Orthogonally Functionalized Donor/Acceptor Homo- and Heterodimeric Dyes for Dye-Sensitized Solar Cells: An Approach to Introduce Panchromaticity and Control the Charge Recombination

2017 ◽  
Vol 9 (40) ◽  
pp. 34875-34890 ◽  
Author(s):  
Manik Chandra Sil ◽  
Vediappan Sudhakar ◽  
Munavvar Fairoos Mele Kavungathodi ◽  
Vellimalai Punitharasu ◽  
Jayaraj Nithyanandhan
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
And Control ◽  
Sensitized Solar Cells

Reducing charge recombination losses in solid state dye sensitized solar cells: the use of donor–acceptor sensitizer dyes

2007 ◽  
pp. 1725-1727 ◽  
Author(s):  
Samantha Handa ◽  
Helga Wietasch ◽  
Mukundan Thelakkat ◽  
James R. Durrant ◽  
Saif A. Haque
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

scholarly journals Pyran-Squaraine as Photosensitizers for Dye-Sensitized Solar Cells: DFT/TDDFT Study of the Electronic Structures and Absorption Properties

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Shaaban A. Elroby ◽  
Abdullah M. Asiri ◽  
Rifaat H. Hilal
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Nbo Analysis ◽  
Basis Set ◽  
Absorption Properties ◽  
Charge Delocalization ◽  
Squaraine Dyes ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

In an effort to provide, assess, and evaluate a theoretical approach which enables designing efficient donor-acceptor dye systems, the electronic structure and optical properties of pyran-squaraine as donor-acceptor dyes used in dye-sensitized solar cells were investigated. Ground state properties have been computed at the B3LYP/6-31+G**level of theory. The long-range corrected density functionals CAM-B3LYP, PBEPBE, PBE1PBE (PBE0), and TPSSH with 6-311++G**were employed to examine absorption properties of the studied dyes. In an extensive comparison between experimental results and ab initio benchmark calculations, the TPSSH functional with 6-311++G**basis set was found to be the most appropriate in describing the electronic properties for the studied pyran and squaraine dyes. Natural transition orbitals (NTO), frontier molecular orbitals (FMO), LUMO, HOMO, and energy gaps, of these dyes, have been analyzed to show their effect on the process of electron injection and dye regeneration. Interaction between HOMO and LUMO of pyran and squaraine dyes was investigated to understand the recombination process and charge-transfer process involving these dyes. Additionally, we performed natural bond orbital (NBO) analysis to investigate the role of charge delocalization and hyperconjugative interactions in the stability of the molecule.

Molecular design of donor-acceptor dyes for efficient dye-sensitized solar cells I: a DFT study

2014 ◽  
Vol 20 (6) ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Abdullah M. Asiri ◽  
Saadullah G. Aziz ◽  
Shaaban A. K. Elroby
Keyword(s):  
Solar Cells ◽  
Molecular Design ◽  
Dye Sensitized Solar Cells ◽  
Dft Study ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

New Dual Donor-Acceptor (2D-π-2A) Porphyrin Sensitizers for Stable and Cost-Effective Dye-Sensitized Solar Cells

2013 ◽  
Vol 8 (9) ◽  
pp. 2144-2153 ◽  
Author(s):  
Ram B. Ambre ◽  
Gao-Fong Chang ◽  
Manoj R. Zanwar ◽  
Ching-Fa Yao ◽  
Eric Wei-Guang Diau ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Cost Effective ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

Using Orbital Symmetry to Minimize Charge Recombination in Dye-Sensitized Solar Cells

2012 ◽  
Vol 125 (3) ◽  
pp. 1007-1009 ◽  
Author(s):  
Emanuele Maggio ◽  
Natalia Martsinovich ◽  
Alessandro Troisi
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Orbital Symmetry ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

scholarly journals Bis-tridentate Ru(ii) sensitizers with a spatially encumbered 2,6-dipyrazolylpyridine ancillary ligand for dye-sensitized solar cells

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42013-42023 ◽  
Author(s):  
Ting-Kuang Chang ◽  
Yun Chi
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Ancillary Ligand ◽  
Dye Sensitized ◽  
Dye Loading ◽  
Sensitized Solar Cells

The sensitizer TF-tBu_C3F7 has shown the highest overall efficiencies of JSC = 18.47 mA cm−2, VOC = 767 mV, FF = 0.71 and PCE = 10.05% under simulated one sun irradiation, due to the fine balance between dye loading and reduced charge recombination.

