Mitigating Structural Instability of High-Energy Lithium- and Manganese-Rich LiNixMnyCoz Oxide by Interfacial Atomic Surface Reduction

2019 ◽  
Vol 31 (10) ◽  
pp. 3840-3847 ◽  
Author(s):  
Rosy ◽  
Hadar Sclar ◽  
Eliran Evenstein ◽  
Shira Haber ◽  
Sandipan Maiti ◽  
...  
2019 ◽  
Vol 19 ◽  
pp. 261-269 ◽  
Author(s):  
Eliran Evenstein ◽  
Rosy ◽  
Shira Haber ◽  
Hadar Sclar ◽  
Lothar Houben ◽  
...  

Author(s):  
Rosy ◽  
Sarah Taragin ◽  
Eliran Evenstein ◽  
Sebastian Maletti ◽  
Daria Mikhailova ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yu-Jie Guo ◽  
Peng-Fei Wang ◽  
Yu-Bin Niu ◽  
Xu-Dong Zhang ◽  
Qinghao Li ◽  
...  

AbstractNa-ion cathode materials operating at high voltage with a stable cycling behavior are needed to develop future high-energy Na-ion cells. However, the irreversible oxygen redox reaction at the high-voltage region in sodium layered cathode materials generates structural instability and poor capacity retention upon cycling. Here, we report a doping strategy by incorporating light-weight boron into the cathode active material lattice to decrease the irreversible oxygen oxidation at high voltages (i.e., >4.0 V vs. Na+/Na). The presence of covalent B–O bonds and the negative charges of the oxygen atoms ensures a robust ligand framework for the NaLi1/9Ni2/9Fe2/9Mn4/9O2 cathode material while mitigating the excessive oxidation of oxygen for charge compensation and avoiding irreversible structural changes during cell operation. The B-doped cathode material promotes reversible transition metal redox reaction enabling a room-temperature capacity of 160.5 mAh g−1 at 25 mA g−1 and capacity retention of 82.8% after 200 cycles at 250 mA g−1. A 71.28 mAh single-coated lab-scale Na-ion pouch cell comprising a pre-sodiated hard carbon-based anode and B-doped cathode material is also reported as proof of concept.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Liguang Wang ◽  
Tongchao Liu ◽  
Alvin Dai ◽  
Vincent De Andrade ◽  
Yang Ren ◽  
...  

AbstractHigh-energy density lithium-rich layered oxides are among the most promising candidates for next-generation energy storage. Unfortunately, these materials suffer from severe electrochemical degradation that includes capacity loss and voltage decay during long-term cycling. Present research efforts are primarily focused on understanding voltage decay phenomena while origins for capacity degradation have been largely ignored. Here, we thoroughly investigate causes for electrochemical performance decline with an emphasis on capacity loss in the lithium-rich layered oxides, as well as reaction pathways and kinetics. Advanced synchrotron-based X-ray two-dimensional and three-dimensional imaging techniques are combined with spectroscopic and scattering techniques to spatially visualize the reactivity at multiple length-scales on lithium- and manganese-rich layered oxides. These methods provide direct evidence for inhomogeneous manganese reactivity and ionic nickel rearrangement. Coupling deactivated manganese with nickel migration provides sluggish reaction kinetics and induces serious structural instability in the material. Our findings provide new insights and further understanding of electrochemical degradation, which serve to facilitate cathode material design improvements.


2021 ◽  
pp. 2106294
Author(s):  
Arka Saha ◽  
Netanel Shpigel ◽  
Rosy ◽  
Nicole Leifer ◽  
Sarah Taragin ◽  
...  

Inorganics ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 13
Author(s):  
Biao Yuan ◽  
Enzheng Shi ◽  
Chao Liang ◽  
Letian Dou ◽  
Yi Yu

Organic–inorganic halide perovskites are promising photovoltaic materials with excellent optoelectronic properties. However, the extreme structural instability hinders their wide application as well as the microstructure characterization using high energy beams such as transmission electron microscopy (TEM). Here, taking BA2FAPb2I7 and BA2MAPb2I7 as examples, we investigate their structural evolution resulting from high energy electron irradiation, moist air, and low temperature, respectively. The results show that the long organic chains are the first to be damaged under electron beam, which is mainly arising from their instability and weak bonding with the framework of [PbI6]4− octahedrons. Then the short organic cations and the framework of [PbI6]4− octahedrons collapses gradually. The final products are clusters of detached PbI2 particles, which can also be observed in the sample degraded in moist air. In addition, the structures of BA2FAPb2I7 and BA2MAPb2I7 are discovered to undergo a phase transformation at liquid nitrogen temperature, which calls attention to the community that cryo-TEM methods should be used cautiously for organic–inorganic halide perovskite materials.


Author(s):  
Amar Patil ◽  
Nilesh Rajaram Chodankar ◽  
Euigeol Jung ◽  
Sanjib Baran Roy ◽  
Deepak P. Dubal ◽  
...  

The structural instability and sluggish kinetics of conventional positive electrodes with the lower capacitance of carbon-based negative electrodes result in an inferior performance for state-of-art supercapacitors (SCs). A general yet...


1984 ◽  
Vol 75 ◽  
pp. 599-602
Author(s):  
T.V. Johnson ◽  
G.E. Morfill ◽  
E. Grun

A number of lines of evidence suggest that the particles making up the E-ring are small, on the order of a few microns or less in size (Terrile and Tokunaga, 1980, BAAS; Pang et al., 1982 Saturn meeting; Tucson, AZ). This suggests that a variety of electromagnetic and plasma affects may be important in considering the history of such particles. We have shown (Morfill et al., 1982, J. Geophys. Res., in press) that plasma drags forces from the corotating plasma will rapidly evolve E-ring particle orbits to increasing distance from Saturn until a point is reached where radiation drag forces acting to decrease orbital radius balance this outward acceleration. This occurs at approximately Rhea's orbit, although the exact value is subject to many uncertainties. The time scale for plasma drag to move particles from Enceladus' orbit to the outer E-ring is ~104yr. A variety of effects also act to remove particles, primarily sputtering by both high energy charged particles (Cheng et al., 1982, J. Geophys. Res., in press) and corotating plasma (Morfill et al., 1982). The time scale for sputtering away one micron particles is also short, 102 - 10 yrs. Thus the detailed particle density profile in the E-ring is set by a competition between orbit evolution and particle removal. The high density region near Enceladus' orbit may result from the sputtering yeild of corotating ions being less than unity at this radius (e.g. Eviatar et al., 1982, Saturn meeting). In any case, an active source of E-ring material is required if the feature is not very ephemeral - Enceladus itself, with its geologically recent surface, appears still to be the best candidate for the ultimate source of E-ring material.


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