Alkyl-Aryl Amine-Rich Molecules for CO2 Removal via Direct Air Capture

Author(s):  
Dharam Raj Kumar ◽  
Cornelia Rosu ◽  
Achintya R. Sujan ◽  
Miles A. Sakwa-Novak ◽  
Eric W. Ping ◽  
...  
Author(s):  
Jeffrey A. Amelse ◽  
Paul K. Behrens

Many corporations and governments aspire to become Net Zero Carbon Dioxide by 2030-2050. Achieving this goal requires understanding where energy is produced and consumed, the magnitude of CO2 generation, and the Carbon Cycle. Many prior proposed solutions focus on reducing future CO2 emissions from continued use of fossil fuels. Examination of these technologies exposes their limitations and shows that none offer a complete solution. For example, bioethanol is shown to be both carbon and energy inefficient. Direct Air Capture technologies are needed to reduce CO2 already in the air. The most natural form of Direct Air Capture involves letting nature do the work of creating biomass via photosynthesis. However, it is necessary to break the Carbon Cycle by permanently sequestering that biomass carbon in “landfills” modified to discourage decomposition to CO2 and methane. Tree leaves and biomass grown on-purpose, such as high yield switchgrass, are proposed as good biomass sources for this purpose. Left unsequestered, leaves decompose with a short Carbon Cycle time constant releasing CO2 back to the atmosphere. While in any given year, leaves represent a small fraction of a tree’s above ground biomass, leaves can represent a substantial fraction of the total biomass generated by a tree when integrated over a tree’s lifetime. Understanding the chemistry of the distinct phases landfills undergo is the key to minimizing or eliminating decomposition. First, the compact cross-linked structure of cellulose and keeping water out will make it difficult for initial depolymerization to release sugars. Air ingress should be minimized to minimize Phase I aerobic decomposition. pH manipulation can discourage acid formation during Phase II. Lignocellulose is low in nutrients needed for anaerobic decomposition. Inhibitors can be added if needed. The goal is to move quickly to the dormant phase where decomposition stops. The cost for Carbon Capture and Storage (CCS) for growing and sequestering high yield switchgrass is estimated to be lower than CCS for steam reforming of methane hydrogen plants (SRM) and supercritical or combined cycle coal power plants. Thus, sequestration of biomass is a natural, carbon efficient, and low-cost method of Direct Capture. Biomass sequestration can provide CO2 removal on giga tonnes per year scale and can be implemented in the needed timeframe (2030-2050).


2021 ◽  
Vol 46 ◽  
pp. 101487
Author(s):  
Marco Marchese ◽  
Giulio Buffo ◽  
Massimo Santarelli ◽  
Andrea Lanzini

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Giulia Realmonte ◽  
Laurent Drouet ◽  
Ajay Gambhir ◽  
James Glynn ◽  
Adam Hawkes ◽  
...  

Joule ◽  
2021 ◽  
Author(s):  
Francesco Sabatino ◽  
Alexa Grimm ◽  
Fausto Gallucci ◽  
Martin van Sint Annaland ◽  
Gert Jan Kramer ◽  
...  

Author(s):  
Haley A. Petersen ◽  
Oana R. Luca

This work maps thermodynamic favorability zones for the capture of carbon dioxide from air.


2017 ◽  
Vol 144 (2) ◽  
pp. 181-193 ◽  
Author(s):  
Adriana Marcucci ◽  
Socrates Kypreos ◽  
Evangelos Panos

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