New insights into electrolyte-component biased and transfer- and transport-limited charge recombination in dye-sensitized solar cells

RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 84959-84966 ◽  
Author(s):  
Dong-Li Gao ◽  
Yi Wang ◽  
Ping Zhang ◽  
Li-Min Fu ◽  
Xi-Cheng Ai ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Density ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
High Electron ◽  
High Electron Density ◽  
Dye Sensitized ◽  
Electrolyte Component ◽  
Sensitized Solar Cells

Charge recombination takes place, respectively, within the frameworks of transfer- and transport-limited recombination mechanisms, at low and high electron density.

Effect of TiO2 surface treatment on electron transfer in dye-sensitized solar cells

2022 ◽  
Author(s):  
Suping Jia ◽  
Tong Cheng ◽  
Huinian Zhang ◽  
Hao Wang ◽  
Caihong Hao
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
High Efficiency ◽  
Surface Defects ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Defect States ◽  
Transport Pathway ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Defect states in the TiO2 nanoparticles can cause severe charge recombination and poor electron-transport efficiency when used as a photoanode in dye-sensitized solar cells (DSSCs). Herein, we report a simple and practical way to passivate the surface defects of TiO2 through hydrothermal treating with acetic acid and H2SO4, introducing a high percentage of 101 facets and sulfonic acid functional groups on the TiO2 surface. A high efficiency of 8.12% has been achieved, which is 14% higher than that of untreated TiO2 under the same condition. EIS results prove that the multiacid-treated TiO2 can promote electron transport and reduce charge recombination at the interface of the TiO2 and electrolyte. This work provides an efficient approach to engineer the electron-transport pathway in DSSCs.

scholarly journals Photovoltaic Performance of Dye-Sensitized Solar Cells Containing ZnO Microrods

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1645 ◽  
Author(s):  
Seong Il Cho ◽  
Hye Kyeong Sung ◽  
Sang-Ju Lee ◽  
Wook Hyun Kim ◽  
Dae-Hwan Kim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Surface Area ◽  
Electrochemical Impedance ◽  
Collection Efficiency ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Growth Time ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

At an elevated temperature of 90 °C, a chemical bath deposition using an aqueous solution of Zn(NO3)2·6H2O and (CH2)6N4 resulted in the formation of both nanoflowers and microrods of ZnO on F-doped SnO2 glass with a seed layer. The nanoflowers and microrods were sensitized with dyes for application to the photoelectrodes of dye-sensitized solar cells (DSSCs). By extending the growth time of ZnO, the formation of nanoflowers was reduced and the formation of microrods favored. As the growth time was increased from 4 to 6 and then to 8 h, the open circuit voltage (Voc) values of the DSSCs were increased, whilst the short circuit current (Jsc) values varied only slightly. Changes in the dye-loading amount, dark current, and electrochemical impedance were monitored and they revealed that the increase in Voc was found to be due to a retardation of the charge recombination between photoinjected electrons and I3− ions and resulted from a reduction in the surface area of ZnO microrods. A reduced surface area decreased the dye contents adsorbed on the ZnO microrods, and thereby decreased the light harvesting efficiency (LHE). An increase in the electron collection efficiency attributed to the suppressed charge recombination counteracted the decreased LHE, resulting in comparable Jsc values regardless of the growth time.

Sign in / Sign up

Export Citation Format

Share Document