Manifestation of an Enhanced Photoreduction of CO2 to CO over the In Situ Synthesized rGO–Covalent Organic Framework under Visible Light Irradiation

Author(s):  
Vishnu Nair Gopalakrishnan ◽  
Duc-Trung Nguyen ◽  
Jorge Becerra ◽  
Mohan Sakar ◽  
Jason M. E. Ahad ◽  
...  
2017 ◽  
Vol 5 (44) ◽  
pp. 22933-22938 ◽  
Author(s):  
Yongfeng Zhi ◽  
Ziping Li ◽  
Xiao Feng ◽  
Hong Xia ◽  
Yumin Zhang ◽  
...  

A robust two-dimensional covalent organic framework (COF-JLU5), which exhibits excellent heterogeneous photocatalytic performances for oxidative C–H functionalizations under visible-light irradiation using O2as a green oxygen source, is reported.


Author(s):  
Ziling Liu ◽  
Yaqi Huang ◽  
Shuqing Chang ◽  
Xiaoli Zhu ◽  
Yanghe Fu ◽  
...  

Highly dispersed Ru nanoparticles are confined in a photosensitizing bipyridine-linked covalent organic framework to construct Ru@TpBpy composites, exhibiting significantly enhanced activities for CO2 reduction under visible-light irradiation.


Author(s):  
Jin-Xian Cui ◽  
Lu-Jie Wang ◽  
Feng Liu ◽  
Bo Meng ◽  
Zi-Yan Zhou ◽  
...  

A β-ketoenamine-based COF is used as photocatalyst to convert CO2 and H2O into CO and O2 under visible-light irradiation without additional photosensitizers and sacrificial agents in gas-solid system. When CO2...


Author(s):  
Chenxiang Lin ◽  
Chaozheng Han ◽  
Lei Gong ◽  
Xin Chen ◽  
Jinxia Deng ◽  
...  

A donor–acceptor type covalent organic framework (COF) was used to construct TBTA/g-C3N4 hybrids for photocatalytic H2 evolution. Under visible light irradiation, the hybrids exhibited an optimized H2 evolution rate of 11.73 mmol g−1 h−1 without Pt.


2021 ◽  
Author(s):  
Jingjing Xu ◽  
Yang liu ◽  
xueping li ◽  
Mindong Chen

Direct Z-scheme Bi3TaO7/Zn0.5Cd0.5S composite photocatalysts were successfully prepared via an in-situ growth hydrothermal method. The photocatalytic activities of composites were investigated by the degradation of levofloxacin under visible light. And...


2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.


2019 ◽  
Vol 9 (10) ◽  
pp. 2563-2570 ◽  
Author(s):  
Yuanguo Xu ◽  
Feiyue Ge ◽  
Meng Xie ◽  
Shuquan Huang ◽  
Junchao Qian ◽  
...  

An in situ photo-Fenton-like and magnetic recycle system, BaFe12O19/Ag3PO4 has been constructed. BaFe12O19 can catalyze the conversion of H2O2 to generate ROSs (˙O2− and ˙OH radicals) on the surface of Ag3PO4.


2020 ◽  
Vol 22 (1) ◽  
pp. 22-27 ◽  
Author(s):  
Yuannian Zhang ◽  
Xin Yang ◽  
Haidi Tang ◽  
Dong Liang ◽  
Jie Wu ◽  
...  

Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons and oxidation of sulfides via in situ generation of H2O2 from O2 under visible light irradiation.


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