Aerosol Jet-Printed LFP Cathodes with Bimodal Pore Distribution Improve the Rate Capability of LIB Cells

2021 ◽  
Vol 4 (9) ◽  
pp. 9507-9512
Author(s):  
Rodrigo Rodriguez ◽  
L. Jay Deiner ◽  
Bang Hung Tsao ◽  
Joseph P. Fellner
Keyword(s):  
Rate Capability ◽  
Pore Distribution

Superionic Lithium Intercalation through 2 nm x 2 nm Columns in the Crystallographic Shear Phase Nb18W8O69

2019 ◽  
Author(s):  
Kent Griffith ◽  
Clare Grey
Keyword(s):  
High Performance ◽  
Rate Capability ◽  
Block Size ◽  
Lithium Intercalation ◽  
Resonance Spectroscopy ◽  
Complex Metal Oxides ◽  
Battery Electrode ◽  
Crystallographic Shear ◽  
Battery Material ◽  
First Time

Nb18W8O69 (9Nb2O5×8WO3) is the tungsten-rich end-member of the Wadsley–Roth crystallographic shear (cs) structures within the Nb2O5–WO3 series. It has the largest block size of any known, stable Wadsley–Roth phase, comprising 5 ´ 5 units of corner-shared MO6 octahedra between the shear planes, giving rise to 2 nm ´ 2 nm blocks. Rapid lithium intercalation is observed in this new candidate battery material and 7Li pulsed field gradient nuclear magnetic resonance spectroscopy – measured in a battery electrode for the first time at room temperature – reveals superionic lithium conductivity. In addition to its promising rate capability, Nb18W8O69 adds a piece to the larger picture of our understanding of high-performance Wadsley–Roth complex metal oxides.

Ultrathin Carbon Nanosheets for Highly-efficient Capacitive K-ion and Zn-ion Storage

2020 ◽  
Author(s):  
Yamin Zhang ◽  
Zhongpu Wang ◽  
Deping Li ◽  
Qing Sun ◽  
Kangrong Lai ◽  
...  
Keyword(s):  
Energy Storage ◽  
Porous Carbon ◽  
Metal Ion ◽  
Rate Capability ◽  
Energy Storage Devices ◽  
Capacity Retention ◽  
Carbon Nanosheets ◽  
Storage Devices ◽  
High Efficient ◽  
Ion Storage

<p></p><p>Porous carbon has attracted extensive attentions as the electrode material for various energy storage devices considering its advantages like high theoretical capacitance/capacity, high conductivity, low cost and earth abundant inherence. However, there still exists some disadvantages limiting its further applications, such as the tedious fabrication process, limited metal-ion transport kinetics and undesired structure deformation at harsh electrochemical conditions. Herein, we report a facile strategy, with calcium gluconate firstly reported as the carbon source, to fabricate ultrathin porous carbon nanosheets. <a>The as-prepared Ca-900 electrode delivers excellent K-ion storage performance including high reversible capacity (430.7 mAh g<sup>-1</sup>), superior rate capability (154.8 mAh g<sup>-1</sup> at an ultrahigh current density of 5.0 A g<sup>-1</sup>) and ultra-stable long-term cycling stability (a high capacity retention ratio of ~81.2% after 4000 cycles at 1.0 A g<sup>-1</sup>). </a>Similarly, when being applied in Zn-ion capacitors, the Ca-900 electrode also exhibits an ultra-stable cycling performance with ~90.9% capacity retention after 4000 cycles at 1.0 A g<sup>-1</sup>, illuminating the applicable potentials. Moreover, the origin of the fast and smooth metal-ion storage is also revealed by carefully designed consecutive CV measurements. Overall, considering the facile preparation strategy, unique structure, application flexibility and in-depth mechanism investigations, this work will deepen the fundamental understandings and boost the commercialization of high-efficient energy storage devices like potassium-ion/sodium-ion batteries, zinc-ion batteries/capacitors and aluminum-ion batteries.</p><br><p></p>

Self-assembly Nb2O5 microsphere with hollow and carbon coated structure as high rate capability lithium-ion electrode materials

