The Dipolar Solar Minimum Corona

The large-scale configuration of the UV solar corona at the minimum activity between solar cycles 22 and 23 is explored in this paper. Exploiting a large sample of spectroscopic observations acquired by the Ultraviolet Coronagraph Spectrometer aboard the Solar and Heliospheric Observatory in the two-year period of 1996–1997, this work provides the first-ever monochromatic O vi 1032 Å image of the extended corona, and the first-ever two-dimensional maps of the kinetic temperature of oxygen ions and the O vi 1037/1032 Å doublet intensity ratio (a proxy for the outflow velocity of the oxygen component of the solar wind), statistically representative of solar minimum conditions. A clear dipolar magnetic structure, both equator- and axis-symmetric, is distinctly shown to shape the solar minimum corona, both in UV emission and in temperature and expansion rate. This statistical approach allows for robust establishment of the key role played by the magnetic field divergence in modulating the speed and temperature of the coronal flows, and identification of the coronal sources of the fast and slow solar wind.

Discovery of a Wind-blown Bubble Associated with the Supernova Remnant G346.6-0.2: A Hint for the Origin of Recombining Plasma

We report on CO and H i studies of the mixed-morphology supernova remnant (SNR) G346.6−0.2. We find a wind-blown bubble along the radio continuum shell with an expansion velocity of ∼10 km s−1, which was likely formed by strong stellar winds from the high-mass progenitor of the SNR. The radial velocities of the CO/H i bubbles at V LSR = −82 to −59 km s−1 are also consistent with those of shock-excited 1720 MHz OH masers. The molecular cloud in the northeastern shell shows a high kinetic temperature of ∼60 K, suggesting that shock heating occurred. The H i absorption studies imply that G346.6−0.2 is located on the farside of the Galactic center from us, and the kinematic distance of the SNR is derived to be 11.1 − 0.3 + 0.5 kpc. We find that the CO line intensity has no specific correlation with the electron temperature of recombining plasma, implying that the recombining plasma in G346.6−0.2 was likely produced by adiabatic cooling. With our estimates of the interstellar proton density of 280 cm−3 and gamma-ray luminosity <5.8 × 1034 erg s−1, the total energy of accelerated cosmic rays of W p < 9.3 × 1047 erg is obtained. A comparison of the age–W p relation to other SNRs suggests that most of the accelerated cosmic rays in G346.6−0.2 have escaped from the SNR shell.

Solar Wind ∼0.15–1.5 keV Electrons around Corotating Interaction Regions at 1 au

Here we present a statistical study of the ∼0.15–1.5 keV suprathermal electrons observed in uncompressed/compressed slow and fast solar wind around 59 corotating interaction regions (CIRs) with good measurements by Wind 3DP from 1995 through 1997. For each of these CIRs, we fit the strahl and halo energy spectra at ∼0.15–1.5 keV to a Kappa function with a Kappa index κ and kinetic temperature T eff. We find that the ∼0.15–1.5 keV strahl electrons behave similarly in both slow and fast wind: the strahl number density n s positively correlates with the solar wind electron temperature T e and interplanetary magnetic field magnitude ∣B∣, while the strahl pitch angle width Θ s decreases with the solar wind speed V sw. These suggest that the strahl electrons are generated by a similar/same process at the Sun in both slow and fast wind that produces these correlations, and the scattering efficiency of strahl in the interplanetary medium (IPM) decreases with V sw. The ∼0.15–1.5 keV halo electrons also behave similarly in both slow and fast wind: the halo parameter positively correlates with the corresponding strahl parameter, and the halo number density n h positively correlates only with T e . These indicate that the halo formation process in the IPM retains most of the strahl properties, but it erases the relationship between n s and ∣B∣. In addition, κ in compressed wind distributes similarly to that in uncompressed wind, for both the strahl and halo. It shows that CIRs at 1 au are not a significant/effective acceleration source for the strahl and halo.

