Effective Anaerobic Decolorization of Azo Dye Acid Orange 7 in Continuous Upflow Packed-Bed Reactor Using Biological Activated Carbon System

2007 ◽  
Vol 46 (21) ◽  
pp. 6788-6792 ◽  
Author(s):  
Gergo Mezohegyi ◽  
Alexey Kolodkin ◽  
Ursula I. Castro ◽  
Christophe Bengoa ◽  
Frank Stuber ◽  
...  
2012 ◽  
Vol 237-238 ◽  
pp. 30-37 ◽  
Author(s):  
Isabel Mesquita ◽  
Luís C. Matos ◽  
Filipa Duarte ◽  
F.J. Maldonado-Hódar ◽  
Adélio Mendes ◽  
...  

2015 ◽  
Vol 36 (2) ◽  
pp. 125-133 ◽  
Author(s):  
Behnaz Sheidaei ◽  
Mohammad A. Behnajady

In this work, a design equation was presented for a batch-recirculated photoreactor composed of a packed bed reactor (PBR) with immobilised TiO2-P25 nanoparticle thin films on glass beads, and a continuous-flow stirred tank (CFST). The photoreactor was studied in order to remove C.I. Acid Orange 7 (AO7), a monoazo anionic dye from textile industry, by means of UV/TiO2 process. The effect of different operational parameters such as the initial concentration of contaminant, the volume of solution in CFST, the volumetric flow rate of liquid, and the power of light source in the removal efficiency were examined. A rate equation for the removal of AO7 is obtained by mathematical kinetic modelling. The results of reaction kinetic analysis indicate the conformity of removal kinetics with Langmuir-Hinshelwood model (kL-H = 0.74 mg L-1 min-1, Kads = 0.081 mg-1 L). The represented design equation obtained from mathematical kinetic modelling can properly predict the removal rate constant of the contaminant under different operational conditions (R2 = 0.963). Thus the calculated and experimental results are in good agreement with each other.


2011 ◽  
Vol 186 (1) ◽  
pp. 659-666 ◽  
Author(s):  
Shiying Yang ◽  
Xin Yang ◽  
Xueting Shao ◽  
Rui Niu ◽  
Leilei Wang

2008 ◽  
Vol 76 (1) ◽  
pp. 142-146 ◽  
Author(s):  
Soon-An Ong ◽  
Eiichi Toorisaka ◽  
Makoto Hirata ◽  
Tadashi Hano

2021 ◽  
Vol 16 (1) ◽  
pp. 205-213
Author(s):  
Viqhi Aswie ◽  
Lailatul Qadariyah ◽  
Mahfud Mahfud

Microalgae, as a potential raw material for biofuel, has several advantages compared to other biomass. One effective way to convert microalgae into biofuel is by thermal cracking or pyrolysis, and using a catalyst or not. So far, studies on the use of microalgae, that are converted into biofuels, is still use highly concentrated catalysts in packed bed reactors, which is not economical. Therefore, the aim of this study is to convert Chlorella sp. into biofuels with conventional pyrolysis without and using an activated carbon catalyst using packed bed reactor with bubble column. The reaction temperature is 400–600 °C, pyrolysis time is 1–4 hours, and the active carbon catalyst concentration is 0–2%. The 200 grams of Chlorella sp. and the catalyst was mixed in a fixed bed reactor under vacuum (−3 mm H20) condition. Next, we set the reaction temperature. When the temperature was reached, the pyrolysis was begun. After certain time was reached, the pyrolysis produced a liquid oil product. Oil products are measured for density and viscosity. The results showed that the conventional pyrolysis succeeded in converting microalgae Chlorella sp. into liquid biofuels. The highest yield of total liquid oil is obtained 50.2 % (heavy fraction yield, 43.75% and light fraction yield, 6.44%) at the highest conditions which was obtained with 1% activated carbon at a temperature and pyrolysis time of 3 hours. Physical properties of liquid biofuel are density of 0.88 kg/m3 and viscosity of 5.79 cSt. This physical properties are within the range of the national biodiesel standard SNI 7182-2012. The packed bed reactor completed with bubble column is the best choice for converting biofuel from microalgae, because it gives different fractions, so that it is easier to process further to the commercial biofuel stage. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 


2019 ◽  
Vol 79 (6) ◽  
pp. 1195-1205 ◽  
Author(s):  
Xuxu Wang ◽  
Xuebin Hu ◽  
Chun Zhao ◽  
Zhihua Sun ◽  
Huaili Zheng ◽  
...  

Abstract In this study, powder activated carbon (PAC) utilized to activate peroxydisulfate (PDS) was investigated for decolorization of Acid Orange 7 (AO7). The results indicated a remarkable synergistic effect in the PAC/PDS system. The effect of PAC, PDS dosages and initial pH on AO7 decolorization were studied and the processes followed first-order kinetics. Response surface method with central composite design (CCD) model was utilized to optimize these three factors and analyze the combined interaction. The optimum condition for the decolorization rate of AO7 was analyzed as the following: PAC (0.19 g/L), PDS (1.64 g/L), and initial pH (4.14). Cl− and SO42− showed a promoting effect on AO7 decolorization while HCO3− had a slightly inhibiting effect. Quenching experiments confirmed that both sulfate and hydroxyl radicals were the oxidizing species, and the oxidation reaction occurred on the surface of PAC. The results of UV-vis spectrum with 100% decolorization rate and the 50% total organic carbon reduction indicated highly efficient decolorization and mineralization of AO7 in the PAC/PDS system. Finally, the recovery performance of PAC was studied and the result indicated PAC had poor reuse in reactivity.


Chemosphere ◽  
2020 ◽  
Vol 241 ◽  
pp. 125125 ◽  
Author(s):  
Zhihua Sun ◽  
Shiyao Li ◽  
Haojie Ding ◽  
Yunhua Zhu ◽  
Xuxu Wang ◽  
...  

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