Effect of Surface Nanopatterning on Slip: The Case of Couette Flow of Long-Chain Polyethylene Melt Flowing Past Gold Surfaces

Effect of molecular structure on polyethylene melt rheology. III. Effects of long-chain branching and of temperature on melt elasticity in shear

Journal of Applied Polymer Science ◽

10.1002/app.1973.070170312 ◽

1973 ◽

Vol 17 (3) ◽

pp. 797-808 ◽

Cited By ~ 22

Author(s):

R. A. Mendelson ◽

F. L. Finger

Keyword(s):

Molecular Structure ◽

Melt Rheology ◽

Chain Branching ◽

Long Chain Branching ◽

Melt Elasticity ◽

Polyethylene Melt ◽

Long Chain

Reaction of Long-Chain Iodoalkanes with Gold Surfaces

Journal of Colloid and Interface Science ◽

10.1006/jcis.1998.5462 ◽

1998 ◽

Vol 202 (1) ◽

pp. 167-172 ◽

Cited By ~ 18

Author(s):

Martina Hirayama ◽

Walter R. Caseri ◽

Ulrich W. Suter

Keyword(s):

Gold Surfaces ◽

Long Chain

An advanced Monte Carlo method for the equilibration of model long-chain branched polymers with a well-defined molecular architecture: Detailed atomistic simulation of an H-shaped polyethylene melt

The Journal of Chemical Physics ◽

10.1063/1.1543580 ◽

2003 ◽

Vol 118 (6) ◽

pp. 2451 ◽

Cited By ~ 28

Author(s):

Nikos Ch. Karayiannis ◽

Ageliki E. Giannousaki ◽

Vlasis G. Mavrantzas

Keyword(s):

Monte Carlo ◽

Monte Carlo Method ◽

Atomistic Simulation ◽

Branched Polymers ◽

Molecular Architecture ◽

Polyethylene Melt ◽

Long Chain

Electrochemical and vibrational spectroscopic studies of coadsorption: the formation of mixed monolayers of methylene blue and long-chain dithioethers at sulfur-modified polycrystalline gold surfaces

Langmuir ◽

10.1021/la00095a024 ◽

1990 ◽

Vol 6 (5) ◽

pp. 1023-1030 ◽

Cited By ~ 17

Author(s):

Barbara J. Barner ◽

Robert M. Corn

Keyword(s):

Methylene Blue ◽

Spectroscopic Studies ◽

Gold Surfaces ◽

Mixed Monolayers ◽

Polycrystalline Gold ◽

Long Chain

ChemInform Abstract: Catalytic Reactions on Model Gold Surfaces: Effect of Surface Steps and of Surface Doping

ChemInform ◽

10.1002/chin.201233220 ◽

2012 ◽

Vol 43 (33) ◽

pp. no-no

Author(s):

Jose L. C. Fajin ◽

Maria Natalia D. S. Cordeiro ◽

Jose R. B. Gomes

Keyword(s):

Catalytic Reactions ◽

Gold Surfaces ◽

Surface Doping ◽

Surface Steps ◽

Effect Of Surface

ON THE CONTRIBUTION OF LONG CHAIN BRANCHING TO POLYETHYLENE MELT RHEOLOGY

Chemical Engineering Communications ◽

10.1080/00986448308940077 ◽

1983 ◽

Vol 24 (1-3) ◽

pp. 139-146 ◽

Cited By ~ 4

Author(s):

W.M. WHITTE ◽

J.C. RANDALL ◽

C.H. LEIGH

Keyword(s):

Melt Rheology ◽

Chain Branching ◽

Long Chain Branching ◽

Polyethylene Melt ◽

Long Chain

Electro-catalytic scission of carbon–iodine bonds. Building of SAMs at gold surfaces through long chain primary radical adsorption

Electrochemistry Communications ◽

10.1016/j.elecom.2013.11.003 ◽

2014 ◽

Vol 38 ◽

pp. 65-67 ◽

Cited By ~ 2

Author(s):

Jacques Simonet ◽

Viatcheslav Jouikov

Keyword(s):

Gold Surfaces ◽

Primary Radical ◽

Radical Adsorption ◽

Long Chain

Catalytic Reactions on Model Gold Surfaces: Effect of Surface Steps and of Surface Doping

Catalysts ◽

10.3390/catal1010040 ◽

2011 ◽

Vol 1 (1) ◽

pp. 40-51 ◽

Cited By ~ 6

Author(s):

José L. C. Fajín ◽

Maria Natália D. S. Cordeiro ◽

José R. B. Gomes

Keyword(s):

Catalytic Reactions ◽

Gold Surfaces ◽

Surface Doping ◽

Surface Steps ◽

Effect Of Surface

Atomistic simulations of long-chain polyethylene melts flowing past gold surfaces: structure and wall-slip

Molecular Physics ◽

10.1080/00268976.2019.1706775 ◽

2020 ◽

Vol 118 (9-10) ◽

pp. e1706775 ◽

Cited By ~ 1

Author(s):

A. P. Sgouros ◽

D. N. Theodorou

Keyword(s):

Wall Slip ◽

Atomistic Simulations ◽

Gold Surfaces ◽

Polyethylene Melts ◽

Long Chain

Self-assembly of short and long-chain n-alkyl thiols onto gold surfaces: A real-time study using surface plasmon resonance techniques

Canadian Journal of Chemistry ◽

10.1139/v96-073 ◽

1996 ◽

Vol 74 (5) ◽

pp. 677-688 ◽

Cited By ~ 56

Author(s):

Reno F. Debono ◽

Glenn D. Loucks ◽

Deborah Della Manna ◽

Ulrich J. Krull

Keyword(s):

Surface Plasmon Resonance ◽

Real Time ◽

Surface Plasmon ◽

Plasmon Resonance ◽

Self Assembly ◽

The Self ◽

Gold Surfaces ◽

Step Process ◽

Long Chain

Gold surfaces coated with monolayers of alkyl thiols are significant in the field of biosensors and chromatography. There is a general concern about the quality of coatings in terms of surface density and voids. The self-assembly of the short-chain hexane (C6) thiol and long-chain dodecane (C12) and hexadecane (C16) thiols to polycrystalline gold surfaces has been investigated in situ and in real time using surface plasmon resonance (SPR) spectroscopy and surface plasmon microscopy (SPM). The self-assembly was followed based on observed changes in reflectivity at a fixed angle of incidence as a function of time. Our results indicate that the data for hexane, dodecane, and hexadecane thiol adsorption to gold surfaces were best fit by a two-step process rather than a one-step process. The mechanism may involve fast adsorption to the surface to give 80% (C12, C16) or 50% (C6) coverage followed by a slow (100-fold slower) "rearrangement" of the adsorbed thiol. SPM shows these surfaces to be smooth and homogenous at a 4 μm scale. An understanding of the process of rearrangement could lead to control of the quality of coatings for analytical applications. Key words: surface plasmon, alkyl thiols, gold, monolayer, kinetics, ellipsometry, microscopy.