Interstellar Nitrogen Isotope Ratios: New NH3 Data from the Galactic Center out to the Perseus Arm

Our aim is to measure the interstellar 14N/15N ratio across the Galaxy, to establish a standard data set on interstellar ammonia isotope ratios, and to provide new constraints on the Galactic chemical evolution. The (J, K) = (1, 1), (2, 2), and (3, 3) lines of 14NH3 and 15NH3 were observed with the Shanghai Tianma 65 m radio telescope (TMRT) and the Effelsberg 100 m telescope toward a large sample of 210 sources. One hundred fourty-one of these sources were detected by the TMRT in 14NH3. Eight of them were also detected in 15NH3. For 10 of the 36 sources with strong NH3 emission, the Effelsberg 100 m telescope successfully detected their 15NH3(1, 1) lines, including 3 sources (G081.7522, W51D, and Orion-KL) with detections by the TMRT telescope. Thus, a total of 15 sources are detected in both the 14NH3 and 15NH3 lines. Line and physical parameters for these 15 sources are derived, including optical depths, rotation and kinetic temperatures, and total column densities. 14N/15N isotope ratios were determined from the 14NH3/15NH3 abundance ratios. The isotope ratios obtained from both telescopes agree for a given source within the uncertainties, and no dependence on heliocentric distance and kinetic temperature is seen. 14N/15N ratios tend to increase with galactocentric distance, confirming a radial nitrogen isotope gradient. This is consistent with results from recent Galactic chemical model calculations, including the impact of superasymptotic giant branch stars and novae.

Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media

The kinetic result of hydrolysis of Ethyl Caprlyate has been investigated at different composition of aqueous-organic solvent with Acetone (30-70% v/v) over the temperature range of 20 to 400c. The calculated result follows second order kinetics and is observed that the rate decreases with increasing proportion of Acetone. This behavior is attributed electrostatic nature that various solvent-solute interaction in reaction media. Linear plots of Logk against water concentration shows that equilibrium shifted from dense form to bulky form. Iso-kinetic temperature has been determined with the help of slopes of (ΔH*) versus (ΔS*). Thermodynamic parameter has been calculated with the help of Wynne-Jones and Eyring equation.

Theoretical studies of carbon isotopic fractionation in reactions of C with C2: dynamics, kinetics, and isotopologue equilibria

Context. Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those involving C with C2. Aims. We aim to supply theoretical thermal rate coefficients as a function of the temperature for the gas-phase isotope-exchange reactions 13C+12C2(X1Σg+,a3Πu)⇌13C12C(X1Σg+,a3Πu)+12C and 13C+13C12C(X1Σg+,a3Πu)⇌13C2(X1Σg+,a3Πu)+12C. Methods. By relying on the large masses of the atoms involved, we employ a variation of the quasi-classical trajectory method, with the previously obtained (mass-independent) potential energy surfaces of C3 dictating the forces between the colliding partners. Results. The calculated rate coefficients within the range of 25 ≤ T∕K ≤ 500 show a positive temperature dependence and are markedly different from previous theoretical estimates. While the forward reactions are fast and inherently exothermic owing to the lower zero-point energy content of the products, the reverse processes have temperature thresholds. For each reaction considered, analytic three-parameter Arrhenius-Kooij formulas are provided that readily interpolate and extrapolate the associated forward and backward rates. These forms can further be introduced in astrochemical networks. Apart from the proper kinetic attributes, we also provide equilibrium constants for these processes, confirming their prominence in the overall C fractionation chemistry. In this respect, the 13C+12C2(X1Σg+) and 13C+12C2(a3Πu) reactions are found to be particularly conspicuous, notably at the typical temperatures of dense molecular clouds. For these reactions and considering both equilibrium and time-dependent chemistry, theoretical 12C/13C ratios as a function of the gas kinetic temperature are also derived and shown to be consistent with available model chemistry and observational data on C2.

Study of the filament WB 673 in ammonia radiolines

We study the molecular filament WB 673 which is located at a distance of 1.8 kpc in the giant molecular cloud G174 + 2.5. Observations of ammonia radiolines NH3 (1,1), (2,2) and (3,3) were carried out in 2019 at the Effelsberg observatory (Germany). The parameters of the lines were determined, maps of the integrated intensities of ammonia in dense clumps WB 668, WB 673, S233-IR and G173.57+2.43 were obtained. The column density of ammonia and the kinetic temperature of the gas were obtained. An analysis of the hyperfine structure anomalies of the NH3 (1,1) lines was carried out.

Estimation of physical conditions in star formation region S255IR-SMA1

The physical conditions were estimated from the methanol radio lines observed at 0.8 mm with IRAM30m in the star-forming region S255IR-SMA1. In the approximation of a large velocity gradient (LVG), the values of the gas kinetic temperature (170 K), the number density of molecular hydrogen (3×106 cm−3), the specific column density of methanol (2×1012 cm−3s), the relative abundance of methanol (10−7) and the filling factor (10 %). The parameter values are typical for hot dense cores. It is shown that the S255IR-SMA1 object is significantly inhomogeneous within the diagram (7.5 ).