Facile Fabrication of Polymerizable Ionic Liquid Based-Gel Beads via Thiol–ene Chemistry

2015 ◽  
Vol 7 (31) ◽  
pp. 17298-17306 ◽  
Author(s):  
Mona Taghavikish ◽  
Surya Subianto ◽  
Naba Kumar. Dutta ◽  
Namita Roy Choudhury
Nanoscale ◽  
2021 ◽  
Author(s):  
Ning Gao ◽  
Kang Zhou ◽  
Kai Feng ◽  
Wanlin Zhang ◽  
Jiecheng Cui ◽  
...  

Micellar and vesicular structures capable of sensing and reporting the chemical environment as well as facilely introducing user-defined functions make a vital contribution to constructing versatile compartmentalized systems. Herein, combing...


2020 ◽  
Vol 49 (48) ◽  
pp. 17772-17778
Author(s):  
Jian-Hua Qin ◽  
Hua Zhang ◽  
Pengfei Sun ◽  
Ya-Dan Huang ◽  
Qingming Shen ◽  
...  

A facile fabrication of porphyrin-integrated MOF nanosheets as efficient photosensitizers for photodynamic therapy (PDT) is presented.


Author(s):  
Kaushik A. Kudtarkar ◽  
Thomas W. Smith ◽  
Patricia Iglesias ◽  
Michael J. Schertzer

In the operation of many common devices and processes, more than 60% of consumed energy is wasted in many common processes. These loses come in many forms including heat, friction, and vibration. Energy harvesters are devices that can recapture some of this waste energy and convert it into electrical energy. This work will focus on electrostatic energy harvesting devices that recapture vibrational energy. Electrostatic energy harvesters recapture mechanical energy when a conductive mass translates or deforms in an electric field. Polymer ionic liquid gel beads may serve as a useful replacement for fluid droplets in electrostatic energy harvesters. This work uses a recently developed method for reliable synthesis of polymer gel beads. These beads are synthesized using a micro-reactor, which generates monomeric droplets in a silicon oil carrier fluid. The monomer solution also contains a photoinitiator and cross linker, which enables the monomer to polymerize when exposed to UV light. The present work demonstrates a method to rapidly synthesize uniform beads with a variety of chemical compositions. These chemical compositions can be used to tune the electromechanical properties of the beads to improve performance in applications such as energy harvesting devices.


2016 ◽  
Vol 40 (9) ◽  
pp. 7923-7927 ◽  
Author(s):  
Xuefei Wu ◽  
Xuhua Zhou ◽  
Qingyin Wu ◽  
Wenfu Yan

Thermal-depended conductive properties of the ternary-POM-based layer-structure ionic liquid [TOAMe]4[In(H2O)PW11O39] was investigated. It shows fast ionic conductivity as high as 2.2 × 10−3 S cm−1 at 90 °C with the conductive activation energy of 30.19 kJ mol−1, which is related to its state, obviously increasing during the reversible phase transformation from a quasi-solid-state gel phase to an isotropic sol phase.


2021 ◽  
Author(s):  
Chongrui Zhang ◽  
Yong Zhang ◽  
Qiang zhao ◽  
Zhigang Xue

Mechanically robust gel polymer electrolyte (GPE) with cross-linked networks are crucial for energy storage and conversion applications. Poly[1-cyanomethyl-3-vinylimidazolium bis(trifluoromethane)sulfonimide] (PCMVImTFSI) was treated via various bases at room temperature, leading to...


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