Finite-Size Charged Species Diffusion and pH Change in Nanochannels

2020 ◽  
Vol 12 (10) ◽  
pp. 12246-12255 ◽  
Author(s):  
Nicola Di Trani ◽  
Alberto Pimpinelli ◽  
Alessandro Grattoni
Keyword(s):  
Finite Size ◽  
Ph Change ◽  
Charged Species ◽  
Species Diffusion

The partial realization theory of finite size two-dimensional arrays

1981 ◽  
Vol 64 (10) ◽  
pp. 1-8
Author(s):  
Tsuyoshi Matsuo ◽  
Yasumichi Hasegawa ◽  
Yoshikuni Okada
Keyword(s):  
Finite Size ◽  
Two Dimensional ◽  
Realization Theory

Dynamics of Ion Locking in Doubly Polymerized Ionic Liquids

2020 ◽  
Author(s):  
Swati Arora ◽  
Julisa Rozon ◽  
Jennifer Laaser
Keyword(s):  
Dielectric Constant ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Ion Pairs ◽  
Polymer Chains ◽  
Ion Motion ◽  
Charged Species ◽  
Broadband Dielectric Spectroscopy ◽  
Covalently Linked ◽  
Insight Into

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>

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