OXIDATION OF PHOSPHOROUS ACID BY PEROXYDISULFATE. I. KINETICS OF THE REACTION IN NEUTRAL SOLUTION1

1963 ◽  
Vol 67 (12) ◽  
pp. 2698-2701 ◽  
Author(s):  
Ephraim Ben-Zvi
Keyword(s):  
Phosphorous Acid ◽  
Kinetics Of

scholarly journals Copper (II) Mediated Oxidative Alkoxylation of White Phosphorus. Communication 1.

2010 ◽  
Vol 12 (3,4) ◽  
pp. 259
Author(s):  
R.R. Abdreimova ◽  
F.Kh. Faizova ◽  
A.A. Karimova
Keyword(s):  
Metal Ion ◽  
Phosphorous Acid ◽  
Inert Atmosphere ◽  
White Phosphorus ◽  
Main Reaction ◽  
Reaction Products ◽  
Dimethyl Phosphite ◽  
Trialkyl Phosphates ◽  
Oxidative Alkoxylation ◽  
Kinetics Of

White phosphorus has been oxidized by copper (II) acetylacetonate, halides or carboxylates in aliphatic alcohols to yield dialkyl phosphates and trialkyl phosphates under inert atmosphere and mild reaction conditions. Trialkyl phosphite has been observed as unstable organophosphorus intermediate, which is being converted into the main reaction products. In the case of methanolic solutions, the derivatives of two step acidolysis of dimethyl phosphite, monomethyl phosphite and phosphorous acid, have been additionally detected among the reaction products. The influence of the copper (II) oxidants on the kinetics of accumulation and transmutation of organophosphorus products has been explored. The order of oxidative ability of the copper (II) compounds has been established. The major steps of the reaction including (i) the coordination of white phosphorus and alcohol to metal ion and (ii) the redox decomposition of this intermediate complex accompanied by reducing elimination of elementary copper and formation of organophosphorus product have been also suggested.

Kinetics of overall decomposition of ozonides of 2,2?-methylene-bis-4-methyl-6-tert-butylphenyl esters of phosphorous acid

1988 ◽  
Vol 37 (4) ◽  
pp. 650-653
Author(s):  
V. V. Sheroshovets ◽  
N. M. Korotaeva ◽  
R. K. Yanbaev ◽  
V. Kh. Kadyrova ◽  
N. A. Mukmeneva ◽  
...  
Keyword(s):  
Phosphorous Acid ◽  
Kinetics Of

Kinetics of the vanadium(V) oxidation of phosphorous acid

1974 ◽  
pp. 226 ◽  
Author(s):  
Kalyan K. Sen Gupta ◽  
Basanta B. Pal ◽  
Dulal C. Mukherjee
Keyword(s):  
Phosphorous Acid ◽  
Kinetics Of

ChemInform Abstract: KINETICS OF THE VANADIUM(V) OXIDATION OF PHOSPHOROUS ACID

1974 ◽  
Vol 5 (11) ◽  
pp. no-no
Author(s):  
KALYAN K. SEN GUPTA ◽  
BASANTA B. PAL ◽  
DULAL C. MUKHERJEE
Keyword(s):  
Phosphorous Acid ◽  
Kinetics Of

Direct observations of radiation-enhanced transformations in glass

1983 ◽  
Vol 41 ◽  
pp. 354-355
Author(s):  
J. F. DeNatale ◽  
D. G. Howitt
Keyword(s):  
Glass Matrix ◽  
Diffusion Mechanism ◽  
Bubble Formation ◽  
Silicate Glasses ◽  
Phase Decomposition ◽  
Direct Observations ◽  
Thin Foils ◽  
Oxygen Bubble ◽  
Electron Energy Loss ◽  
Kinetics Of

The electron irradiation of silicate glasses containing metal cations produces various types of phase separation and decomposition which includes oxygen bubble formation at intermediate temperatures figure I. The kinetics of bubble formation are too rapid to be accounted for by oxygen diffusion but the behavior is consistent with a cation diffusion mechanism if the amount of oxygen in the bubble is not significantly different from that in the same volume of silicate glass. The formation of oxygen bubbles is often accompanied by precipitation of crystalline phases and/or amorphous phase decomposition in the regions between the bubbles and the detection of differences in oxygen concentration between the bubble and matrix by electron energy loss spectroscopy cannot be discerned (figure 2) even when the bubble occupies the majority of the foil depth.The oxygen bubbles are stable, even in the thin foils, months after irradiation and if van der Waals behavior of the interior gas is assumed an oxygen pressure of about 4000 atmospheres must be sustained for a 100 bubble if the surface tension with the glass matrix is to balance against it at intermediate temperatures.

Irradiation behavior of pyrolytic silicon carbide

1983 ◽  
Vol 41 ◽  
pp. 72-73
Author(s):  
R. J. Lauf
Keyword(s):  
Silicon Carbide ◽  
Fission Products ◽  
Thermodynamics And Kinetics ◽  
Neutron Fluences ◽  
Fuel Particles ◽  
Sic Coatings ◽  
Irradiation Behavior ◽  
Kinetics Of ◽  
Htgr Fuel

Fuel particles for the High-Temperature Gas-Cooled Reactor (HTGR) contain a layer of pyrolytic silicon carbide to act as a miniature pressure vessel and primary fission product barrier. Optimization of the SiC with respect to fuel performance involves four areas of study: (a) characterization of as-deposited SiC coatings; (b) thermodynamics and kinetics of chemical reactions between SiC and fission products; (c) irradiation behavior of SiC in the absence of fission products; and (d) combined effects of irradiation and fission products. This paper reports the behavior of SiC deposited on inert microspheres and irradiated to fast neutron fluences typical of HTGR fuel at end-of-life.

The Ordered Phase Formation in Ti-Al-Ga Alloys

1970 ◽  
Vol 28 ◽  
pp. 440-441
Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Titanium Alloys ◽  
Growth Kinetics ◽  
Stoichiometric Composition ◽  
Good Potential ◽  
Alpha Titanium ◽  
Cold Rolled ◽  
Kinetics Of ◽  
Thermal Stability Of

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization

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