Physical Characteristics of Poly(vinyl alcohol) and Calcium Alginate Hydrogels for the Immobilization of Activated Sludge

2001 ◽  
Vol 2 (2) ◽  
pp. 568-574 ◽  
Author(s):  
M. C. Doria-Serrano ◽  
F. A. Ruiz-Treviño ◽  
C. Rios-Arciga ◽  
M. Hernández-Esparza ◽  
P. Santiago



2016 ◽  
Vol 36 (9) ◽  
pp. 891-898
Author(s):  
Sadao Araki ◽  
Yuko Shirakura ◽  
Harufumi Suzuki ◽  
Hideki Yamamoto

Abstract Spherical glutaraldehyde cross-linked poly(vinyl alcohol) (PVA) hydrogels (G-PVA) were prepared in three steps: gelatification, cross-linking, and removal of alginate. Gelatification was carried out by dropping a solution of alginate, PVA, and glutaraldehyde into a calcium chloride solution to form calcium alginate. Calcium alginate gels were prepared at 20°C, 40°C, 60°C, and 80°C to study the effect of gelatification temperature on the formation of pores on the surface of G-PVA. The effect of the alginate content was studied. PVA and glutaraldehyde were cross-linked by immersion of the gels in a solution of H2SO4 and Na2SO4. The effect of sodium alginate and inorganic salts, such as MgSO4 and K2SO4, on the formation of pores on the surface of G-PVA was confirmed.



2013 ◽  
Vol 67 (2) ◽  
Author(s):  
Steva Levic ◽  
Verica Djordjevic ◽  
Nevenka Rajic ◽  
Milan Milivojevic ◽  
Branko Bugarski ◽  
...  

AbstractElectrostatic extrusion was applied to the encapsulation of 3-ethoxy-4-hydroxybenzaldehyde (ethyl vanillin) in calcium alginate and calcium alginate/poly(vinyl alcohol) beads. The calcium alginate/poly(vinyl alcohol) hydrogel spheres were formed after contact with the cross-linker solution of calcium chloride, followed by the freeze-thaw method for poly(vinyl alcohol) gel formation. The entrapment of aroma in beads was investigated by FTIR and thermal analysis (thermogravimetry/differential thermal gravimetry; TGA/DTG). The mass loss in the temperature range of 150–300°C is related to degradation of the matrix and the release of ethyl vanillin. According to the DTG curve, the release of ethyl vanillin occurs at about 260°C. TGA measurements of the stored samples confirmed that formulations were stable for a period of one month. FTIR analysis provides no evidence for chemical interactions between flavour and alginate that would alter the nature of the functional groups in the flavour compound.



Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3993
Author(s):  
Cristian Valdés ◽  
Oscar Valdés ◽  
Daniel Bustos ◽  
Diana Abril ◽  
Gustavo Cabrera-Barjas ◽  
...  

Pesticides are used worldwide to increase crop yields in agriculture. However, their toxicity and accumulation capacity can make them toxic to the environment, animals and humans. In the case of workers chronically exposed to these substances, they must be sampled continuously, so urine is an excellent option. In this sense, this study proposes to use poly(vinyl alcohol)-malic acid hydrogels, and chitosan-coated calcium alginate as new sorbent phases to be used in pesticide determination processes in urine. To better understand the behavior of these materials in the capture and desorption process, molecular dynamics simulations (MDS) were used, and desorption experiments were performed, using mechanical agitation, ultrasound, and pH variation in the desorption process, in order to optimize the parameters to obtain better recoveries. Under the optimal experimental conditions, the maximum recoveries were of the order of 11% (CFN), 3% (KCF), 53% (DMT), 18% (MTD) and 35% (MTL). Although the recoveries were not exhaustive, they are a first approximation for the use of these new sorbent phases in the determination of this type of compound in aqueous solutions and urine.



2013 ◽  
Vol 49 (2) ◽  
pp. 290-298 ◽  
Author(s):  
Romana Rošic ◽  
Jan Pelipenko ◽  
Julijana Kristl ◽  
Petra Kocbek ◽  
Marija Bešter-Rogač ◽  
...  


2008 ◽  
Vol 60 ◽  
pp. 32-37 ◽  
Author(s):  
George K. Stylios ◽  
Tao Yu Wan

This paper reports a novel method of developing SMART nanocomposite membranes and coatings by in situ synthesis of iron oxide particles in a Poly(vinyl alcohol) (PVA)matrix, using co-precipitation of different amounts of Fe(II) and Fe(III) taken in an alkaline medium. Poly(vinyl alcohol) was used to encapsulate iron oxide nanoparticles, as scaffold for particle nucleation and its influence on particle size and on magnetic properties were studied. The ferrogels were prepared by a freeze/thawing process of the solutions containing magnetite nanoparticles. Magnetite particles with an average diameter of 20-40 nm were obtained homogeneously within the matrix because of the tridimensional structure and chelating capacities of PVA. Calcium-alginate PVA gel was used to encapsulate the iron oxide/PVA nanocomposite. The mechanical properties and the saturation magnetization of the system were measured. The combination of magnetic properties of iron nanoparticles with the biocompatibility of calcium-alginate suggests that these materials have great potential for use as controlled delivery systems activated externally by magnetic stimuli.









Sign in / Sign up

Export Citation Format

Share Document