Fabrication of Structurally Controlled Poly(n-butyl acrylate) Particles by Ab Initio Emulsion Organotellurium-Mediated Radical Polymerization. Synthesis of High Molecular Weight Homo and Block Copolymers

2021 ◽  
Author(s):  
Yuhan Jiang ◽  
Weijia Fan ◽  
Masatoshi Tosaka ◽  
Michael F. Cunningham ◽  
Shigeru Yamago
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
Ab Initio ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Butyl Acrylate

High Molecular Weight Block Copolymers by Sequential Monomer Addition via Cu(0)-Mediated Living Radical Polymerization (SET-LRP): An Optimized Approach

2013 ◽  
Vol 2 (10) ◽  
pp. 896-900 ◽  
Author(s):  
Athina Anastasaki ◽  
Christopher Waldron ◽  
Paul Wilson ◽  
Cyrille Boyer ◽  
Per B. Zetterlund ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Sequential Monomer Addition

High-molecular-weight polar acrylate block copolymers as high-performance dismantlable adhesive materials in response to photoirradiation and postbaking

RSC Advances ◽  
2014 ◽  
Vol 4 (47) ◽  
pp. 24719-24728 ◽  
Author(s):  
Tadashi Inui ◽  
Eriko Sato ◽  
Akikazu Matsumoto
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Failure Mode ◽  
Adhesion Strength ◽  
High Performance ◽  
Living Radical Polymerization ◽  
Controlled Synthesis ◽  
Adhesive Materials

Controlled synthesis of block copolymers as dismantlable adhesives using an organotellurium-mediated living radical polymerization (TERP) for discussion of adhesion strength and failure mode.

scholarly journals Synergistic toughening of polypropylene with ultra-high molecular weight polyethylene and elastomer-olefin block copolymers

RSC Advances ◽  
2019 ◽  
Vol 9 (41) ◽  
pp. 23994-24002 ◽  
Author(s):  
Lucheng Qi ◽  
Lei Wu ◽  
Ren He ◽  
Hui Cheng ◽  
Boping Liu ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
Rheological Properties ◽  
High Molecular Weight ◽  
Twin Screw Extruder ◽  
Screw Extruder ◽  
Twin Screw ◽  
Ultra High Molecular Weight

Blends of polypropylene (PP) and ultra-high molecular weight polyethylene (UHMWPE) with elastomer-olefin block copolymers (OBC) were prepared using an ultrasonic twin-screw extruder, and their mechanical and rheological properties were investigated.

Synthesis of high-molecular-weight polyamine by radical polymerization ofN,N-diallyl-N-methylamine

2000 ◽  
Vol 49 (3) ◽  
pp. 431-437 ◽  
Author(s):  
Yu. A. Vasilieva ◽  
N. A. Kleshcheva ◽  
G. L. Gromova ◽  
A. I. Rebrov ◽  
M. P. Filatova ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Radical Polymerization

Synthesis of high molecular weight poly(n-butyl acrylate) macromolecules via seATRP: From polymer stars to molecular bottlebrushes

2020 ◽  
Vol 126 ◽  
pp. 109566 ◽  
Author(s):  
Izabela Zaborniak ◽  
Paweł Chmielarz ◽  
Michael R. Martinez ◽  
Karol Wolski ◽  
Zongyu Wang ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Butyl Acrylate ◽  
High Molecular Weight Poly

Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhengji Song ◽  
Carole Pelletier ◽  
Yinghua Qi ◽  
Jasim Ahmed ◽  
Sunil K. Varshney ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Alkyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
H Nmr

AbstractABA and/or ABC type triblock copolymers were synthesized by living anionic and controlled radical polymerization in which poly(methyl methacrylate) was used as central block. The structural composition of these block copolymers were determined by 1H NMR. The block length/molecular weight and microstructure of these polymers were measured by SEC. The microstructure of resultant central alkyl methacrylate block can be tailored from highly syndiotactic to highly isotactic structure by varying the solvent and/or initiator. The thermal and rheological properties of center poly(methyl methacrylate) block and poly(styreneb- methyl methacrylate-b- styrene) tri block copolymers were studied in detail.

Efficient synthesis of narrowly dispersed amphiphilic double-brush copolymers through the polymerization reaction of macromonomer micelle emulsifiers at the oil–water interface

2016 ◽  
Vol 7 (27) ◽  
pp. 4476-4485 ◽  
Author(s):  
Heng Li ◽  
Han Miao ◽  
Yong Gao ◽  
Huaming Li ◽  
Daoyong Chen
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Pickering Emulsion ◽  
Polymerization Reaction ◽  
Water Interface ◽  
Efficient Synthesis ◽  
Oil Water

Narrowly dispersed amphiphilic PMA-g-PMMA/PDMA DBCs with high molecular weight were efficiently synthesized by Pickering emulsion template directed radical polymerization of macromonomer micelles.

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