scholarly journals From molecules to dust grains: The role of alumina cluster seeds

2019 ◽  
Vol 15 (S350) ◽  
pp. 245-248
Author(s):  
David Gobrecht ◽  
John M.C. Plane ◽  
Stefan T. Bromley ◽  
Leen Decin ◽  
Sergio Cristallo

AbstractAsymptotic Giant Branch (AGB) stars contribute a major part to the global dust budget in galaxies. Owing to their refractory nature alumina (stoichiometric formula AlO) is a promising candidate to be the first condensate emerging in the atmospheres of oxygen-rich AGB stars. Strong evidence for that is supplied by the presence of alumina in pristine meteorites and a broad spectral feature observed around ∼ 13 μm. The emergence of a specific condensate depends on the thermal stability of the solid, the gas density and its composition. The evaluation of the condensates is based on macroscopic bulk properties. The growth and size distribution of dust grains is commonly described by Classical Nucleation Theory (CNT). We question the applicability of CNT in an expanding circumstellar envelope as CNT presumes thermodynamic equilibrium and requires, in practise, seed nuclei on which material can condense. However, nano-sized molecular clusters differ significantly from bulk analogues. Quantum effects of the clusters lead to non-crystalline structures, whose characteristics (energy, geometry) differ substantially, compared to the bulk material. Hence, a kinetic quantum-chemical treatment involving various transition states describes dust nucleation most accurately. However, such a treatment is prohibitive for systems with more than 10 atoms. We discuss the viability of chemical-kinetic routes towards the formation of the monomer (Al2O3) and the dimer (Al4O6) of alumina.

2019 ◽  
Vol 624 ◽  
pp. A107 ◽  
Author(s):  
J. L. Verbena ◽  
V. Bujarrabal ◽  
J. Alcolea ◽  
M. Gómez-Garrido ◽  
A. Castro-Carrizo

Context. Asymptotic giant branch (AGB) stars go through a process of strong mass loss that involves pulsations of the atmosphere, which extends to a region in which the conditions are adequate for dust grains to form. Radiation pressure acts on these grains which, coupled to the gas, drive a massive outflow. The details of this process are not clear, including which molecules are involved in the condensation of dust grains. Aims. We seek to study the role of the SiO molecule in the process of dust formation and mass loss in M-type AGB stars. Methods. Using the IRAM NOEMA interferometer we observed the 28SiO and 29SiO J = 3−2, v = 0 emission from the inner circumstellar envelope of the evolved stars IK Tau and IRC+10011. We computed azimuthally averaged emission profiles to compare the observations to models using a molecular excitation and ray-tracing code for SiO thermal emission. Results. We observe circular symmetry in the emission distribution. We also find that the source diameter varies only marginally with radial velocity, which is not the expected behaviour for envelopes expanding at an almost constant velocity. The adopted density, velocity, and abundance laws, together with the mass-loss rate, which best fit the observations, give us information concerning the chemical behaviour of the SiO molecule and its role in the dust formation process. Conclusions. The results indicate that there is a strong coupling between the depletion of gas-phase SiO and gas acceleration in the inner envelope. This could be explained by the condensation of SiO into dust grains.


2018 ◽  
Vol 14 (S343) ◽  
pp. 119-128
Author(s):  
David Gobrecht ◽  
Stefan T. Bromley ◽  
John M. C. Plane ◽  
Leen Decin ◽  
Sergio Cristallo

AbstractA promising candidate to initiate dust formation in oxygen-rich AGB stars is alumina (Al2O3) showing an emission feature around ∼13μm attributed to Al−O stretching and bending modes (Posch+99,Sloan+03). The counterpart to alumina in carbon-rich AGB atmospheres is the highly refractory silicon carbide (SiC) showing a characteristic feature around 11.3μm (Treffers74). Alumina and SiC grains are thought to represent the first condensates to emerge in AGB stellar atmospheres. We follow a bottom-up approach, starting with the smallest stoichiometric clusters (i.e. Al4O6, Si2C2), successively building up larger-sized clusters. We present new results of quantum-mechanical structure calculations of (Al2O3)n, n = 1−10 and (SiC)n clusters with n = 1−16, including potential energies, rotational constants, and structure-specific vibrational spectra. We demonstrate the energetic viability of homogeneous nucleation scenarios where monomers (Al2O3 and SiC) or dimers (Al4O6 and Si2C2) are successively added. We find significant differences between our quantum theory based results and nanoparticle properties derived from (classical) nucleation theory.


