Improving Cycling Performance of Si-Based Lithium Ion Batteries Anode with Se-Loaded Carbon Coating

2019 ◽  
Vol 2 (7) ◽  
pp. 5124-5132 ◽  
Author(s):  
Xin Gu ◽  
Wang Tian ◽  
Xiaoqiang Tian ◽  
Yaqin Ding ◽  
Xiaofeng Jia ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (58) ◽  
pp. 36735-36743 ◽  
Author(s):  
Liyong Wang ◽  
Zhanjun Liu ◽  
Quangui Guo ◽  
Xiaohui Guo ◽  
Jianjun Gu

Hollow graphite fibers and carbon coating were applied to improve lithium storage and cycling performance of silicon nanoparticles.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4348
Author(s):  
Chi Zhang ◽  
Zheng Wang ◽  
Yu Cui ◽  
Xuyao Niu ◽  
Mei Chen ◽  
...  

The volume expansion during Li ion insertion/extraction remains an obstacle for the application of Sn-based anode in lithium ion-batteries. Herein, the nanoporous (np) Cu6Sn5 alloy and Cu6Sn5/Sn composite were applied as a lithium-ion battery anode. The as-dealloyed np-Cu6Sn5 has an ultrafine ligament size of 40 nm and a high BET-specific area of 15.9 m2 g−1. The anode shows an initial discharge capacity as high as 1200 mA h g−1, and it remains a capacity of higher than 600 mA h g−1 for the initial five cycles at 0.1 A g−1. After 100 cycles, the anode maintains a stable capacity higher than 200 mA h g−1 for at least 350 cycles, with outstanding Coulombic efficiency. The ex situ XRD patterns reveal the reverse phase transformation between Cu6Sn5 and Li2CuSn. The Cu6Sn5/Sn composite presents a similar cycling performance with a slightly inferior rate performance compared to np-Cu6Sn5. The study demonstrates that dealloyed nanoporous Cu6Sn5 alloy could be a promising candidate for lithium-ion batteries.


2017 ◽  
Vol 5 (44) ◽  
pp. 23221-23227 ◽  
Author(s):  
Hao Wang ◽  
Ziliang Chen ◽  
Yang Liu ◽  
Hongbin Xu ◽  
Licheng Cao ◽  
...  

Hybrid nanocomposites constructed from starfish-like ZnxCo1−xS rooted in porous carbon and strongly coupled carbon nanotubes have been rationally designed and they exhibit excellent lithium-storage performance.


2021 ◽  
Vol MA2021-01 (2) ◽  
pp. 124-124
Author(s):  
Shuo Zhou ◽  
Shan Fang ◽  
Chen Fang ◽  
Gao Liu

2016 ◽  
Vol 724 ◽  
pp. 87-91 ◽  
Author(s):  
Chang Su Kim ◽  
Yong Hoon Cho ◽  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim

We investigated the electrochemical properties of carbon-coated niobium dioxide (NbO2) as a negative electrode material for lithium-ion batteries. Carbon-coated NbO2 powders were synthesized by ball-milling using carbon nanotubes as the carbon source. The carbon-coated NbO2 samples were of smaller particle size compared to the pristine NbO2 samples. The carbon layers were coated non-uniformly on the NbO2 surface. The X-ray diffraction patterns confirmed that the inter-layer distances increased after carbon coating by ball-milling. This lead to decreased charge-transfer resistance, confirmed by electrochemical impedance spectroscopy, allowing electrons and lithium-ions to quickly transfer between the active material and electrolyte. Electrochemical performance, including capacity and initial coulombic efficiency, was therefore improved by carbon coating by ball-milling.


2015 ◽  
Vol 3 (7) ◽  
pp. 3962-3967 ◽  
Author(s):  
Xiaolei Wang ◽  
Ge Li ◽  
Fathy M. Hassan ◽  
Matthew Li ◽  
Kun Feng ◽  
...  

High-performance robust CNT–graphene–Si composites are designed as anode materials with enhanced rate capability and excellent cycling stability for lithium-ion batteries. Such an improvement is mainly attributed to the robust sponge-like architecture, which holds great promise in future practical applications.


2019 ◽  
Vol 237 ◽  
pp. 224-227 ◽  
Author(s):  
S. Karthickprabhu ◽  
Dhanasekaran Vikraman ◽  
A. Kathalingam ◽  
K. Prasanna ◽  
Hyun-Seok Kim ◽  
...  

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