Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline

2016 ◽  
Vol 8 (13) ◽  
pp. 8436-8444 ◽  
Author(s):  
Xiaojuan Wang ◽  
Leran Zou ◽  
He Fu ◽  
Yifu Xiong ◽  
Zixu Tao ◽  
...  
2016 ◽  
Vol 7 (7) ◽  
pp. 4167-4173 ◽  
Author(s):  
Wenling Gu ◽  
Liuyong Hu ◽  
Wei Hong ◽  
Xiaofang Jia ◽  
Jing Li ◽  
...  

A high-efficiency noble-metal-free oxygen reduction reaction (ORR) catalyst was obtained based on the pyrolysis of the inexpensive precursor cobalt dithiolene (an S4-chelate complex) on simultaneously reduced graphene oxide (GO) as a support matrix.


2019 ◽  
Vol 44 (45) ◽  
pp. 24922-24933 ◽  
Author(s):  
Sagar B. Ingavale ◽  
Indrajit Patil ◽  
Haridas Parse ◽  
Divya Catherin Sesu ◽  
Phiralang Marbaniang ◽  
...  

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 130-139 ◽  
Author(s):  
Tamás Varga ◽  
Lívia Vásárhelyi ◽  
Gergő Ballai ◽  
Henrik Haspel ◽  
Albert Oszkó ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92648-92655 ◽  
Author(s):  
Sankararao Mutyala ◽  
Jayaraman Mathiyarasu ◽  
Ashok Mulchandani

Here, we report a low-cost, noble metal free Fe–N–C catalyst prepared using carbonized polyaniline (PANI) and ferric chloride as precursors in an inert atmosphere for oxygen reduction reaction.


2016 ◽  
Vol 4 (29) ◽  
pp. 11156-11178 ◽  
Author(s):  
C. Retna Raj ◽  
Arpan Samanta ◽  
Seung Hyo Noh ◽  
Siniya Mondal ◽  
Takeyoshi Okajima ◽  
...  

Recent progress in the development of a new class of inexpensive metal-free and non-noble metal-based electrocatalysts for the cathodic reduction of oxygen is discussed.


2017 ◽  
Vol 60 (12) ◽  
pp. 1494-1507 ◽  
Author(s):  
Xiaoxiao Huang ◽  
Yazhou Wang ◽  
Wei Li ◽  
Yanglong Hou

Author(s):  
Xiaoyang Dong ◽  
Jinxing Wang ◽  
Xiao Wang ◽  
Jingdong Yang ◽  
Ling Zhu ◽  
...  

Abstract Developing efficient, durable, and cost-effective non-noble metal catalysts for oxygen reduction reaction (ORR) is necessary to promote the efficiency and performance of Mg-air batteries. Herein, the Co3O4/CuO nanoparticles were synthesized by a low-cost and simple approach using CuCo-based prussian blue analogue (PBA) as precursor of pyrolysis at different calcination temperatures. It was found that the Co3O4/CuO nanoparticles calcined at 600ºC (CCO-600) have relatively small size and superior ORR performance. The onset potential is 0.889 V and the diffusion limiting current density achieves 6.746 mA·cm-2, as well as prominent stability in 0.1 M KOH electrolyte. The electron transfer number of the CCO-600 is 3.89 under alkaline medium, which indicates that the reaction mechanism of ORR is dominated by 4 e process, similar to commercial Pt. The primary Mg-air battery with the CCO-600 as the cathode catalyst has been assembled and possesses better discharge performance than the CuCo-based PBA. The open circuit voltage of CCO-600 arrives at 1.76 V and energy density of 1895.95 mWh/g. This work provides an effective strategy to develop non-noble metal ORR catalyst for the application of metal-air batteries


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