2018 ◽  
Vol 14 (S343) ◽  
pp. 129-133
Author(s):  
J. Boulangier ◽  
D. Gobrecht ◽  
L. Decin

AbstractUnderstanding Asymptotic Giant Branch (AGB) stars is important as they play a vital role in the chemical life cycle of galaxies. AGB stars are in a phase of their life time where they have almost ran out of fuel and are losing vast amounts of material to their surroundings, via stellar winds. As this is an evolutionary phase of low mass stars, almost all stars go through this phase making them one of the main contributors to the chemical enrichment of galaxies. It is therefore important to understand what kind of material is being lost by these stars, and how much and how fast. This work summarises the steps we have taken towards developing a self-consistent AGB wind model. We improve on current models by firstly coupling chemical and hydrodynamical evolution, and secondly by upgrading the nucleation theory framework to investigate the creation of TiO2, SiO, MgO, and Al2O3 clusters.


1996 ◽  
Vol 13 (2) ◽  
pp. 185-186
Author(s):  
Jessica M. Chapman

Radio emission at centimetre and millimetre wavelengths provides a powerful tool for studying the circumstellar envelopes of evolved stars. These include stars on the asymptotic giant branch (AGB), post-AGB stars and a small number of massive M-type supergiant stars. The AGB stars and M-type supergiants are characterised by extremely high mass-loss rates. The mass loss in such an evolved star is driven by radiation pressure acting on grains which form in the outer stellar atmosphere. The grains are accelerated outwards and transfer momentum to the gas through grain–gas collisions. The outflowing dust and gas thus form an expanding circumstellar envelope through which matter flows from the star to the interstellar medium, at a typical velocity of 15 km s−1. For a recent review of circumstellar mass loss see Chapman, Habing & Killeen (1995).


2019 ◽  
Vol 626 ◽  
pp. A92 ◽  
Author(s):  
M. Gładkowski ◽  
R. Szczerba ◽  
G. C. Sloan ◽  
E. Lagadec ◽  
K. Volk

Aims. We present an analysis and comparison of the 30 μm dust features seen in the Spitzer Space Telescope spectra of 207 carbon-rich asymptotic giant branch (AGB) stars, post-AGB objects, and planetary nebulae (PNe) located in the Milky Way, the Magellanic Clouds (MCs), or the Sagittarius dwarf spheroidal galaxy (Sgr dSph), which are characterised by different average metallicities. We investigated whether the formation of the 30 μm feature carrier may be a function of the metallicity. Through this study we expect to better understand the late stages of stellar evolution of carbon-rich stars in these galaxies. Methods. Our analysis uses the “Manchester method” as a basis for estimating the temperature of dust for the carbon-rich AGB stars and the PNe in our sample. For post-AGB objects we changed the wavelength ranges used for temperature estimation, because of the presence of the 21 μm feature on the short wavelength edge of the 30 μm feature. We used a black-body function with a single temperature deduced from the Manchester method or its modification to approximate the continuum under the 30 μm feature. Results. We find that the strength of the 30 μm feature increases until dust temperature drops below 400 K. Below this temperature, the large loss of mass and probably the self-absorption effect reduces the strength of the feature. During the post-AGB phase, when the intense mass-loss has terminated, the optical depth of the circumstellar envelope is smaller, and the 30 μm feature becomes visible again, showing variety of values for post-AGB objects and PNe, and being comparable with the strengths of AGB stars. In addition, the AGB stars and post-AGB objects show similar values of central wavelengths – usually between 28.5 and 29.5 μm. However, in case of PNe the shift of the central wavelength towards longer wavelengths is visible. The normalised median profiles for AGB stars look uniformly for various ranges of dust temperature, and different galaxies. We analysed the profiles of post-AGB objects and PNe only within one dust temperature range (below 200 K), and they were also similar in different galaxies. In the spectra of 17 PNe and five post-AGB objects we found the broad 16–24 μm feature. Two objects among the PNe group are the new detections: SMP LMC 51, and SMP LMC 79, whereas in the case of post-AGBs the new detections are: IRAS 05370-7019, IRAS 05537-7015, and IRAS 21546+4721. In addition, in the spectra of nine PNe we found the new detections of 16–18 μm feature. We also find that the Galactic post-AGB object IRAS 11339-6004 has a 21 μm emission. Finally, we have produced online catalogues of photometric data and Spitzer IRS spectra for all objects that show the 30 μm feature. These resources are available online for use by the community. Conclusions. The most important conclusion of our work is the fact that the formation of the 30 μm feature is affected by metallicity. Specifically that, as opposed to more metal-poor samples of AGB stars in the MCs, the feature is seen at lower mass-loss rates, higher temperatures, and has seen to be more prominent in Galactic carbon stars. The averaged feature (profile) in the AGB, post-AGB objects, and PNe seems unaffected by metallicity at least between a fifth and solar metallicity, but in the case of PNe it is shifted to significantly longer wavelengths.


