Shining Light on Cyclopentadienone–Norbornadiene Diels–Alder Adducts to Enable Photoinduced Click Chemistry with Cyclopentadiene

A catalytic enzyme-linked click chemistry assay (cat-ELCCA) for Dicer-catalyzed pre-microRNA maturation was optimized to employ inverse-electron demand Diels–Alder (IEDDA) chemistry affording high-throughput screening capability.

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Self-healable Functional Polymers based on Diels-Alder ‘Click Chemistry’ Involving Substituted Furan and Triazolinedione Derivatives; A Simple and Very Fast Approach

Polymer Chemistry ◽

10.1039/d1py00910a ◽

2021 ◽

Author(s):

Prantik Mondal ◽

Gourhari Jana ◽

Tuhin Subhra Pal ◽

Pratim K. Chattaraj ◽

Nikhil K Singha

Keyword(s):

Click Chemistry ◽

Materials Science ◽

Functional Polymers ◽

Diels Alder ◽

Polymer Materials ◽

Self Healing ◽

Natural Phenomena ◽

Science And Engineering ◽

Fast Approach ◽

Materials Science And Engineering

Nowadays, the design of functional polymer materials that can mimic natural phenomena, e.g., self-healing of skin cuts, has got a tremendous interest in materials science and engineering. Recently, 1,2,4-triazoline-3,5-dione (TAD)...

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An Eco-Friendly Scheme for the Cross-Linked Polybutadiene Elastomer via Thiol–Ene and Diels–Alder Click Chemistry

Macromolecules ◽

10.1021/acs.macromol.5b00389 ◽

2015 ◽

Vol 48 (11) ◽

pp. 3539-3546 ◽

Cited By ~ 92

Author(s):

Jing Bai ◽

Hui Li ◽

Zixing Shi ◽

Jie Yin

Keyword(s):

Click Chemistry ◽

Diels Alder ◽

The Cross

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Adding Spatial Control to Click Chemistry: Phototriggered Diels-Alder Surface (Bio)functionalization at Ambient Temperature

Angewandte Chemie International Edition ◽

10.1002/anie.201107095 ◽

2011 ◽

Vol 51 (4) ◽

pp. 1071-1074 ◽

Cited By ~ 143

Author(s):

Thomas Pauloehrl ◽

Guillaume Delaittre ◽

Volker Winkler ◽

Alexander Welle ◽

Michael Bruns ◽

...

Keyword(s):

Ambient Temperature ◽

Click Chemistry ◽

Diels Alder ◽

Spatial Control

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Correction: An injectable hyaluronic acid/PEG hydrogel for cartilage tissue engineering formed by integrating enzymatic crosslinking and Diels–Alder “click chemistry”

Polymer Chemistry ◽

10.1039/c8py90106f ◽

2018 ◽

Vol 9 (28) ◽

pp. 3959-3960 ◽

Cited By ~ 1

Author(s):

Feng Yu ◽

Xiaodong Cao ◽

Yuli Li ◽

Lei Zeng ◽

Bo Yuan ◽

...

Keyword(s):

Tissue Engineering ◽

Hyaluronic Acid ◽

Click Chemistry ◽

Cartilage Tissue Engineering ◽

Diels Alder ◽

Cartilage Tissue

Correction for ‘An injectable hyaluronic acid/PEG hydrogel for cartilage tissue engineering formed by integrating enzymatic crosslinking and Diels–Alder “click chemistry”’ by Feng Yu et al., Polym. Chem., 2014, 5, 1082–1090.

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Improving excretory pathways of technetium-99m SPECT imaging agents based on bioorthogonal Diels-Alder click chemistry

Nuclear Medicine and Biology ◽

10.1016/s0969-8051(19)30366-x ◽

2019 ◽

Vol 72-73 ◽

pp. S65

Author(s):

J. Walsh ◽

L. Francesconi ◽

V. Sanders ◽

D. Iskhakov ◽

B. Zeglis ◽

...

Keyword(s):

Click Chemistry ◽

Diels Alder ◽

Spect Imaging ◽

Imaging Agents ◽

Technetium 99M

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A mutually stabilized host-guest pair

Science Advances ◽

10.1126/sciadv.aax6707 ◽

2019 ◽

Vol 5 (11) ◽

pp. eaax6707 ◽

Cited By ~ 1

Author(s):

Chi Zhang ◽

Hongye Wang ◽

Jie Zhong ◽

Ye Lei ◽

Renfeng Du ◽

...

Keyword(s):

Click Chemistry ◽

Uv Light ◽

Alder Reaction ◽

Diels Alder ◽

Protecting Group ◽

Face To Face ◽

Π Interactions ◽

Diels Alder Reaction

By using click chemistry, a hexacationic cage was synthesized. The cage contains two triscationic π-electron–deficient trispyridiniumtriazine (TPZ3+) platforms that are bridged in a face-to-face manner by three ethylene-triazole-ethylene linkers. A diversity of π-electron–rich guests can be recognized within the pocket of the cage, driven by host-guest π-π interactions. The cage cavity acts as a protecting group, preventing an anthracene guest from undergoing Diels-Alder reaction. Under ultraviolet (UV) light, the pyridinium C─N bonds in TPZ3+ platforms are polarized and weakened, resulting in the occurrence of cage decomposition via β-elimination. Guest recognition could help to prevent this UV-stimulated cage decomposition by suppressing the excitation of the TPZ3+ units.

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