In Situ Generation of Carbon Monoxide from Solid Molybdenum Hexacarbonyl. A Convenient and Fast Route to Palladium-Catalyzed Carbonylation Reactions

2002 ◽  
Vol 4 (2) ◽  
pp. 109-111 ◽  
Author(s):  
Nils-Fredrik K. Kaiser ◽  
Anders Hallberg ◽  
Mats Larhed
Keyword(s):  
Carbon Monoxide ◽  
Molybdenum Hexacarbonyl ◽  
Fast Route ◽  
Palladium Catalyzed ◽  
In Situ Generation

Palladium‐Catalyzed Chlorocarbonylation of Aryl (Pseudo)Halides Through In Situ Generation of Carbon Monoxide

2020 ◽  
Vol 59 (41) ◽  
pp. 17887-17896 ◽  
Author(s):  
Philip Boehm ◽  
Sven Roediger ◽  
Alessandro Bismuto ◽  
Bill Morandi
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalyzed ◽  
In Situ Generation ◽  
Pseudo Halides

Palladium‐Catalyzed Chlorocarbonylation of Aryl (Pseudo)Halides Through In Situ Generation of Carbon Monoxide

2020 ◽  
Vol 132 (41) ◽  
pp. 18043-18052 ◽  
Author(s):  
Philip Boehm ◽  
Sven Roediger ◽  
Alessandro Bismuto ◽  
Bill Morandi
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalyzed ◽  
In Situ Generation ◽  
Pseudo Halides

In-situ generation of graphene network in silicon carbide fibers: Role of iodine and carbon monoxide

Carbon ◽  
2020 ◽  
Vol 158 ◽  
pp. 110-120
Author(s):  
Junsung Hong ◽  
Youngjin Ko ◽  
Kwang-Yeon Cho ◽  
Dong-Geun Shin ◽  
Prabhakar Singh ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Silicon Carbide ◽  
Silicon Carbide Fibers ◽  
In Situ Generation

Oxalic acid as the in situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

2017 ◽  
Vol 15 (23) ◽  
pp. 5033-5040 ◽  
Author(s):  
Changdong Shao ◽  
Ailan Lu ◽  
Xiaoling Wang ◽  
Bo Zhou ◽  
Xiaohong Guan ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Oxalic Acid ◽  
Highly Efficient ◽  
Palladium Catalyzed

Oxalic acid as a highly efficient, safe and tractable concentrated carbon monoxide surrogate was successfully introduced into the palladium-catalyzed hydroxycarbonylation of arylhalides.

scholarly journals Palladium Catalyzed Alternating Cooligomerization of Ethylene and Carbon Monoxide to Unsaturated Ketones

1995 ◽  
Vol 50 (3) ◽  
pp. 430-438 ◽  
Author(s):  
Wilhelm Keim ◽  
Heiko Maas ◽  
Stefan Mecking
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalysts ◽  
Methylene Chloride ◽  
General Structure ◽  
Phosphine Ligands ◽  
Unsaturated Ketones ◽  
Palladium Catalyzed ◽  
First Time ◽  
Cationic Palladium

Cationic palladium catalysts have been used to cooligomerize ethylene and carbon monoxide. At high ethylene/CO ratios (m /m = 10:1) in methylene chloride as a solvent, unsaturated alternating cooligomers of the general structure R[C(O)CH2CH2]mH ( m ≥ 1 ; R ≡CH2=CH-, CH2=CHCH2CH2- and CH3CH = CHCH2-) were obtained for the first time. Single component catalyst precursors [(allyl)Pd(P^X )]+Y- (P^X = Ph2P(CH2)nC(= O )OR, Ph2P(CH2)2P(=O)Ph2, Ph2P(CH2)nPh2P(CH2)2S (=O )Ph, n = 1 - 3 , R = Me, Et; Y- = BF4-, SbF6- ) with bidentate P,O- and P,S-ligands as well as in situ catalysts with unfunctionalized phosphine ligands were used. With P"Bu3 as a ligand, selectivities for ethylvinylketone of 40% based on the CO converted were obtained. The hemilabile phosphino-ester and phosphinothiophene ligands behave like monodentate phosphines under catalytic conditions.

Sign in / Sign up

Export Citation Format

Share Document