2021 ◽  
Vol 654 ◽  
pp. A18
Author(s):  
W. H. T. Vlemmings ◽  
T. Khouri ◽  
D. Tafoya

Context. Observation of CO emission around asymptotic giant branch (AGB) stars is the primary method to determine gas mass-loss rates. While radiative transfer models have shown that molecular levels of CO can become mildly inverted, causing maser emission, CO maser emission has yet to be confirmed observationally. Aims. High-resolution observations of the CO emission around AGB stars now have the brightness temperature sensitivity to detect possible weak CO maser emission. Methods. We used high angular resolution observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA) to observe the small-scale structure of CO J = 3−2 emission around the oxygen-rich AGB star W Hya. Results. We find CO maser emission amplifying the stellar continuum with an optical depth τ ≈−0.55. The maser predominantly amplifies the limb of the star because CO J = 3−2 absorption from the extended stellar atmosphere is strongest towards the centre of the star. Conclusions. The CO maser velocity corresponds to a previously observed variable component of high-frequency H2O masers and with the OH maser that was identified as the amplified stellar image. This implies that the maser originates beyond the acceleration region and constrains the velocity profile since we find the population inversion primarily in the inner circumstellar envelope. We find that inversion can be explained by the radiation field at 4.6 μm and that the existence of CO maser emission is consistent with the estimated mass-loss rates for W Hya. However, the pumping mechanism requires a complex interplay between absorption and emission lines in the extended atmosphere. Excess from dust in the circumstellar envelope of W Hya is not sufficient to contribute significantly to the required radiation field at 4.6 μm. The interplay between molecular lines that cause the pumping can be constrained by future multi-level CO observations.


2016 ◽  
Vol 12 (S323) ◽  
pp. 165-168
Author(s):  
Flavia Dell’Agli

AbstractAsymptotic giant branch (AGB) stars are among the most important gas and dust polluters of the Universe. The latest AGB evolutionary models take into account dust production in the circumstellar envelope of these stars, starting from a detailed computation of the main physical processes and chemical surface variations occurring in this evolutionary phase. Following the formation and growth of dust particles, they provide the unique possibility of interpreting the AGB population observed in resolved galaxies. The first application was for the Spitzer observations of dusty AGBs in the Magellanic Clouds, characterising carbon-rich and oxygen-rich stars in terms of initial mass, epoch of star formation, evolutionary time on the AGB and dust contribution. The same set of models are able to interpret the CNO surface abundances observed for the PNe of the same galaxies.


