Synergetic Molecular Oxygen Activation and Catalytic Oxidation of Formaldehyde over Defective MIL-88B(Fe) Nanorods at Room Temperature

2021 ◽  
Author(s):  
Shuping Zhang ◽  
Yifan Zhuo ◽  
Chizoba I. Ezugwu ◽  
Chong-chen Wang ◽  
Chuanhao Li ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Room Temperature ◽  
Oxygen Activation

Improved Oxygen Activation over a Carbon/Co3O4 Nanocomposite for Efficient Catalytic Oxidation of Formaldehyde at Room Temperature

2021 ◽  
Vol 55 (6) ◽  
pp. 4054-4063
Author(s):  
Rong Li ◽  
Yu Huang ◽  
Dandan Zhu ◽  
Wingkei Ho ◽  
Junji Cao ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Room Temperature ◽  
Oxygen Activation

Oxygen activation by copper camphor complexes

2015 ◽  
Vol 2 (11) ◽  
pp. 1019-1028 ◽  
Author(s):  
Alexandra P. S. Roseiro ◽  
Pedro Adão ◽  
Adelino M. Galvão ◽  
João Costa Pessoa ◽  
Ana M. Botelho do Rego ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Oxygen Activation

In situreduction of CuCl2enables formation of Cu(i) complexes prone to activate molecular oxygen from air towards catalytic oxidation of 1,3-dicarbonyls.

Giant Electron–Hole Interactions in Confined Layered Structures for Molecular Oxygen Activation

2017 ◽  
Vol 139 (13) ◽  
pp. 4737-4742 ◽  
Author(s):  
Hui Wang ◽  
Shichuan Chen ◽  
Dingyu Yong ◽  
Xiaodong Zhang ◽  
Shuang Li ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Oxygen Activation ◽  
Layered Structures ◽  
Electron Hole

Fluorous Biphasic Catalytic Oxidation of Sulfides by Molecular Oxygen/2,2-Dimethylpropanal

2001 ◽  
Vol 2001 (1) ◽  
pp. 181-186 ◽  
Author(s):  
Stefano Colonna ◽  
Nicoletta Gaggero ◽  
Fernando Montanari ◽  
Gianluca Pozzi ◽  
Silvio Quici
Keyword(s):  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Oxidation Of Sulfides

Kinetic Model of the 1,2-Propanediol Oxidation Reaction in the Presence of 3wt%Pd/α-Al2O3 Catalyst

2021 ◽  
Vol 903 ◽  
pp. 143-148
Author(s):  
Svetlana Cornaja ◽  
Svetlana Zhizhkuna ◽  
Jevgenija Vladiko
Keyword(s):  
Activation Energy ◽  
Lactic Acid ◽  
Kinetic Model ◽  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Oxidation Reaction ◽  
Main Product ◽  
Oxidation Process ◽  
Water Solution ◽  
Reaction Conditions

Supported 3wt%Pd/α-Al₂O₃ catalyst was tested in selective oxidation of 1,2-propanediol by molecular oxygen. It was found that the catalyst is active in an alkaline water solution. Lactic acid was obtained as the main product of the reaction. Influence of different reaction conditions on 1,2-PDO conversion and oxidation process selectivity was studied. Partial kinetic orders of the reaction with respect to 1,2-propanediol, c0(NaOH), p(O2), n(1,2-PDO)/n(Pd)) were determined and an experimental kinetic model of the catalytic oxidation reaction was obtained. Activation energy of the process was calculated and was found to be about 53 ± 5 kJ/mol.

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