2020 ◽  
Vol 331 ◽  
pp. 135364 ◽  
Author(s):  
Jiajun Hu ◽  
Jiajia Li ◽  
Kai Wang ◽  
Hongyan Xia
Keyword(s):  
Self Assembly ◽  
Electrode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Rate ◽  
High Rate Capability ◽  
Carbon Coated

Unveiling the Synergic Roles of Mg/Zr Co-Doping on Rate Capability and Cycling Stability of Li4Ti5O12

2019 ◽  
Vol 166 (4) ◽  
pp. A658-A666 ◽  
Author(s):  
Zhenya Wang ◽  
Limei Sun ◽  
Wenyun Yang ◽  
Jinbo Yang ◽  
Kai Sun ◽  
...  
Keyword(s):  
Rate Capability ◽  
Cycling Stability ◽  
Co Doping

scholarly journals High-Mass Loading Hierarchically Porous Activated Carbon Electrode for Pouch-Type Supercapacitors with Propylene Carbonate-Based Electrolyte

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 785
Author(s):  
Tai-Feng Hung ◽  
Tzu-Hsien Hsieh ◽  
Feng-Shun Tseng ◽  
Lu-Yu Wang ◽  
Chang-Chung Yang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Propylene Carbonate ◽  
Rational Design ◽  
Rate Capability ◽  
High Mass ◽  
Electrochemical Performances ◽  
Mass Loading ◽  
Hierarchically Porous ◽  
Symmetric Supercapacitor ◽  
Porous Activated Carbon

Rational design and development of the electrodes with high-mass loading yet maintaining the excellent electrochemical properties are significant for a variety of electrochemical energy storage applications. In comparison with the slurry-casted electrode, herein, a hierarchically porous activated carbon (HPAC) electrode with higher mass loading (8.3 ± 0.2 mg/cm2) is successfully prepared. The pouch-type symmetric device (1 cell) with the propylene carbonate-based electrolyte shows the rate capability (7.1 F at 1 mA/cm2 and 4.8 F at 10 mA/cm2) and the cycling stability (83% at 12,000 cycles). On the other hand, an initial discharge capacitance of 32.4 F and the capacitance retention of 96% after 30,000 cycles are delivered from a pouch-type symmetric supercapacitor (five cells). The corresponding electrochemical performances are attributed to the fascinating properties of the HPAC and the synergistic features of the resulting electrode.

scholarly journals Effect of disordered pore distribution on the fracture of brittle porous media studied by bonded DEM

2021 ◽  
Author(s):  
Quanshui Huang ◽  
Gang Ma ◽  
Takashi Matsushima ◽  
Wei Zhou ◽  
Mingchun Lin
Keyword(s):  
Porous Media ◽  
Pore Distribution

A SnO2@carbon nanocluster anode material with superior cyclability and rate capability for lithium-ion batteries

Nanoscale ◽  
2013 ◽  
Vol 5 (8) ◽  
pp. 3298 ◽  
Author(s):  
Min He ◽  
Lixia Yuan ◽  
Xianluo Hu ◽  
Wuxing Zhang ◽  
Jie Shu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Rate Capability ◽  
Lithium Ion

Enabling superior rate capability and reliable sodium ion batteries by employing galvanostatic-potentiostatic operation mode

2021 ◽  
Vol 496 ◽  
pp. 229834
Author(s):  
Yi Wan ◽  
Yanling Qiu ◽  
Canpei Wang ◽  
Huamin Zhang ◽  
Qiong Zheng ◽  
...  
Keyword(s):  
Operation Mode ◽  
Rate Capability ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Hexagonal petal-like cobalt oxide nanowire arrays encapsulated by MOF-derived Co/N-codoped carbon for boosting electrochemical capacitor behaviour

2021 ◽  
Author(s):  
Xiao-Man Cao ◽  
Zhi-Jia Sun ◽  
Zheng-Bo Han
Keyword(s):  
Cobalt Oxide ◽  
Rate Capability ◽  
Electrochemical Capacitor ◽  
Nanowire Arrays ◽  
Core Shell ◽  
Unique Structure ◽  
Good Rate Capability

A novel core–shell hetero-structured electrode (NF@CoO@Co/N–C) is designed and synthesized via a “anchor-etch-calcine” process for boosting electrochemical capacitor behaviour. The unique structure endows NF@CoO@Co/N–C with ultrahigh areal capacitances and good rate capability.

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