to H2 surface density is increasing from about 5 near the Sun to about 100 at R≈20kpc (Wouterloot et al., 1990). Because of the “flaring” of the gaseous disk, the scale height of both the atomic and the molecular gas increases by about a factor of 3 between R0 and 2R0 (Wouterloot et al., 1990), so the mean volume density of both constituents decreases even more rapidly than their surface densities. The size of HII regions decreases significantly with increasing galactocentric distance (Fich and Blitz, 1984), probably due to the fact that outer Galaxy clouds are less massive (see section 3.3), and therefore form fewer O-type stars than their inner Galaxy counter parts. There are indications that the cloud kinetic temperature is lower by a few degrees (Mead and Kutner, 1988), although it is not clear to what extent this is caused by beam dilution.

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