An anion-resin carrying the catalyst iron(II) tetra(1,4-dithin)porphyrazine, ( Fe (II) Pz ( dtn )4/resin), may effectively interact with the lone-pair electron of the sulfur in the Fe (II) Pz ( dtn )4 to keep the absorption for the catalyst molecule, which can efficiently activate molecular oxygen coordinated with iron(II) on the axial orientation of Fe (II) Pz ( dtn )4 through electron transfer in a heterogeneous process. On the other hand, the hydrophilic property of the resin also facilitates adsorption of the anion-substrates in the aqueous solution onto the unoccupied resin surface to increase the substrate concentration around the Fe (II) Pz ( dtn )4 and the contact probability between the substrate with activated molecular oxygen to promote the oxidative degradation of these adsorbed substrates. The stability and repeatability of the Fe (II) Pz ( dtn )4/resin were determined by some control experiments. The results indicate that Fe (II) Pz ( dtn )4 was stable enough in the presence of active oxygen species under irradiation of visible light and could degrade recalcitrant organic pollutants such as rhodamine B and p-nitrobenzoic acid. It can be reused at least 5 cycling runs without losing activity.
Theoretical Study of Sigmatropic Rearrangement of Cycloprop-2-en-1-ol and its Fluorine Derivatives: Pericyclic or Pseudopericyclic Character from NICS and LLPE
