Equivalence point potential in redox titrations

1970 ◽  
Vol 47 (3) ◽  
pp. 240
Author(s):  
Arno H. A. Heyn
1968 ◽  
Vol 20 (03/04) ◽  
pp. 548-554
Author(s):  
J Gajewski ◽  
G Markus

SummaryA method for the standardization of human plasminogen is proposed, based on the stoichiometric interaction between plasminogen and streptokinase, resulting in inhibition of proteolytic activity. Activation of a constant amount of plasminogen with increasing amounts of streptokinase yields linearly decreasing activities, as a function of streptokinase, with a sharp transition to a constant residual level. The point of transition corresponds to complete saturation of plasmin with streptokinase in a 1:1 molar ratio, and is therefore a measure of the amount of plasminogen present initially, in terms of streptokinase equivalents. The equivalence point is independent of the kind of protein substrate used, buffer, pH, length of digestion and, within limits, temperature. The method, therefore, is not subject to the variations commonly encountered in the usual determination based on specific activity measurements.


2016 ◽  
Vol 8 (29) ◽  
pp. 5806-5811 ◽  
Author(s):  
Stephen A. Ferguson ◽  
Xuewei Wang ◽  
Mark E. Meyerhoff

This manuscript reports a novel and facile method for PQ-10/SLS separation and subsequent PQ-10 quantification via potentiometric titration.


Vestnik MEI ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 51-59
Author(s):  
Vladimir M. Tereshkin ◽  
◽  
Irshat L. Aitov ◽  
Dmitriy A. Grishin ◽  
Vyacheslav V. Tereshkin ◽  
...  

The aim of the study is to determine the parameters characterizing the ripple of a motor's three- and five-phase windings common point potentials (for the star winding connection diagram) with respect to the converter zero point. One of the reserves for decreasing electromagnetically induced vibration of an electric motor with a rotating field is to increase the number of working winding phases. The study subject is a five-phase motor winding connected to a bridge converter, namely, its ability to reduce electromagnetically induced vibration in comparison with that in using a three-phase winding. The common point potential ripple parameters are studied, and an approach is proposed to estimating the amplitude modulation of the space-time voltage vector of three- and five-phase windings under the influence of the common point potential ripple with respect to the converter zero point. Theoretical studies were carried out using the Fourier series expansion method and vector analysis methods. To confirm the theoretical results, experimental studies of the prototypes of three-phase and five-phase synchronous motors with inductors made on the basis of permanent magnets were carried out. The main results have shown the following. With increasing the number of phases of the rotating field motor working winding connected to a bridge converter, the common point potential ripple amplitude with respect to the converter zero point decreases, and the ripple frequency increases. The product of ripple amplitude by frequency remains unchanged. It is assumed that the common point potential ripple of the motor multiphase winding with respect to the converter zero terminal results in the amplitude modulation of the space-time voltage vector. With increasing the number of winding phases, the modulation amplitude decreases, and the modulation frequency increases. A five-phase motor has a lower level of the working winding common point potential ripple with respect to the converter zero point in comparison with a three-phase motor. Thus, it can be assumed that there will be a lower level of electromagnetically induced vibration in using a simple converter operation algorithm. The obtained results can be used in designing electric traction systems with vector control on the basis of multiphase motors. With increasing the number of phases, the common point potential ripple amplitude in a multiphase winding with respect to the converter zero point decreases, and the ripple frequency increases. Thus, the common point potential ripple amplitude in a five-phase winding is 5/3 times less than that in a three-phase winding, and the ripple frequency increases by 5/3 times, respectively. With increasing the number of working winding phases, the amplitude modulation of the resulting space-time voltage vector decreases. This circumstance has a positive effect on decreasing the electromagnetically induced vibration.


2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Yingjie Wang ◽  
Haiyuan Liu ◽  
Wenchao Wang ◽  
Kangan Wang

The neutral-point (NP) potential balance control in three-level neutral-point-clamped (NPC) back-to-back converter is a research nodus. Its current strategies are the same as the strategies of a single three-level NPC converter. But the strategies do not give full play to its advantages that the neutral-point current can only flow through the connected midlines in both sides of the converter but does not flow through the DC-bus capacitors. In this paper, firstly the NP potential model based on the NP current injected is proposed. It overcomes numerous variable constraints and mutual coupling in the conventional model based on the zero-sequence voltage injected. And then on this basis, three NP-potential balance control algorithms, unilateral control, bilateral independent control, and bilateral coordinated control, are proposed according to difference requirements. All of these algorithms use the midlines rather than the DC-bus capacitors to flow the NP current as much as possible. Their control abilities are further quantitatively analyzed and compared. Finally, simulation results verify the validity and effectiveness of these algorithms.


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