Ligand Dependent Growth and Optical Properties of Hybrid Organo-metal Halide Perovskite Magic Sized Clusters

2019 ◽  
Vol 123 (30) ◽  
pp. 18746-18752 ◽  
Author(s):  
Evan T. Vickers ◽  
Ke Xu ◽  
Benjamin W. Dreskin ◽  
Thomas A. Graham ◽  
Xueming Li ◽  
...  
Nanomaterials ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 151
Author(s):  
Ivan D. Skurlov ◽  
Wenxu Yin ◽  
Azat O. Ismagilov ◽  
Anton N. Tcypkin ◽  
Haohang Hua ◽  
...  

Metal halide perovskite nanocrystals (NCs) attract much attention for light-emitting applications due to their exceptional optical properties. More recently, perovskite NCs have begun to be considered a promising material for nonlinear optical applications. Numerous strategies have recently been developed to improve the properties of metal halide perovskite NCs. Among them, B-site doping is one of the most promising ways to enhance their brightness and stability. However, there is a lack of study of the influence of B-site doping on the nonlinear optical properties of inorganic perovskite NCs. Here, we demonstrate that Cd2+ doping simultaneously improves both the linear (higher photoluminescence quantum yield, larger exciton binding energy, reduced trap states density, and faster radiative recombination) and nonlinear (higher two- and three-photon absorption cross-sections) optical properties of CsPbBr3 NCs. Cd2+ doping results in a two-photon absorption cross-section, reaching 2.6 × 106 Goeppert-Mayer (GM), which is among the highest reported for CsPbBr3 NCs.


2019 ◽  
Vol 119 (5) ◽  
pp. 3296-3348 ◽  
Author(s):  
Javad Shamsi ◽  
Alexander S. Urban ◽  
Muhammad Imran ◽  
Luca De Trizio ◽  
Liberato Manna

Author(s):  
Lorenzo Malavasi ◽  
Luca Bindi ◽  
Mauro Coduri ◽  
Filippo De Angelis ◽  
Francesco Fracassi ◽  
...  

The elucidation of the structure-property correlation in 2D metal halide perovskite is a key issue to understand the dependence of optical properties on structural distortions and to design novel tailored...


Author(s):  
Zhousu Xu ◽  
Tao Chen ◽  
Duoduo Zhang ◽  
Guojun Zheng ◽  
Zhuo Wang ◽  
...  

All inorganic metal halide perovskite quantum dots (QDs) exhibit excellent optical properties promising for diverse applications, while their inherent frangibility remains an enormous challenge for both scientific research and practical...


Author(s):  
Khagendra P. Bhandari ◽  
Anup Lamichhane ◽  
Travis Maenle ◽  
Ebin Bastola ◽  
Randy J. Ellingson

Author(s):  
Christian Kriso ◽  
Markus Stein ◽  
Tobias Haeger ◽  
Neda Pourdavoud ◽  
Marina Gerhard ◽  
...  

2019 ◽  
Author(s):  
Michael Worku ◽  
Yu Tian ◽  
Chenkun Zhou ◽  
Haoran Lin ◽  
Maya Chaaban ◽  
...  

Metal halide perovskite nanocrystals (NCs) have emerged as a new generation light emitting materials with narrow emissions and high photoluminescence quantum efficiencies (PLQEs). Various types of perovskite NCs, e.g. platelets, wires, and cubes, have been discovered to exhibit tunable emissions across the whole visible spectral region. Despite remarkable advances in the field of metal halide perovskite NCs over the last few years, many nanostructures in inorganic NCs have yet been realized in metal halide perovskites and producing highly efficient blue emitting perovskite NCs remains challenging and of great interest. Here we report for the first time the discovery of highly efficient blue emitting cesium lead bromide perovskite (CsPbBr3) NCs with hollow structures. By facile solution processing of cesium lead bromide perovskite precursor solution containing additional ethylenediammonium bromide and sodium bromide, in-situ formation of hollow CsPbBr3 NCs with controlled particle and pore sizes is realized. Synthetic control of hollow nanostructures with quantum confinement effects results in color tuning of CsPbBr3 NCs from green to blue with high PLQEs of up to 81 %.<br><div><br></div>


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