Quantitative evaluation of molecular orientation in thin Langmuir-Blodgett films by FT-IR transmission and reflection-absorption spectroscopy

1990 ◽  
Vol 94 (1) ◽  
pp. 62-67 ◽  
Author(s):  
Junzo. Umemura ◽  
Toshihide. Kamata ◽  
Takeshi. Kawai ◽  
Tohru. Takenaka
1989 ◽  
Vol 178 (1-2) ◽  
pp. 281-287 ◽  
Author(s):  
Junzo Umemura ◽  
Yoshiki Hishiro ◽  
Takeshi Kawai ◽  
Tohru Takenaka ◽  
Yoshinori Gotoh ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 22 (7) ◽  
pp. no-no
Author(s):  
T. KAMATA ◽  
J. UMEMURA ◽  
T. TAKENAKA ◽  
K. TAKEHARA ◽  
K. ISOMURA ◽  
...  

1995 ◽  
Vol 49 (4) ◽  
pp. 466-471 ◽  
Author(s):  
Ricardo Aroca ◽  
Eric Johnson ◽  
Asim Kumar Maiti

The molecular organization in Langmuir-Blodgett (LB) monolayers for five organic dyes with a common chromophore moiety was studied. With the use of transmission and reflection-absorption (FT)IR spectroscopy (RAIRS), the orientation of the chromophore units in the LB monolayer was determined. The results obtained with carbonyl and C=C stretching vibrations exclude a flat-on orientation of the chromophore moiety and may be rationalized in terms of a tilted head-on organization of the chromophore on the Ag, ZnS, and Ge surfaces. The tilt angle, φ, formed between the direction of the dynamic dipole moment and the normal to the surface of the film was determined from the combined infrared data obtained in a transmission geometry and in RAIRS. The aromatic-aromatic interaction plays a significant role in determining the molecular alignment in the Langmuir and LB monolayers.


Langmuir ◽  
1994 ◽  
Vol 10 (6) ◽  
pp. 1898-1902 ◽  
Author(s):  
Norihisa Katayama ◽  
Yukihiro Ozaki ◽  
Takahiro Seki ◽  
Takashi Tamaki ◽  
Keiji Iriyama

1989 ◽  
Vol 28 (Part 1, No. 9) ◽  
pp. 1673-1676 ◽  
Author(s):  
Sonoko Suzuki ◽  
Satoru Isoda ◽  
Mitsuo Maeda

1998 ◽  
Vol 102 (33) ◽  
pp. 6425-6432 ◽  
Author(s):  
Xiaoxi Chen ◽  
Christopher C. Moser ◽  
Denis L. Pilloud ◽  
P. Leslie Dutton

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