2019 ◽  
Vol 489 (4) ◽  
pp. 4890-4911 ◽  
Author(s):  
Jels Boulangier ◽  
D Gobrecht ◽  
L Decin ◽  
A de Koter ◽  
J Yates

ABSTRACT Unravelling the composition and characteristics of gas and dust lost by asymptotic giant branch (AGB) stars is important as these stars play a vital role in the chemical life cycle of galaxies. The general hypothesis of their mass-loss mechanism is a combination of stellar pulsations and radiative pressure on dust grains. However, current models simplify dust formation, which starts as a microscopic phase transition called nucleation. Various nucleation theories exist, yet all assume chemical equilibrium, growth restricted by monomers, and commonly use macroscopic properties for a microscopic process. Such simplifications for initial dust formation can have large repercussions on the type, amount, and formation time of dust. By abandoning equilibrium assumptions, discarding growth restrictions, and using quantum mechanical properties, we have constructed and investigated an improved nucleation theory in AGB wind conditions for four dust candidates, TiO2, MgO, SiO, and Al2O3. This paper reports the viability of these candidates as first dust precursors and reveals implications of simplified nucleation theories. Monomer restricted growth underpredicts large clusters at low temperatures and overpredicts formation times. Assuming the candidates are present, Al2O3 is the favoured precursor due to its rapid growth at the highest considered temperatures. However, when considering an initially atomic chemical mixture, only TiO2-clusters form. Still, we believe Al2O3 to be the prime candidate due to substantial physical evidence in presolar grains, observations of dust around AGB stars at high temperatures, and its ability to form at high temperatures and expect the missing link to be insufficient quantitative data of Al-reactions.


2021 ◽  
Author(s):  
◽  
Lisa Shepard

Stars between about 0.8 and 8 times the mass of the Sun will eventually evolve, becoming asymptotic giant branch (AGB) stars, where they pulsate and eject mass from their atmospheres, forming dust shells in the space around them. Evolved low- and intermediate-mass stars with carbon-to-oxygen ratios (C/O) below unity are known as oxygen-rich stars. O-rich stars are surrounded by dust shells containing mineral species dominated by silicate dust grains. In this dissertation, I examine whether dust grains around evolved, oxygen-rich AGB stars have any correlation with maser emission, and to understand the connection, if any, between specific types of maser emission and dust spectral features. I have investigated several methods of continuum elimination using spectroscopy data for the archetypal dusty AGB star, Mira. I have investigated the ~10[mu]m and ~18[mu]m spectral features in the continuum-eliminated spectrum including peak position, barycenter, and full width half maxima (FWHM). The positions and widthved spectral features were compared with those seen in laboratory spectra. I then looked for a correlation between maser emission and dust spectral features in a sample of Mira variables. The types of masers have been identified, and peak positions, barycenter positions, and FWHM have been measured for the sample spectra. The results show that the method of continuum elimination matters for correct identification of dust minerals, while varying the temperature and precise continuum shapes do not have a major effect on the positions of spectral features. Observed astronomical silicate features are complex and indicate the need for different compositions of minerals. Finally, there does not appear to be a correlation between the presence of a maser and dust spectral features based on the information available for analysis.


Universe ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 80
Author(s):  
Sergio Cristallo ◽  
Luciano Piersanti ◽  
David Gobrecht ◽  
Lucio Crivellari ◽  
Ambra Nanni

The interplay between AGB interiors and their outermost layers, where molecules and dust form, is a problem of high complexity. As a consequence, physical processes like mass loss, which depend on the chemistry of the circumstellar envelope, are often oversimplified. The best candidates to drive mass-loss in AGB stars are dust grains, which trap the outgoing radiation and drag the surrounding gas. Grains build up, however, is far from being completely understood. Our aim is to model both the physics and the chemistry of the cool expanding layers around AGB stars in order to characterize the on-going chemistry, from atoms to dust grains. This has been our rationale to develop ab initio VULCAN, a FORTRAN hydro code able to follow the propagation of shocks in the circumstellar envelopes of AGB stars. The version presented in this paper adopts a perfect gas law and a very simplified treatment of the radiative transfer effects and dust nucleation. In this paper, we present preliminary results obtained with our code.


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