Hydrothermal Synthesis of a Three-Dimensional Organic−Inorganic Hybrid Network Formed by Poly(oxomolybdophosphate) Anions and Nickel Coordination Cations

2006 ◽  
Vol 45 (17) ◽  
pp. 6586-6588 ◽  
Author(s):  
Wen-Jung Chang ◽  
Yau-Chen Jiang ◽  
Sue-Lein Wang ◽  
Kwang-Hwa Lii
Keyword(s):  
Hydrothermal Synthesis ◽  
Three Dimensional ◽  
Hybrid Network ◽  
Inorganic Hybrid

Hydrothermal Synthesis of a Microporous Organic-Inorganic Hybrid Framework [Fe0.28V0.72OH0.8(NH4)0.2(C8H4O4)] · 0.53(C8H6O4)

2002 ◽  
Vol 755 ◽  
Author(s):  
Tabatha R. Whitfield ◽  
Xiqu Wang ◽  
Allan J. Jacobson
Keyword(s):  
Hydrothermal Synthesis ◽  
Chemical Reactivity ◽  
Three Dimensional ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
X Ray ◽  
Hybrid Framework ◽  
Inorganic Framework ◽  
New Phase

ABSTRACTSingle crystals of a novel organic-inorganic framework [Fe0.28V0.72OH0.8(NH4)0.2(C8H4O4)] · 0.53(C8H6O4), 1, have been prepared by hydrothermal synthesis in the presence of an oxidizing agent. The structure was solved by single crystal X-ray diffraction: space group Pnma, a = 17.6956 (19) Å, b = 6.8745 (7) Å, c = 11.9303(12) Å. The three dimensional framework is constructed from Fe/V-O chains that are cross-linked by 1,4-benzene dicarboxylate (BDC) anions forming large one-dimensional channels. As synthesized, the compound contains additional dicarboxylate groups occupying disordered positions in the channels that can be removed by heating. The chemical reactivity of 1 and its magnetic properties are reported. The new phase is closely related to analogous Cr (III) and V(III) phases recently reported by Férey and co-workers.

Hydrothermal synthesis, structure and magnetic properties of a three-dimensional cobalt(ii) – aminophenyltetrazolate coordination polymer

2014 ◽  
Vol 43 (19) ◽  
pp. 7263-7268 ◽  
Author(s):  
Tiffany M. Smith ◽  
Michael Tichenor ◽  
Yuan-Zhu Zhang ◽  
Kim R. Dunbar ◽  
Jon Zubieta
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Hydrothermal Synthesis ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Magnetic Behavior ◽  
Ac Magnetic Susceptibility

The three-dimensional [Co3(OH)2(H2O)2(aptet)4] exhibits magnetic properties consistent with a ferrimagnetic chain with the non-compensating resultant moment of one Co(ii) per trinuclear Co(ii) subunit and ac magnetic susceptibility indicative of glassy-like magnetic behavior.

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